In this paper, single crystal EPR study of a new binuclear copper (Ⅱ) cluster compound-[Cu2(α-C(10) H7CH2CO2)4 (DMF)2]·[DMF]2·H2O](DMF= (CH3)2NCOH) at room temperature is reported. The lines of △Ms=±...In this paper, single crystal EPR study of a new binuclear copper (Ⅱ) cluster compound-[Cu2(α-C(10) H7CH2CO2)4 (DMF)2]·[DMF]2·H2O](DMF= (CH3)2NCOH) at room temperature is reported. The lines of △Ms=±1 allowing transition and △M=2 forbiding transition are shown in EPR spectra. The experimental data are consistent with the calculated results by the leastsquares fitting prograrn in three principal planes of g and D tensors. The spin Hamiltonian parameters are as follows: gx=2. 1482, gy=2. 0529 ,gz=2. 3905, D= 0. 348 cm￣(-1) and E =0. 01 cm-1. The diagrams of the energy levels have been obtained when the magnetic field is oriented to three principal axes. The polycrystal EPR spectra have been measured at room temperature and 77K, respectively.and the parameters of these spectra are given (g∥= 2. 094, g⊥= 2. 425, D= 0. 37 cm-1,E=0). The parameter of the isotropic magnetic exchange interaction J=-254cm-1 is determined, and that of the anisotropic magnetic exchange J1=-153 cm-1 is calculated. The average magnetic susceptibility of the polycrystal sample χ= 1. 39 ×10-6 (c. g. s) has been measured by Faraday powder method. Thus the average magnetic mornent μ=1. 43 B. M. can be calculated. It is shown that the exchange interactions between the metal ions of the binuclear copper(Ⅱ) cluster compound are confirmed antiferromagnetic In nature.展开更多
A novel compound, (HGly) 4[HPMo 12 O 40 ] 2·22H 2O, was synthesized and characterized by means of elemental analysis, IR and X ray diffraction. The compound crystallized in a monoclinic space group ...A novel compound, (HGly) 4[HPMo 12 O 40 ] 2·22H 2O, was synthesized and characterized by means of elemental analysis, IR and X ray diffraction. The compound crystallized in a monoclinic space group Cc with a =4 0060(0 8) nm, b =1 2527(0 3) nm, c =1 9930(0 4) nm, β =96 36(3)°, V =9 940(3) nm 3, Z =2, R 1=0 0576, wR 2 =0 1746. The anti tumor activity of this compound was tested in two human tumor cell lines in vitro .展开更多
Lijiang-Daju fault, the seismogenic fault of the 1996 Lijiang M=7.0 earthquake, can be divided into Lijiang-Yuhu segment in the south and Yuhu-Daju segment in the north. The two segments show clear difference in geolo...Lijiang-Daju fault, the seismogenic fault of the 1996 Lijiang M=7.0 earthquake, can be divided into Lijiang-Yuhu segment in the south and Yuhu-Daju segment in the north. The two segments show clear difference in geological tectonics, but have the similar dynamic features. Both normal dip-slip and sinistral strike-slip coexist on the fault plane. This kind of movement started at the beginning of the Quaternary (2.4~2.5 Ma B.P.). As to the tectonic types, the detachment fault with low angle was developed in the Early Pleistocene and the normal fault with high angle only after the Mid-Pleistocene (0.8 Ma B.P.). Based on the horizontal displacements of gullies and the vertical variance of planation surfaces cross the Lijiang-Daju fault at east piedmont of Yulong-Haba range, the average horizontal and vertical slip rates are calculated. They are 0.84 mm/a and 0.70 mm/a since the Quaternary and 1.56 mm/a and 1.69 mm/a since the Mid-Pleistocene. The movements of the nearly N-S-trending Lijiang-Daju fault are controlled not only by the regional stress field, but also by the variant movement between the Yulong-Haba range and Lijiang basin. The two kinds of dynamic processes form the characteristics of seismotectonic environment of occurring the 1996 Lijiang earthquake.展开更多
Summary: The efficiency of cold storage red blood cells (CSRBC) or whole blood at -80 ℃ used in 27 Rh(D) negative patients during surgical operation was reported. The Rh(D) negative patients received the transfusion...Summary: The efficiency of cold storage red blood cells (CSRBC) or whole blood at -80 ℃ used in 27 Rh(D) negative patients during surgical operation was reported. The Rh(D) negative patients received the transfusion of CSRBC or whole blood stored at -80 ℃ for 180 to 360 days. The changes in the indexes, such as blood TB, DB, K +, Na +, BUN, Cr, urine protein (URPO), UOB, Hb, HCT, serum total protein, relative to hemolytic reaction and blood volume before and after transfusion were observed. The results showed that after transfusion of CSRBC or whole blood 27 cases were negative for urine protein and UOB, and the levels of BUN and Cr were normal (P>0.05). Blood TB, DB, Hb, and HCT were increased, while pH, blood K + and blood Na + was normal with the difference being not significant before and after operation (P>0.05). Plasma protein was decreased, but there was no significant difference before and after operation (P>0.05). It was suggested that CSRBC or whole blood at -80 ℃ could be safely infused to the Rh(D) negative patients without side effects during the surgical operation.展开更多
Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studi...Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studies. It can disperse easily in epoxy resin to form exfoliated nanocomposites. The nanoscale silicate platelets dispersed in water can be metallized by silver deposition.展开更多
In the paper, nano-hydroxyapatite was synthesized by hydrothermal treatment. The crystal morphology and compositions of the synthetic HA were investigated using TEM, IR, XRD and XPS techniques and were compared with t...In the paper, nano-hydroxyapatite was synthesized by hydrothermal treatment. The crystal morphology and compositions of the synthetic HA were investigated using TEM, IR, XRD and XPS techniques and were compared with those of porcine femoral bone apatite. The results showed that the synthetic HA is nanometer rod crystal similar to the bone apatite, and the average crystal sizes calculated by Scherrer equation for the four samples (HA dried at 80℃, unburned bone apatite, HA calcined at 750℃ and bone apatite calcined at 750℃) are 20.6, 21.7, 22.5 and 27.6nm, respectively. Moreover, the essential compositions for the synthetic HA and bone apatite are almost the same.展开更多
Sampled-data iterative learning control (SILC) for singular systems is addressed for the first time. With the introduction of the constrained relative degree, an SILC algorithm combined with a feedback control law is ...Sampled-data iterative learning control (SILC) for singular systems is addressed for the first time. With the introduction of the constrained relative degree, an SILC algorithm combined with a feedback control law is proposed for singular systems. Convergence of the algorithm is proved in sup-norm, while the conventional convergence analysis is in λ-norm. The final tracking error uniformly converges to a small residual set whose level of magnitude depends on the system dynamics and the sampling-period. Due to inequalities to estimate the level of the existing results of SILC, convergence is guaranteed not only at the sampling instants but on the entire operation interval, so that the inter-sample behavior is guaranteed, which is more practical for real implementation.展开更多
Dear Editor,Bacteriophages(phages)are viruses that specifically infect and kill bacteria.They are ubiquitous throughout all environments that bacteria inhabit.Following their discovery by F.W.Twort in 1915 and F.d’He...Dear Editor,Bacteriophages(phages)are viruses that specifically infect and kill bacteria.They are ubiquitous throughout all environments that bacteria inhabit.Following their discovery by F.W.Twort in 1915 and F.d’Herele in 1917,bacteriophages were recognized as potential agents to treat bacterial diseases and phage therapy has been used展开更多
In 1999 summer, Chinese Arctic Research Expedition operated the Chukchi Sea. On Chinese icebreaker Xuelong, we made many high resolution ozonesonds measurements. During the period from August 18 to 24, a synoptic sca...In 1999 summer, Chinese Arctic Research Expedition operated the Chukchi Sea. On Chinese icebreaker Xuelong, we made many high resolution ozonesonds measurements. During the period from August 18 to 24, a synoptic scale observation was taken at 75°N, 160°W. Using the above data, together with TOMS total ozone and NCEP circulation data, we showed that atmospheric ozone amount experienced a high low high variation, with low high low tropopause altitude. Correlation analysis showed a close relation between the total ozone and ozone below 13 km, while the variation of the maximum concentration at about 20 km didn't show any relation to the column ozone. In 500 hPa height maps, there was also the weak strong weak southwesterly pattern. Therefore we suggested that the synoptic system might be responsible to a low ozone advection during this ozone variation.展开更多
In the paper, the distribution characteristics of strong earthquakes in Sichuan-Yunnan area and their geological tectonic background, especially the relation to Sichuan-Yunnan and Sichuan-Qinghai crustal blocks have b...In the paper, the distribution characteristics of strong earthquakes in Sichuan-Yunnan area and their geological tectonic background, especially the relation to Sichuan-Yunnan and Sichuan-Qinghai crustal blocks have been studied. The main results are: a) Strong earthquakes in Sichuan-Yunnan area distribute mainly in Sichuan-Yunnan and Sichuan-Qinghai crustal blocks; b) Most of strong earthquakes of the two blocks distribute mainly along their boundary faults; c) A few strong earthquakes are not obviously related to active faults. It shows that the relation between strong earthquakes and geological tectonics can be very complex; d) There is a certain correlativity for seismic activities among boundary faults of the two blocks, but they have different features; e) There are some anomalous changes of velocity structures in the deep crust of boundary faults of the two blocks. Many boundary faults, especially Longmenshan fault, cut obviously the Moho discontinuity. The Xianshuihe fault, a typical strike-slip fault, has no obvious indication of cutting the Moho discontinuity, but has distinct low-velocity zone in different depths.展开更多
Objective To observe the effects of chronic emotional stress on the activities of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) and malonialdehyde (MDA) level in female rats’ brain. Methods The rats ...Objective To observe the effects of chronic emotional stress on the activities of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) and malonialdehyde (MDA) level in female rats’ brain. Methods The rats were randomly divided into 4 groups: normal control group (group N), emotional stress group (group E), emotional stress + pregnancy group (group E+P) and regularly drinking group (group R). Emotional stress in rats was induced by training rats with empty drinking bottles. Having been finished the stress procedure, the brain was taken out and homogenized. Then the activities of SOD, GSH-Px and MDA level were measured. Results Compared to group N, both the activities of SOD in brain tissues of group E and group E+P were significantly decreased ( P <0.05 and P <0.01, respectively) while the MDA level increased ( P <0.05). However, the extent of changes in group E+P was more obvious than that in E. GSH-Px activities in E+P and E were significantly changed. However, the GSH-Px activity in E+P was decreased ( P <0.05) while the activity in E increased ( P <0.05).Conclusion The chronic emotional stress can reduce the antioxidative system by decreasing the antioxidative enzyme activity and potentiating the lipid peroxidation in the brain. It is also suggested that the combination of emotional stress and pregnancy can augment the oxidative damage in rats’ brain.展开更多
Bifurcations of subharmonic solutions of order m of a planar periodic perturbed system near a hyperbolic limit cycle are discussed. By using a Poincare map and the method of rescaling a discriminating condition for th...Bifurcations of subharmonic solutions of order m of a planar periodic perturbed system near a hyperbolic limit cycle are discussed. By using a Poincare map and the method of rescaling a discriminating condition for the existence of subharmonic solutions of order m is obtained. An example is given in the end of the paper.展开更多
文摘In this paper, single crystal EPR study of a new binuclear copper (Ⅱ) cluster compound-[Cu2(α-C(10) H7CH2CO2)4 (DMF)2]·[DMF]2·H2O](DMF= (CH3)2NCOH) at room temperature is reported. The lines of △Ms=±1 allowing transition and △M=2 forbiding transition are shown in EPR spectra. The experimental data are consistent with the calculated results by the leastsquares fitting prograrn in three principal planes of g and D tensors. The spin Hamiltonian parameters are as follows: gx=2. 1482, gy=2. 0529 ,gz=2. 3905, D= 0. 348 cm￣(-1) and E =0. 01 cm-1. The diagrams of the energy levels have been obtained when the magnetic field is oriented to three principal axes. The polycrystal EPR spectra have been measured at room temperature and 77K, respectively.and the parameters of these spectra are given (g∥= 2. 094, g⊥= 2. 425, D= 0. 37 cm-1,E=0). The parameter of the isotropic magnetic exchange interaction J=-254cm-1 is determined, and that of the anisotropic magnetic exchange J1=-153 cm-1 is calculated. The average magnetic susceptibility of the polycrystal sample χ= 1. 39 ×10-6 (c. g. s) has been measured by Faraday powder method. Thus the average magnetic mornent μ=1. 43 B. M. can be calculated. It is shown that the exchange interactions between the metal ions of the binuclear copper(Ⅱ) cluster compound are confirmed antiferromagnetic In nature.
基金Supported by National Natural Science Foundation of China(No.2 0 1710 10 ) .
文摘A novel compound, (HGly) 4[HPMo 12 O 40 ] 2·22H 2O, was synthesized and characterized by means of elemental analysis, IR and X ray diffraction. The compound crystallized in a monoclinic space group Cc with a =4 0060(0 8) nm, b =1 2527(0 3) nm, c =1 9930(0 4) nm, β =96 36(3)°, V =9 940(3) nm 3, Z =2, R 1=0 0576, wR 2 =0 1746. The anti tumor activity of this compound was tested in two human tumor cell lines in vitro .
基金Joint Seismological Science Foundation of China (198023) and National Natural Science Foundation (40272087).
文摘Lijiang-Daju fault, the seismogenic fault of the 1996 Lijiang M=7.0 earthquake, can be divided into Lijiang-Yuhu segment in the south and Yuhu-Daju segment in the north. The two segments show clear difference in geological tectonics, but have the similar dynamic features. Both normal dip-slip and sinistral strike-slip coexist on the fault plane. This kind of movement started at the beginning of the Quaternary (2.4~2.5 Ma B.P.). As to the tectonic types, the detachment fault with low angle was developed in the Early Pleistocene and the normal fault with high angle only after the Mid-Pleistocene (0.8 Ma B.P.). Based on the horizontal displacements of gullies and the vertical variance of planation surfaces cross the Lijiang-Daju fault at east piedmont of Yulong-Haba range, the average horizontal and vertical slip rates are calculated. They are 0.84 mm/a and 0.70 mm/a since the Quaternary and 1.56 mm/a and 1.69 mm/a since the Mid-Pleistocene. The movements of the nearly N-S-trending Lijiang-Daju fault are controlled not only by the regional stress field, but also by the variant movement between the Yulong-Haba range and Lijiang basin. The two kinds of dynamic processes form the characteristics of seismotectonic environment of occurring the 1996 Lijiang earthquake.
文摘Summary: The efficiency of cold storage red blood cells (CSRBC) or whole blood at -80 ℃ used in 27 Rh(D) negative patients during surgical operation was reported. The Rh(D) negative patients received the transfusion of CSRBC or whole blood stored at -80 ℃ for 180 to 360 days. The changes in the indexes, such as blood TB, DB, K +, Na +, BUN, Cr, urine protein (URPO), UOB, Hb, HCT, serum total protein, relative to hemolytic reaction and blood volume before and after transfusion were observed. The results showed that after transfusion of CSRBC or whole blood 27 cases were negative for urine protein and UOB, and the levels of BUN and Cr were normal (P>0.05). Blood TB, DB, Hb, and HCT were increased, while pH, blood K + and blood Na + was normal with the difference being not significant before and after operation (P>0.05). Plasma protein was decreased, but there was no significant difference before and after operation (P>0.05). It was suggested that CSRBC or whole blood at -80 ℃ could be safely infused to the Rh(D) negative patients without side effects during the surgical operation.
文摘Montmorillonite (MMT) was modified through intercalative polymerization of phenol and formaldehyde catalyzed by oxalic acid. The modified montmorillonite was delaminated at large, as demonstrated by XRD and TEM studies. It can disperse easily in epoxy resin to form exfoliated nanocomposites. The nanoscale silicate platelets dispersed in water can be metallized by silver deposition.
文摘In the paper, nano-hydroxyapatite was synthesized by hydrothermal treatment. The crystal morphology and compositions of the synthetic HA were investigated using TEM, IR, XRD and XPS techniques and were compared with those of porcine femoral bone apatite. The results showed that the synthetic HA is nanometer rod crystal similar to the bone apatite, and the average crystal sizes calculated by Scherrer equation for the four samples (HA dried at 80℃, unburned bone apatite, HA calcined at 750℃ and bone apatite calcined at 750℃) are 20.6, 21.7, 22.5 and 27.6nm, respectively. Moreover, the essential compositions for the synthetic HA and bone apatite are almost the same.
文摘Sampled-data iterative learning control (SILC) for singular systems is addressed for the first time. With the introduction of the constrained relative degree, an SILC algorithm combined with a feedback control law is proposed for singular systems. Convergence of the algorithm is proved in sup-norm, while the conventional convergence analysis is in λ-norm. The final tracking error uniformly converges to a small residual set whose level of magnitude depends on the system dynamics and the sampling-period. Due to inequalities to estimate the level of the existing results of SILC, convergence is guaranteed not only at the sampling instants but on the entire operation interval, so that the inter-sample behavior is guaranteed, which is more practical for real implementation.
基金supported by the Jilin Industrial Technology Research and Development Projects (Grant number: 2013C015-2)Jilin high tech industry development project
文摘Dear Editor,Bacteriophages(phages)are viruses that specifically infect and kill bacteria.They are ubiquitous throughout all environments that bacteria inhabit.Following their discovery by F.W.Twort in 1915 and F.d’Herele in 1917,bacteriophages were recognized as potential agents to treat bacterial diseases and phage therapy has been used
基金This work was supported by the National Natural Science Foundation of China (40075029) and Institute of Atmospheric Physics, Chinese Academy of Sciences (8 2212). We would like to thank the data providers, TOMS data processing team at Godard Flight Center, NASA, NCAR/NCEP, and Chinese Arctic Expedition 1999, National Ocean Administration of China. In addition, authors give great appreciation to Mr. Wang Wei's data collecting work in the Chinese Arctic Expedition 1999.
文摘In 1999 summer, Chinese Arctic Research Expedition operated the Chukchi Sea. On Chinese icebreaker Xuelong, we made many high resolution ozonesonds measurements. During the period from August 18 to 24, a synoptic scale observation was taken at 75°N, 160°W. Using the above data, together with TOMS total ozone and NCEP circulation data, we showed that atmospheric ozone amount experienced a high low high variation, with low high low tropopause altitude. Correlation analysis showed a close relation between the total ozone and ozone below 13 km, while the variation of the maximum concentration at about 20 km didn't show any relation to the column ozone. In 500 hPa height maps, there was also the weak strong weak southwesterly pattern. Therefore we suggested that the synoptic system might be responsible to a low ozone advection during this ozone variation.
文摘In the paper, the distribution characteristics of strong earthquakes in Sichuan-Yunnan area and their geological tectonic background, especially the relation to Sichuan-Yunnan and Sichuan-Qinghai crustal blocks have been studied. The main results are: a) Strong earthquakes in Sichuan-Yunnan area distribute mainly in Sichuan-Yunnan and Sichuan-Qinghai crustal blocks; b) Most of strong earthquakes of the two blocks distribute mainly along their boundary faults; c) A few strong earthquakes are not obviously related to active faults. It shows that the relation between strong earthquakes and geological tectonics can be very complex; d) There is a certain correlativity for seismic activities among boundary faults of the two blocks, but they have different features; e) There are some anomalous changes of velocity structures in the deep crust of boundary faults of the two blocks. Many boundary faults, especially Longmenshan fault, cut obviously the Moho discontinuity. The Xianshuihe fault, a typical strike-slip fault, has no obvious indication of cutting the Moho discontinuity, but has distinct low-velocity zone in different depths.
文摘Objective To observe the effects of chronic emotional stress on the activities of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) and malonialdehyde (MDA) level in female rats’ brain. Methods The rats were randomly divided into 4 groups: normal control group (group N), emotional stress group (group E), emotional stress + pregnancy group (group E+P) and regularly drinking group (group R). Emotional stress in rats was induced by training rats with empty drinking bottles. Having been finished the stress procedure, the brain was taken out and homogenized. Then the activities of SOD, GSH-Px and MDA level were measured. Results Compared to group N, both the activities of SOD in brain tissues of group E and group E+P were significantly decreased ( P <0.05 and P <0.01, respectively) while the MDA level increased ( P <0.05). However, the extent of changes in group E+P was more obvious than that in E. GSH-Px activities in E+P and E were significantly changed. However, the GSH-Px activity in E+P was decreased ( P <0.05) while the activity in E increased ( P <0.05).Conclusion The chronic emotional stress can reduce the antioxidative system by decreasing the antioxidative enzyme activity and potentiating the lipid peroxidation in the brain. It is also suggested that the combination of emotional stress and pregnancy can augment the oxidative damage in rats’ brain.
文摘Bifurcations of subharmonic solutions of order m of a planar periodic perturbed system near a hyperbolic limit cycle are discussed. By using a Poincare map and the method of rescaling a discriminating condition for the existence of subharmonic solutions of order m is obtained. An example is given in the end of the paper.
