Shape control of mesoporous carbon microparticles(MCMPs)is of critical importance;in particular,asymmetric shapes that can yield unique properties have attracted significant attention.However,the tailored synthesis of...Shape control of mesoporous carbon microparticles(MCMPs)is of critical importance;in particular,asymmetric shapes that can yield unique properties have attracted significant attention.However,the tailored synthesis of asymmetric MCMPs with ordered structures remains challenging.Herein,we report a facile route to prepare asymmetric MCMPs by dynamic neutral interface-guided 3D-confined self-assembly(3D-CSA)of block copolymer/homopolymer(BCP/hP)blends,followed by a self-templated selective direct carbonization strategy.BCP/h P Janus microparticles with ordered hierarchical mesostructures were prepared with emulsion solvent evaporation-induced 3D-CSA.The continuous phase of BCP domains was then crosslinked.Composite asymmetric MCMPs are successfully generated after selective carbonization of the crosslinked continuous phase.This method allows tuning the shape of MCMPs easily by varying the blending ratio of BCP/h P.The composite asymmetric MCMPs combine the advantages of asymmetric shape,ordered structure,high specific surface area,chemical inertness and thermal stability and could provide great possibilities for applications in catalysis,drug delivery,energy conversion and storage.展开更多
A new fluorescent fingerprint powder(DFF-MMT)was formulated by blending cyclic chalcone dye DFF with montmorillonite(MMT),which can develop latent fingerprints(LFPs)with exceptional resolution and contrast on various ...A new fluorescent fingerprint powder(DFF-MMT)was formulated by blending cyclic chalcone dye DFF with montmorillonite(MMT),which can develop latent fingerprints(LFPs)with exceptional resolution and contrast on various surfaces,including ordinary glass,tin foil,marble,LED screens,and materials with distinct colors and fluorescent backgrounds.The fluorescence of DFF-MMT transforms from orange to bright yellow with LFPs,allowing for a flawless visualization of fingerprints on uneven surfaces or materials with static electricity.Impressively,fingerprints developed by DFF-MMT can be stored for over 21 months and conveniently duplicated.The developed LFPs by DFF-MMT still keep high quality under the influence of aquatic condition,illumination and thermal effects.DFF-MMT also exhibits benefits,such as affordability,real-time,high-resolution,high-contrast development and no damage to DNA,making it an ideal choice for sophisticated criminal investigations.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.52003094 and 52273010)。
文摘Shape control of mesoporous carbon microparticles(MCMPs)is of critical importance;in particular,asymmetric shapes that can yield unique properties have attracted significant attention.However,the tailored synthesis of asymmetric MCMPs with ordered structures remains challenging.Herein,we report a facile route to prepare asymmetric MCMPs by dynamic neutral interface-guided 3D-confined self-assembly(3D-CSA)of block copolymer/homopolymer(BCP/hP)blends,followed by a self-templated selective direct carbonization strategy.BCP/h P Janus microparticles with ordered hierarchical mesostructures were prepared with emulsion solvent evaporation-induced 3D-CSA.The continuous phase of BCP domains was then crosslinked.Composite asymmetric MCMPs are successfully generated after selective carbonization of the crosslinked continuous phase.This method allows tuning the shape of MCMPs easily by varying the blending ratio of BCP/h P.The composite asymmetric MCMPs combine the advantages of asymmetric shape,ordered structure,high specific surface area,chemical inertness and thermal stability and could provide great possibilities for applications in catalysis,drug delivery,energy conversion and storage.
基金supported by the National Natural Science Foundation of China(22377064 and 22122705)CAMS Innovation Fund for Medical Sciences(CIFMS)(2021-12M-1-054)Youth Innovation Team Development Program of Shandong Higher Education Institutions(2022KJC004).
文摘A new fluorescent fingerprint powder(DFF-MMT)was formulated by blending cyclic chalcone dye DFF with montmorillonite(MMT),which can develop latent fingerprints(LFPs)with exceptional resolution and contrast on various surfaces,including ordinary glass,tin foil,marble,LED screens,and materials with distinct colors and fluorescent backgrounds.The fluorescence of DFF-MMT transforms from orange to bright yellow with LFPs,allowing for a flawless visualization of fingerprints on uneven surfaces or materials with static electricity.Impressively,fingerprints developed by DFF-MMT can be stored for over 21 months and conveniently duplicated.The developed LFPs by DFF-MMT still keep high quality under the influence of aquatic condition,illumination and thermal effects.DFF-MMT also exhibits benefits,such as affordability,real-time,high-resolution,high-contrast development and no damage to DNA,making it an ideal choice for sophisticated criminal investigations.
