Spiritual demand as one of the basic requirements of human, has more important significance for the elderly group. Descriptive statistic analysis shows that in the CLHLS, the elderly spiritual demand and supply is in ...Spiritual demand as one of the basic requirements of human, has more important significance for the elderly group. Descriptive statistic analysis shows that in the CLHLS, the elderly spiritual demand and supply is in a state of disequilibrium in our country, supply is far less than demand. The main factors of restricting the old people＇s spiritual need are not being met, including economic factors, intergenerational relations factors, emotional factors and the particularity of spiritual demand, etc. So we need to change our ideas, with the demand of the old structure and strength, by constructing a complete supply system of family, society and government to strengthen for the supply of the spiritual needs of old people, so that the elderly would be happy during his or her later lives.展开更多
By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimizatio...By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimization of multiple primary reactions for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Many catalysts developed through entropy engineering have been built in nearly equimolar ratios to pursue high entropy,hindering the identification of the active sites and potentially diluting the concentration of real active sites while weakening their electronic interactions with reaction intermediates.Herein,this work proposes an entropy-engineering strategy in metal nanoparticle-embedded nitrogen carbon electrocatalysts,implemented by entropy-engineered Prussian blue analogs(PBA)as precursors to enhance the catalytic activity of primary Cu-Fe active sites.Through the introduction of the micro-strains driven by entropy engineering,density functional theory(DFT)calculations and geometric phase analysis(GPA)using Lorentz electron microscopy further elucidate the optimization of the adsorption/desorption of intermediates.Furthermore,the multi-dimensional morphology and the size diminishment of the nanocrystals serve to expand the electrochemical area,maximizing the catalytic activity for both ORR and OER.Notably,the Zn-air battery assembled with CuFeCoNiZn-NC operated for over 1300 h with negligible decay.This work presents a paradigm for the design of low-cost electrocatalysts with entropy engineering for multi-step reactions.展开更多
文摘Spiritual demand as one of the basic requirements of human, has more important significance for the elderly group. Descriptive statistic analysis shows that in the CLHLS, the elderly spiritual demand and supply is in a state of disequilibrium in our country, supply is far less than demand. The main factors of restricting the old people＇s spiritual need are not being met, including economic factors, intergenerational relations factors, emotional factors and the particularity of spiritual demand, etc. So we need to change our ideas, with the demand of the old structure and strength, by constructing a complete supply system of family, society and government to strengthen for the supply of the spiritual needs of old people, so that the elderly would be happy during his or her later lives.
基金supported by the National Natural Science Foundation of China(52071083,52231007,12327804,52471224)Zhuhai Fudan Innovation Institute,and the Science and Technology Commission of Shanghai Municipality(23ZR1405000).
文摘By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimization of multiple primary reactions for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Many catalysts developed through entropy engineering have been built in nearly equimolar ratios to pursue high entropy,hindering the identification of the active sites and potentially diluting the concentration of real active sites while weakening their electronic interactions with reaction intermediates.Herein,this work proposes an entropy-engineering strategy in metal nanoparticle-embedded nitrogen carbon electrocatalysts,implemented by entropy-engineered Prussian blue analogs(PBA)as precursors to enhance the catalytic activity of primary Cu-Fe active sites.Through the introduction of the micro-strains driven by entropy engineering,density functional theory(DFT)calculations and geometric phase analysis(GPA)using Lorentz electron microscopy further elucidate the optimization of the adsorption/desorption of intermediates.Furthermore,the multi-dimensional morphology and the size diminishment of the nanocrystals serve to expand the electrochemical area,maximizing the catalytic activity for both ORR and OER.Notably,the Zn-air battery assembled with CuFeCoNiZn-NC operated for over 1300 h with negligible decay.This work presents a paradigm for the design of low-cost electrocatalysts with entropy engineering for multi-step reactions.
