The crystal plane plays a very important role in the properties of Ni-rich cathodes.[003]crystallographic texture regulation has been proven to improve structural stability,and yet,the discrepancy of particles with di...The crystal plane plays a very important role in the properties of Ni-rich cathodes.[003]crystallographic texture regulation has been proven to improve structural stability,and yet,the discrepancy of particles with different exposed ratios of[003]in structural attenuation has not been clarified.Herein,we have unraveled comprehensively the structural decay difference for Ni-rich cathodes’primary particles with the different percentages of exposed[003]by regulating the precursor coprecipitation process.The findings based on structural characterization,first-principles calculations,finite element analysis,and electrochemical test reveal that the length and width of particles represent[110]and[003]directions,respectively,and show that cathode particles with a higher[110]/[003]ratio can effectively inhibit structure degradation and intergranular/intragranular crack formation owing to the low oxygen vacancy formation energy on(003)planes and the small local stress on secondary/primary particles.This study may provide guidance for the structural design of layered cathodes.展开更多
基金National Natural Science Foundation of China,Grant/Award Numbers:20A20145,21878195,22108183,21975154,22179078Distinguished Young Foundation of Sichuan Province,Grant/Award Number:2020JDJQ0027+7 种基金2020 Strategic cooperation project between Sichuan University and Zigong Municipal People's Government,Grant/Award Number:2020CDZG-09State Key Laboratory of Polymer Materials Engineering,Grant/Award Number:sklpme2020-3-02Sichuan Provincial Department of Science and Technology,Grant/Award Numbers:2020YFG0471,2020YFG0022Sichuan Province Science and Technology Achievement Transfer and Trans-formation Project,Grant/Award Number:21ZHSF0111Sichuan University postdoctoral interdisciplinary Innovation Fund,the State Key Laboratory of Electrical Insulation and Power Equipment,Xi'an Jiaotong University,Grant/Award Number:EIPE22208National Postdoctoral Program for Innovative Talents,Grant/Award Number:BX20200222China Postdoctoral Science Foundation,Grant/Award Numbers:2020M682878,2022M712231Start-up funding of Chemistry and Chemical Engineering Guangdong Laboratory,Grant/Award Number:2122010。
文摘The crystal plane plays a very important role in the properties of Ni-rich cathodes.[003]crystallographic texture regulation has been proven to improve structural stability,and yet,the discrepancy of particles with different exposed ratios of[003]in structural attenuation has not been clarified.Herein,we have unraveled comprehensively the structural decay difference for Ni-rich cathodes’primary particles with the different percentages of exposed[003]by regulating the precursor coprecipitation process.The findings based on structural characterization,first-principles calculations,finite element analysis,and electrochemical test reveal that the length and width of particles represent[110]and[003]directions,respectively,and show that cathode particles with a higher[110]/[003]ratio can effectively inhibit structure degradation and intergranular/intragranular crack formation owing to the low oxygen vacancy formation energy on(003)planes and the small local stress on secondary/primary particles.This study may provide guidance for the structural design of layered cathodes.
