The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase preci...The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.展开更多
In the sentence beginning'and more irreversible hydrogentrapping sites….'in this article,the value'0.38×1025 cm-3'should have read'0.68×1020 cm-3'.These corrections do not alter the ...In the sentence beginning'and more irreversible hydrogentrapping sites….'in this article,the value'0.38×1025 cm-3'should have read'0.68×1020 cm-3'.These corrections do not alter the primary conclusion that the irreversible hydrogen trap density in 42CrNiMoV steel is nearly twice that of 40CrNiMo steel.展开更多
Hydrogen embrittlement(HE)remains a critical challenge for high-strength steels.This study comparatively investigates the HE behavior and hydrogen diffusion characteristics of a vanadium-micro-alloyed 42CrNiMoV steel ...Hydrogen embrittlement(HE)remains a critical challenge for high-strength steels.This study comparatively investigates the HE behavior and hydrogen diffusion characteristics of a vanadium-micro-alloyed 42CrNiMoV steel against conventional 40CrNiMo steel through slow strain rate testing(SSRT),hydrogen thermal desorption,and hydrogen permeation measurements.The 42CrNiMoV steel demonstrated better mechanical properties and improved HE resistance under SSRT with both hydrogen pre-charged and in situ charging conditions.Microstructural analysis revealed that vanadium micro-alloying leads to grain refinement and reduces hydrogen diffusivity through vanadium carbides.Fractographic investigations revealed the environment-dependent fracture mechanisms,transitioning from ductile-to brittle-dominated failure modes under different hydrogen-charging conditions.These findings validate that vanadium micro-alloying represents a promising,cost-effective strategy for developing hydrogen-resistant high-strength steels,while emphasizing the crucial need for rigorous hydrogen ingress control in practical applications.展开更多
A duplex ultrafine microstructure in a medium manganese steel （0.2C-5Mn） was produced by austenite re- verted transformation annealing （ART-annealing）. The microstructural evolution during annealing was examined b...A duplex ultrafine microstructure in a medium manganese steel （0.2C-5Mn） was produced by austenite re- verted transformation annealing （ART-annealing）. The microstructural evolution during annealing was examined by scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and X-ray diffraction （XRD）. Based on the microstructure examination, it was found that some M3C type carbides appeared in the martensitic matrix at the beginning of the ART-annealing. But with further increasing annealing time, these carbides would be dissolved and finally disappeared. Meanwhile, the austenite lath was developed in the ART-annealing process and the volume fraction of austenite increosed with the increase of the annealing time, which resulted in a duplex microstructure con- sisting of ultrafine-grained ferrite and large fraction of reverted austenite after long time annealing. The mechanical property examinations by uniaxial tensile tests showed that ART-annealing （6 h, 650 ℃） resulted in a superhigh product of strength to elongation up to 42 GPa ·%.展开更多
The medium-Mn steel with ferrite and austenite structure was rolled in the intercritical region down to dif- ferent rolling reduction. The microstructure and mechanical properties of the rolled steels were investigate...The medium-Mn steel with ferrite and austenite structure was rolled in the intercritical region down to dif- ferent rolling reduction. The microstructure and mechanical properties of the rolled steels were investigated by scan- ning electron microscopy, transmission electron microscopy, X-ray diffraction and tensile tests. It was found that the ferrite and austenite structure gradually evolved into an ultrafine structure from the random directional lath structure to lamellar structure with lath longitudinal direction parallel to the rolling direction with increasing rolling strain. It was found that the thickness of the laths was gradually refined with increasing rolling strain. The lath thickness is about 0. 15 9m stored with high density dislocations and the austenite volume fraction of the steel is about 24% after 80% rolling reduction. Furthermore, it was interesting to find that yield strength, tensile strength and total elongation of the 80% rolled medium-Mn steel are about 1000 MPa, 1250 MPa and 24%, respectively, demonstrating an excellent combination of the strength and ductility. Based on the microstructure examination, it was proposed that the grain refinement of the medium-Mn steels could be attributed to the duplex structure and the low rolling temperature. Analysis of the relationship between the microstructure and the mechanical properties indicated that the high yield strength mainly resulted from the ultrafine grain size and the high density dislocation, but the improved ductili- ty may be attributed to the large fractions of austenite retained after intercritical rolling.展开更多
Addressing the issue of the healthy and coordinated development of the population and economic factors in rural areas will not only help consolidate and expand the achievements of poverty alleviation,but will also lay...Addressing the issue of the healthy and coordinated development of the population and economic factors in rural areas will not only help consolidate and expand the achievements of poverty alleviation,but will also lay a foundation for comprehensive rural revitalization.In this paper,the spatial coupling relationship between the population and economic factors in rural areas in the QinlingDaba Mountains,China,is explored to provide a reference for rural revitalization and regional sustainable development in poverty areas.Sixty-eight county units in rural areas in the Qinling-Daba Mountains,as well as the population and economic factors in rural areas,are used to study the spatial coupling relationship between population and economy,as well as the driving mechanism,in rural areas in the Qinling-Daba Mountains from 2010 to 2020.The results show that a population contraction phenomenon occurred in the rural areas in the Qinling-Daba Mountains,and the spatial agglomeration trends of the population and economic factors were consistent.The agglomeration was mainly located in the suburban areas of the municipal area,and the agglomeration degree was significantly higher in these areas than in other areas.In terms of the spatial distribution,the economic development level of the rural areas in the northeastern part of the Qinling-Daba Mountains was generally higher than that in the central and western parts,and the unbalanced trends of the population and economic spatial differentiation in the eastern and western regions were significant.The spatial coupling relationship between the population and economy changed from coordinated development to economic advancement.This was mainly due to the mutual restriction and joint actions of the industrial structure,capital situation,natural environment,policies,and institutional regulations,among which the industrial structure and capital status had significant effects.展开更多
A TiA1N coating was deposited on a heat resistant steel X12CrMoWVNbN10-1-1 by vacuum arc ion plating. The tensile and fatigue properties of the coated steel were investigated at room temperature （RT） and 650 ℃. The...A TiA1N coating was deposited on a heat resistant steel X12CrMoWVNbN10-1-1 by vacuum arc ion plating. The tensile and fatigue properties of the coated steel were investigated at room temperature （RT） and 650 ℃. The results reveal that the TiA1N coating is compact, on which a small number of large particle and pits are present. The Ti/Al atomic ratio in the coating is about 0.94. The average hardness of the coating is 1 868 HV0.1 and the interface bonding force between TiAIN coating and the substrate is about 3 l N. The elastic modulus and the strength of the steel are improved by the deposition of TiAIN coating. The influence of the TiA1N coating on the tensile properties of the steel can be ignored at both RT and 650 ℃. Moreover, there is no obvious decrease of the fatigue limit of substrate when the steel is coated by the coating at the investigated temperature.展开更多
The thermal stability of retained austenite（RA）and the mechanical properties of the quenched and intercritical annealed 0.1C-5Mn steel with the starting ultrafine lamellar duplex structure of ferrite and retained au...The thermal stability of retained austenite（RA）and the mechanical properties of the quenched and intercritical annealed 0.1C-5Mn steel with the starting ultrafine lamellar duplex structure of ferrite and retained austenite during tempering within the range from 200 to 500°C were studied by X-ray diffraction（XRD）,transmission electron microscopy（TEM）and tensile testing.The results showed that there was a slight decrease in the RA volume fraction with increasing tempering temperature up to 400°C.This caused a slight increase in the ultimate tensile strength（UTS）and a slight decrease in the total elongation（TE）;thus,the product of UTS to TE（UTS×TE）as high as 31GPa·% was obtained and remained nearly unchanged.However,aportion of the RA began to decompose when tempered at 500°C and thus caused a^35% decrease of the RA fraction and a^16%decrease of the value of UTS×TE.It is concluded that the ultrafine lamellar duplex structure is rather stable and the excellent combination of strength and ductility could be retained with tempering temperature up to 400°C.Thus,thermal processes such as galvanization are feasible for the tested steel provided that their temperatures are not higher than 400°C.展开更多
业务流程合规性检查可以帮助企业及早发现潜在问题,保证业务流程的正常运行和安全性。提出一种基于改进BERT(Bidirectional Encoder Representations from Transformers)和轻量化卷积神经网络(CNN)的业务流程合规性检查方法。首先,根据...业务流程合规性检查可以帮助企业及早发现潜在问题,保证业务流程的正常运行和安全性。提出一种基于改进BERT(Bidirectional Encoder Representations from Transformers)和轻量化卷积神经网络(CNN)的业务流程合规性检查方法。首先,根据历史事件日志中的轨迹提取轨迹前缀,构造带拟合情况标记的数据集;其次,使用融合相对上下文关系的BERT模型完成轨迹特征向量的表示;最后,使用轻量化CNN模型构建合规性检查分类器,完成在线业务流程合规性检查,有效提高合规性检查的准确率。在5个真实事件日志数据集上进行实验,结果表明,该方法相比Word2Vec+CNN模型、Transformer模型、BERT分类模型在准确率方面有较大提升,且与传统BERT+CNN相比,所提方法的准确率最高可提升2.61%。展开更多
基金the National Natural Science Foundation of China(Key Program)(52031004).
文摘The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.
文摘In the sentence beginning'and more irreversible hydrogentrapping sites….'in this article,the value'0.38×1025 cm-3'should have read'0.68×1020 cm-3'.These corrections do not alter the primary conclusion that the irreversible hydrogen trap density in 42CrNiMoV steel is nearly twice that of 40CrNiMo steel.
基金supported by the Natural Science Foundation of Shanghai(No.23ZR1421700).
文摘Hydrogen embrittlement(HE)remains a critical challenge for high-strength steels.This study comparatively investigates the HE behavior and hydrogen diffusion characteristics of a vanadium-micro-alloyed 42CrNiMoV steel against conventional 40CrNiMo steel through slow strain rate testing(SSRT),hydrogen thermal desorption,and hydrogen permeation measurements.The 42CrNiMoV steel demonstrated better mechanical properties and improved HE resistance under SSRT with both hydrogen pre-charged and in situ charging conditions.Microstructural analysis revealed that vanadium micro-alloying leads to grain refinement and reduces hydrogen diffusivity through vanadium carbides.Fractographic investigations revealed the environment-dependent fracture mechanisms,transitioning from ductile-to brittle-dominated failure modes under different hydrogen-charging conditions.These findings validate that vanadium micro-alloying represents a promising,cost-effective strategy for developing hydrogen-resistant high-strength steels,while emphasizing the crucial need for rigorous hydrogen ingress control in practical applications.
基金Sponsored by National Natural Science Foundation of China(51371057,11172187)National Basic Research Program(973 Program)of China(2010CB630803)Program for New Century Excellent Talents in University of China(NCET-12-0372)
文摘A duplex ultrafine microstructure in a medium manganese steel （0.2C-5Mn） was produced by austenite re- verted transformation annealing （ART-annealing）. The microstructural evolution during annealing was examined by scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and X-ray diffraction （XRD）. Based on the microstructure examination, it was found that some M3C type carbides appeared in the martensitic matrix at the beginning of the ART-annealing. But with further increasing annealing time, these carbides would be dissolved and finally disappeared. Meanwhile, the austenite lath was developed in the ART-annealing process and the volume fraction of austenite increosed with the increase of the annealing time, which resulted in a duplex microstructure con- sisting of ultrafine-grained ferrite and large fraction of reverted austenite after long time annealing. The mechanical property examinations by uniaxial tensile tests showed that ART-annealing （6 h, 650 ℃） resulted in a superhigh product of strength to elongation up to 42 GPa ·%.
基金Item Sponsored by National Basic Research Program(973Program)of China(2010CB630830)
文摘The medium-Mn steel with ferrite and austenite structure was rolled in the intercritical region down to dif- ferent rolling reduction. The microstructure and mechanical properties of the rolled steels were investigated by scan- ning electron microscopy, transmission electron microscopy, X-ray diffraction and tensile tests. It was found that the ferrite and austenite structure gradually evolved into an ultrafine structure from the random directional lath structure to lamellar structure with lath longitudinal direction parallel to the rolling direction with increasing rolling strain. It was found that the thickness of the laths was gradually refined with increasing rolling strain. The lath thickness is about 0. 15 9m stored with high density dislocations and the austenite volume fraction of the steel is about 24% after 80% rolling reduction. Furthermore, it was interesting to find that yield strength, tensile strength and total elongation of the 80% rolled medium-Mn steel are about 1000 MPa, 1250 MPa and 24%, respectively, demonstrating an excellent combination of the strength and ductility. Based on the microstructure examination, it was proposed that the grain refinement of the medium-Mn steels could be attributed to the duplex structure and the low rolling temperature. Analysis of the relationship between the microstructure and the mechanical properties indicated that the high yield strength mainly resulted from the ultrafine grain size and the high density dislocation, but the improved ductili- ty may be attributed to the large fractions of austenite retained after intercritical rolling.
基金Under the auspices of National Natural Science Foundation of China(No.42071220,42371223)China Postdoctoral Science Foundation(No.2021M701053)Postgraduate Cultivating Innovation and Quality Improvement Action Plan of Henan University(No.SYLYC2022017)。
文摘Addressing the issue of the healthy and coordinated development of the population and economic factors in rural areas will not only help consolidate and expand the achievements of poverty alleviation,but will also lay a foundation for comprehensive rural revitalization.In this paper,the spatial coupling relationship between the population and economic factors in rural areas in the QinlingDaba Mountains,China,is explored to provide a reference for rural revitalization and regional sustainable development in poverty areas.Sixty-eight county units in rural areas in the Qinling-Daba Mountains,as well as the population and economic factors in rural areas,are used to study the spatial coupling relationship between population and economy,as well as the driving mechanism,in rural areas in the Qinling-Daba Mountains from 2010 to 2020.The results show that a population contraction phenomenon occurred in the rural areas in the Qinling-Daba Mountains,and the spatial agglomeration trends of the population and economic factors were consistent.The agglomeration was mainly located in the suburban areas of the municipal area,and the agglomeration degree was significantly higher in these areas than in other areas.In terms of the spatial distribution,the economic development level of the rural areas in the northeastern part of the Qinling-Daba Mountains was generally higher than that in the central and western parts,and the unbalanced trends of the population and economic spatial differentiation in the eastern and western regions were significant.The spatial coupling relationship between the population and economy changed from coordinated development to economic advancement.This was mainly due to the mutual restriction and joint actions of the industrial structure,capital situation,natural environment,policies,and institutional regulations,among which the industrial structure and capital status had significant effects.
基金Funded by National Science Foundation of China(No.51172182)the Program for New Century Excellent Talents in University(No.NCET-08-0460)the 111 Project(No.B08040)
文摘A TiA1N coating was deposited on a heat resistant steel X12CrMoWVNbN10-1-1 by vacuum arc ion plating. The tensile and fatigue properties of the coated steel were investigated at room temperature （RT） and 650 ℃. The results reveal that the TiA1N coating is compact, on which a small number of large particle and pits are present. The Ti/Al atomic ratio in the coating is about 0.94. The average hardness of the coating is 1 868 HV0.1 and the interface bonding force between TiAIN coating and the substrate is about 3 l N. The elastic modulus and the strength of the steel are improved by the deposition of TiAIN coating. The influence of the TiA1N coating on the tensile properties of the steel can be ignored at both RT and 650 ℃. Moreover, there is no obvious decrease of the fatigue limit of substrate when the steel is coated by the coating at the investigated temperature.
基金sponsored by the High-level Scientific Research Foundation for the Introduction of Talent of Beijing Jiaotong University(M14RC00010)the Fundamental Research Funds for the Central Universities(No.2014JBM108)
文摘The thermal stability of retained austenite（RA）and the mechanical properties of the quenched and intercritical annealed 0.1C-5Mn steel with the starting ultrafine lamellar duplex structure of ferrite and retained austenite during tempering within the range from 200 to 500°C were studied by X-ray diffraction（XRD）,transmission electron microscopy（TEM）and tensile testing.The results showed that there was a slight decrease in the RA volume fraction with increasing tempering temperature up to 400°C.This caused a slight increase in the ultimate tensile strength（UTS）and a slight decrease in the total elongation（TE）;thus,the product of UTS to TE（UTS×TE）as high as 31GPa·% was obtained and remained nearly unchanged.However,aportion of the RA began to decompose when tempered at 500°C and thus caused a^35% decrease of the RA fraction and a^16%decrease of the value of UTS×TE.It is concluded that the ultrafine lamellar duplex structure is rather stable and the excellent combination of strength and ductility could be retained with tempering temperature up to 400°C.Thus,thermal processes such as galvanization are feasible for the tested steel provided that their temperatures are not higher than 400°C.
文摘业务流程合规性检查可以帮助企业及早发现潜在问题,保证业务流程的正常运行和安全性。提出一种基于改进BERT(Bidirectional Encoder Representations from Transformers)和轻量化卷积神经网络(CNN)的业务流程合规性检查方法。首先,根据历史事件日志中的轨迹提取轨迹前缀,构造带拟合情况标记的数据集;其次,使用融合相对上下文关系的BERT模型完成轨迹特征向量的表示;最后,使用轻量化CNN模型构建合规性检查分类器,完成在线业务流程合规性检查,有效提高合规性检查的准确率。在5个真实事件日志数据集上进行实验,结果表明,该方法相比Word2Vec+CNN模型、Transformer模型、BERT分类模型在准确率方面有较大提升,且与传统BERT+CNN相比,所提方法的准确率最高可提升2.61%。
