The metallurgy industry consumes a considerable amount of coal and fossil fuels,and its carbon dioxide emissions are increasing every year.Replacing coal with renewable,carbon-neutral biomass for metallurgical product...The metallurgy industry consumes a considerable amount of coal and fossil fuels,and its carbon dioxide emissions are increasing every year.Replacing coal with renewable,carbon-neutral biomass for metallurgical production is of great significance in reducing global carbon consumption.This study describes the current state of research in biomass metallurgy in recent years and analyzes the concept and scientific principles of biomass metallurgy.The fundamentals of biomass pretreatment technology and biomass metallurgy technology were discussed,and the industrial application framework of biomass metallurgy was proposed.Furthermore,the economic and social advantages of biomass metallurgy were analyzed to serve as a reference for the advancement of fundamental theory and industrial application of biomass metallurgy.展开更多
Erratum to:International Journal of Minerals,Metallurgy and Materials Volume 29,Number 6,June 2022,Page 1133 https://doi.org/10.1007/s12613-022-2501-9 The original version of this article unfortunately contained a mis...Erratum to:International Journal of Minerals,Metallurgy and Materials Volume 29,Number 6,June 2022,Page 1133 https://doi.org/10.1007/s12613-022-2501-9 The original version of this article unfortunately contained a mistake.The spelling of the surname of one of the co-authors was incorrect.The name should be Alberto N.Conejo.展开更多
Under the background of the strategic goal of"double carbon,"the carbon reduction and consumption reduction of the iron and steel industry,especially in the ironmaking process,need to be further improved.The...Under the background of the strategic goal of"double carbon,"the carbon reduction and consumption reduction of the iron and steel industry,especially in the ironmaking process,need to be further improved.The raceway of tuyere provides the chemical environment,fuel and power source for blast furnace smelting.The research on the characteristics of its action mode and mechanism is of great significance to clarify the way of reducing carbon and consumption of blast furnace.In general,the formation mechanism,energy distribution,research progress,extended resource injection and directional regulation are studied and expounded.The research results of various scholars on the characteristics of the raceway show that the raceway is a complex process including multiphase turbulent flow,heat,momentum,mass and homogeneous and heterogeneous chemical reactions.With the development of multi-source fuel injection technology,the complexity of problem research is more obvious.Therefore,the collection of multi-factor,multi-directional and multi-process characteristic information in the raceway can provide guarantee for the stability,smooth operation,high yield,carbon reduction and consumption reduction of blast furnace and provide new ideas for the green and low-carbon development of iron and steel industry.展开更多
Eggshells,a by-product of the food industry,represent a significant yet often overlooked waste stream.Given their vast production volume and inherent properties,eggshells have the potential to serve as a sustainable a...Eggshells,a by-product of the food industry,represent a significant yet often overlooked waste stream.Given their vast production volume and inherent properties,eggshells have the potential to serve as a sustainable and environmentally friendly co-fuel.Aiming to explore the co-combustion characteristics and kinetics of pulverized coal blended with eggshells and offer insights into their combined use as a renewable energy source,a systematic investigation was conducted to evaluate the physical and chemical properties of Shangwan bituminous coal,Shouyang anthracite coal,eggshell(ES)and their blends.Additionally,comprehensive experimental analyses were performed at different heating rates applying a non-isothermal thermogravimetric method.The findings revealed that the addition of ES enhanced the combustion efficiency.The combustion characteristics were significantly influenced by the ES content,with an optimal blend ratio identified for maximum combustion efficiency.To represent the thermal degradation experiments,random pore model and volume model were employed.Furthermore,activation energies and pre-exponential factors were determined.The random pore model demonstrated more superior performance compared to the volume model.The activation energies of all the samples ranged between 18.29 and 42.48 kJ/mol,with the lowest value observed for the sample containing 20 mass%ES.展开更多
The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel.The results showed that after upgrading,the volatile con...The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel.The results showed that after upgrading,the volatile content of biochar ranged from 16.19%to 45.35%,and the alkali metal content,ash content,and specific surface area were significantly reduced.The optimal route for biochar pro-duction is hydrothermal carbonization-pyrolysis(P-HC),resulting in biochar with a higher calorific value,C=C structure,and increased graphitization degree.The apparent activation energy(E)of the sample ranges from 199.1 to 324.8 kJ/mol,with P-HC having an E of 277.8 kJ/mol,lower than that of raw biomass,primary biochar,and anthracite.This makes P-HC more suitable for blast furnace injection fuel.Additionally,the paper proposes a path for P-HC injection in blast furnaces and calculates potential environmental benefits.P-HC of-fers the highest potential for carbon emission reduction,capable of reducing emissions by 96.04 kg/t when replacing 40wt%coal injec-tion.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51704216)the State Key Laboratory of Advanced Metallurgy,University of Science and Technology Beijing(Nos.41620025,41620026,and 41621009)+1 种基金the Interdisciplinary Research Project for Young Teachers of University of ScienceTechnology Beijing(Fundamental Research Funds f or the Central Universities)(No.FRF-IDRY-20-014)。
文摘The metallurgy industry consumes a considerable amount of coal and fossil fuels,and its carbon dioxide emissions are increasing every year.Replacing coal with renewable,carbon-neutral biomass for metallurgical production is of great significance in reducing global carbon consumption.This study describes the current state of research in biomass metallurgy in recent years and analyzes the concept and scientific principles of biomass metallurgy.The fundamentals of biomass pretreatment technology and biomass metallurgy technology were discussed,and the industrial application framework of biomass metallurgy was proposed.Furthermore,the economic and social advantages of biomass metallurgy were analyzed to serve as a reference for the advancement of fundamental theory and industrial application of biomass metallurgy.
文摘Erratum to:International Journal of Minerals,Metallurgy and Materials Volume 29,Number 6,June 2022,Page 1133 https://doi.org/10.1007/s12613-022-2501-9 The original version of this article unfortunately contained a mistake.The spelling of the surname of one of the co-authors was incorrect.The name should be Alberto N.Conejo.
基金financially supported by the Major Science and Technology-Special Plan“Unveiling and Leading”Project of Shanxi Province(No.202201050201011)National Natural Science Foundation of China(No.52274316)+4 种基金China Baowu Low-Carbon Metallurgy Innovation Foundation(No.BWLCF202116)National Key R&D Program of China(No.2022YFE0208100)Major Science and Technology Project of Xinjiang(No.2022A01003)Major Science and Technology Projects of Anhui Province(No.202210700037)Special Funding for Science and Technology of China Minmetals Corporation(No.2021ZXD01).
文摘Under the background of the strategic goal of"double carbon,"the carbon reduction and consumption reduction of the iron and steel industry,especially in the ironmaking process,need to be further improved.The raceway of tuyere provides the chemical environment,fuel and power source for blast furnace smelting.The research on the characteristics of its action mode and mechanism is of great significance to clarify the way of reducing carbon and consumption of blast furnace.In general,the formation mechanism,energy distribution,research progress,extended resource injection and directional regulation are studied and expounded.The research results of various scholars on the characteristics of the raceway show that the raceway is a complex process including multiphase turbulent flow,heat,momentum,mass and homogeneous and heterogeneous chemical reactions.With the development of multi-source fuel injection technology,the complexity of problem research is more obvious.Therefore,the collection of multi-factor,multi-directional and multi-process characteristic information in the raceway can provide guarantee for the stability,smooth operation,high yield,carbon reduction and consumption reduction of blast furnace and provide new ideas for the green and low-carbon development of iron and steel industry.
基金sponsored by the Major Science and Technology Special Plan“Unveiling and Leading”Project of Shanxi Province(No.202201050201011)Major Science and Technology Projects of Anhui Province(No.202210700037)Special Funding for Science and Technology of China Minmetals Corporation(No.2021ZXD01).
文摘Eggshells,a by-product of the food industry,represent a significant yet often overlooked waste stream.Given their vast production volume and inherent properties,eggshells have the potential to serve as a sustainable and environmentally friendly co-fuel.Aiming to explore the co-combustion characteristics and kinetics of pulverized coal blended with eggshells and offer insights into their combined use as a renewable energy source,a systematic investigation was conducted to evaluate the physical and chemical properties of Shangwan bituminous coal,Shouyang anthracite coal,eggshell(ES)and their blends.Additionally,comprehensive experimental analyses were performed at different heating rates applying a non-isothermal thermogravimetric method.The findings revealed that the addition of ES enhanced the combustion efficiency.The combustion characteristics were significantly influenced by the ES content,with an optimal blend ratio identified for maximum combustion efficiency.To represent the thermal degradation experiments,random pore model and volume model were employed.Furthermore,activation energies and pre-exponential factors were determined.The random pore model demonstrated more superior performance compared to the volume model.The activation energies of all the samples ranged between 18.29 and 42.48 kJ/mol,with the lowest value observed for the sample containing 20 mass%ES.
基金the National Key R&D Program of China(No.2022YFE0208100)the National Natural Science Foundation of China(No.5274316)+1 种基金the Key Research and Development Plan of Anhui Province,China(No.202210700037)the Major Science and Technology Project of Xinjiang Uygur Autonomous Region,China(No.2022A01003).
文摘The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel.The results showed that after upgrading,the volatile content of biochar ranged from 16.19%to 45.35%,and the alkali metal content,ash content,and specific surface area were significantly reduced.The optimal route for biochar pro-duction is hydrothermal carbonization-pyrolysis(P-HC),resulting in biochar with a higher calorific value,C=C structure,and increased graphitization degree.The apparent activation energy(E)of the sample ranges from 199.1 to 324.8 kJ/mol,with P-HC having an E of 277.8 kJ/mol,lower than that of raw biomass,primary biochar,and anthracite.This makes P-HC more suitable for blast furnace injection fuel.Additionally,the paper proposes a path for P-HC injection in blast furnaces and calculates potential environmental benefits.P-HC of-fers the highest potential for carbon emission reduction,capable of reducing emissions by 96.04 kg/t when replacing 40wt%coal injec-tion.
