Strong electron-donating dialkylamino groups were incoporated onto the phthalocyanine ligand in bis(phthalocyaninato)rare earth complexes for the first time to investigate their effects on the spectroscopic properties...Strong electron-donating dialkylamino groups were incoporated onto the phthalocyanine ligand in bis(phthalocyaninato)rare earth complexes for the first time to investigate their effects on the spectroscopic properties,electrochemistry,and electronic structure.展开更多
基金support from the National Key Basic Research Program of China(Grant No.2013CB933402)the Natural Science Foundation of China(No.21290174,21631003,21671017,21301017,and 21401009)the Beijing Municipal Commission of Education,and the University of Science and Technology Beijing is gratefully acknowledged.
文摘Strong electron-donating dialkylamino groups were incoporated onto the phthalocyanine ligand in bis(phthalocyaninato)rare earth complexes for the first time to investigate their effects on the spectroscopic properties,electrochemistry,and electronic structure.