With the completion of Chinese BeiDou Navigation Satellite System(BDS),the world has begun to enjoy the Positioning,Navigation,and Timing(PNT)services of four Global Navigation Satellite Systems(GNSS).In order to impr...With the completion of Chinese BeiDou Navigation Satellite System(BDS),the world has begun to enjoy the Positioning,Navigation,and Timing(PNT)services of four Global Navigation Satellite Systems(GNSS).In order to improve the GNSS performance and expand its applications,Low Earth Orbit(LEO)Enhanced Global Navigation Satellite System(LeGNSS)is being vigorously advocated.Combined with high-,medium-,and low-earth orbit satellites,it can improve GNSS performance in terms of orbit determination,Precise Point Positioning(PPP)convergence time,etc.This paper comprehensively reviews the current status of LeGNSS,focusing on analyzing its advantages and challenges for precise orbit and clock determination,PPP convergence,earth rotation parameter estimation,and global ionosphere modeling.Thanks to the fast geometric change brought by LEO satellites,LeGNSS is expected to fundamentally solve the problem of the long convergence time of PPP without any augmentation.The convergence time can be shortened within 1 minute if appropriate LEO constellations are deployed.However,there are still some issues to overcome,such as the optimization of LEO constellation as well as the real time LEO precise orbit and clock determination.展开更多
The recruitment of the Low Earth Orbit(LEO)constellation is recognized as an effective way to augment Global Navigation Satellite System(GNSS)Precise Point Positioning(PPP)in the near future.Its potential to accelerat...The recruitment of the Low Earth Orbit(LEO)constellation is recognized as an effective way to augment Global Navigation Satellite System(GNSS)Precise Point Positioning(PPP)in the near future.Its potential to accelerate PPP convergence has been proved with simulated data.However,the mechanism of how the geometric change of LEO accelerates the convergence of GNSS PPP has not been studied from a theoretical perspective,which hampers the understanding and exploitation of the enhancement of LEO.In this article,the convergence mechanism of LEO enhanced GNSS PPP is investigated in terms of theoretical analysis and simulated verification.To show the characteristics of the ambiguities during convergence,eigenvalue decomposition is used to divide the ambiguities into orthogonal components,named geometric-related component,clock-error-related component,and independent component.The results show that the precision of geometric-related components of ambiguities,which correlates with position parameters,is low at a single epoch,while the precision can be greatly improved with the fast geometric change of LEO.On the other hand,the precision of clock-error-related components of ambiguities,which correlates with clock errors,cannot be improved by fast geometric change of LEO constellation due to its irrelevance to geometry,which causes the precision of each ambiguity to be low.Further investigations show that single-differenced ambiguities could overcome this drawback and are beneficial to ambiguity resolution.展开更多
Real-Time Precise Point Positioning(RT-PPP)has been one of the research hotspots in GNSS(Global Navigation Satellite System)community for decades.Real-time precise products of satellite orbits and clocks are the prere...Real-Time Precise Point Positioning(RT-PPP)has been one of the research hotspots in GNSS(Global Navigation Satellite System)community for decades.Real-time precise products of satellite orbits and clocks are the prerequisite for RT-PPP.Thus,it is of great importance to investigate the current multi-GNSS real-time precise products in State Space Representation(SSR)from diferent analysis centers.In this article,SSR products from 10 analysis centers are comprehensively evaluated by comparing them with the fnal products and performing the kinematic PPP.The results show that analysis centers CNES(Centre National D’Etudes Spatiales)and WHU(GNSS Research Center of Wuhan University)provide the most complete products with the best quality.Concerning the accuracy of real-time products for the GNSSs,the accuracies of orbit and clock products are better than 5 cm and 0.15 ns,respectively,for Global Positioning System(GPS),followed by Galileo navigation satellite system(Galileo),BeiDou-3 Navigation Satellite System(BDS-3),GLObal NAvigation Satellite System(GLONASS),and BeiDou-2 Navigation Satellite System(BDS-2).Meanwhile,the results of the RT-PPP with quad-system show that the positioning accuracies are 1.76,1.12 and 2.68 cm in east,north,and up directions,respectively,and the convergence time to 0.1,0.1,0.2 m for corresponding directions is 15.35 min.展开更多
Li ions affect the upconversion efficiency by changing the local crystal field of the luminescent center. Herein, in order to improve the upconversion efficiency of NaYF4:Yb3+/Eu3+, a series of NaYF4:Yb3+/Eu3+micro-pa...Li ions affect the upconversion efficiency by changing the local crystal field of the luminescent center. Herein, in order to improve the upconversion efficiency of NaYF4:Yb3+/Eu3+, a series of NaYF4:Yb3+/Eu3+micro-particles with different Li+doping concentrations were synthesized by the hydrothermal synthesis method, respectively.Firstly, the structure and morphology of NaYF4:Yb3+/Eu3+upconversion micro-particles(UCMPs) with different doping concentrations were analyzed by X-ray diffraction and a scanning electron microscope(SEM). SEM results show that the UCMPs are not only highly crystallized, but also have hexagons with different Li+concentrations of NaYF4:Yb3+/Eu3+. X-ray diffraction shows that the crystal field around Eu3+changes with the increase of Li+concentration. Then, the fluorescence spectrum of NaYF4:Yb3+/Eu3+was studied under the irradiation of a 980 nm laser. The results show that the fluorescence intensity of NaYF4:Yb3+/Eu3+with2% Li+is the strongest, which is twice the intensity of NaYF4:Yb3+/Eu3+without Li+. Finally, the fluorescence imaging analysis of NaYF4:Yb3+/Eu3+with 2% Li+concentration was carried out. The UCMPs are used to screen printing to evaluate the imaging effect on different sample surfaces. The results show NaYF4:Yb3+/Eu3+(with 2% Li+) has great application prospects in anti-counterfeiting recognition.展开更多
Thioether skeletons are widely present in drugs,natural products,functional materials,and life science.In the past decade,the selective C–H functionalization of thioethers has been extensively studied to construct no...Thioether skeletons are widely present in drugs,natural products,functional materials,and life science.In the past decade,the selective C–H functionalization of thioethers has been extensively studied to construct novel thioether derivatives.This mini-review systematically introduces the recent advances in the field of the directα-C(sp^(3))-H functionalization of thioethers.展开更多
基金the National Natural Science Funds of China[grant numbers 41874030,42074026]Natural Science Funds of Shanghai[grant number 21ZR1465600]+3 种基金the Program of Shanghai Academic Research Leader[grant number 20XD1423800]the Innovation Program of Shanghai Municipal Education Commission[grant number 2021-01-07-00-07-E00095]the“Shuguang Program”supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission[grant number 20SG18]the Scientific and Technological Innovation Plan from Shanghai Science and Technology Committee[grant numbers 20511103302,20511103402 and 20511103702].
文摘With the completion of Chinese BeiDou Navigation Satellite System(BDS),the world has begun to enjoy the Positioning,Navigation,and Timing(PNT)services of four Global Navigation Satellite Systems(GNSS).In order to improve the GNSS performance and expand its applications,Low Earth Orbit(LEO)Enhanced Global Navigation Satellite System(LeGNSS)is being vigorously advocated.Combined with high-,medium-,and low-earth orbit satellites,it can improve GNSS performance in terms of orbit determination,Precise Point Positioning(PPP)convergence time,etc.This paper comprehensively reviews the current status of LeGNSS,focusing on analyzing its advantages and challenges for precise orbit and clock determination,PPP convergence,earth rotation parameter estimation,and global ionosphere modeling.Thanks to the fast geometric change brought by LEO satellites,LeGNSS is expected to fundamentally solve the problem of the long convergence time of PPP without any augmentation.The convergence time can be shortened within 1 minute if appropriate LEO constellations are deployed.However,there are still some issues to overcome,such as the optimization of LEO constellation as well as the real time LEO precise orbit and clock determination.
基金supported by the National Natural Science Funds of China[grant numbers 42104013 and 42225401]the Innovation Program of Shanghai Municipal Education Commission[grant number 2021-01-07-00-07-E00095]+3 种基金Natural Science Fund of Shanghai[grant number 21ZR1465600]the Scientific and Technological Innovation Plan from Shanghai Science and Technology Committee[grant numbers 21511103902 and 22511103003]the industrial Collaborative Innovation Project(Technology)of Shanghai Municipality[grant numbers XTCX-KJ-2023-35 and XTCX-KJ-2022-09]the Fundamental Research Funds for the Central Universities.
文摘The recruitment of the Low Earth Orbit(LEO)constellation is recognized as an effective way to augment Global Navigation Satellite System(GNSS)Precise Point Positioning(PPP)in the near future.Its potential to accelerate PPP convergence has been proved with simulated data.However,the mechanism of how the geometric change of LEO accelerates the convergence of GNSS PPP has not been studied from a theoretical perspective,which hampers the understanding and exploitation of the enhancement of LEO.In this article,the convergence mechanism of LEO enhanced GNSS PPP is investigated in terms of theoretical analysis and simulated verification.To show the characteristics of the ambiguities during convergence,eigenvalue decomposition is used to divide the ambiguities into orthogonal components,named geometric-related component,clock-error-related component,and independent component.The results show that the precision of geometric-related components of ambiguities,which correlates with position parameters,is low at a single epoch,while the precision can be greatly improved with the fast geometric change of LEO.On the other hand,the precision of clock-error-related components of ambiguities,which correlates with clock errors,cannot be improved by fast geometric change of LEO constellation due to its irrelevance to geometry,which causes the precision of each ambiguity to be low.Further investigations show that single-differenced ambiguities could overcome this drawback and are beneficial to ambiguity resolution.
基金supported by the National Natural Science Funds of China(41874030,42074026,42104013)Natural Science Fund of Shanghai(21ZR1465600)+3 种基金the Program of Shanghai Academic Research Leader(20XD1423800)the Innovation Program of Shanghai Municipal Education Commission(2021-01-07-00-07-E00095)the“Shuguang Program”supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission(20SG18)the Scientifc and Technological Innovation Plan from Shanghai Science and Technology Committee(20511103302,20511103402 and 20511103702).
文摘Real-Time Precise Point Positioning(RT-PPP)has been one of the research hotspots in GNSS(Global Navigation Satellite System)community for decades.Real-time precise products of satellite orbits and clocks are the prerequisite for RT-PPP.Thus,it is of great importance to investigate the current multi-GNSS real-time precise products in State Space Representation(SSR)from diferent analysis centers.In this article,SSR products from 10 analysis centers are comprehensively evaluated by comparing them with the fnal products and performing the kinematic PPP.The results show that analysis centers CNES(Centre National D’Etudes Spatiales)and WHU(GNSS Research Center of Wuhan University)provide the most complete products with the best quality.Concerning the accuracy of real-time products for the GNSSs,the accuracies of orbit and clock products are better than 5 cm and 0.15 ns,respectively,for Global Positioning System(GPS),followed by Galileo navigation satellite system(Galileo),BeiDou-3 Navigation Satellite System(BDS-3),GLObal NAvigation Satellite System(GLONASS),and BeiDou-2 Navigation Satellite System(BDS-2).Meanwhile,the results of the RT-PPP with quad-system show that the positioning accuracies are 1.76,1.12 and 2.68 cm in east,north,and up directions,respectively,and the convergence time to 0.1,0.1,0.2 m for corresponding directions is 15.35 min.
基金supported by the National Natural Science Foundation of China (No. 61805198)the Special Research Projects of Department of Education of Shaanxi Province (No. 18JK0707)。
文摘Li ions affect the upconversion efficiency by changing the local crystal field of the luminescent center. Herein, in order to improve the upconversion efficiency of NaYF4:Yb3+/Eu3+, a series of NaYF4:Yb3+/Eu3+micro-particles with different Li+doping concentrations were synthesized by the hydrothermal synthesis method, respectively.Firstly, the structure and morphology of NaYF4:Yb3+/Eu3+upconversion micro-particles(UCMPs) with different doping concentrations were analyzed by X-ray diffraction and a scanning electron microscope(SEM). SEM results show that the UCMPs are not only highly crystallized, but also have hexagons with different Li+concentrations of NaYF4:Yb3+/Eu3+. X-ray diffraction shows that the crystal field around Eu3+changes with the increase of Li+concentration. Then, the fluorescence spectrum of NaYF4:Yb3+/Eu3+was studied under the irradiation of a 980 nm laser. The results show that the fluorescence intensity of NaYF4:Yb3+/Eu3+with2% Li+is the strongest, which is twice the intensity of NaYF4:Yb3+/Eu3+without Li+. Finally, the fluorescence imaging analysis of NaYF4:Yb3+/Eu3+with 2% Li+concentration was carried out. The UCMPs are used to screen printing to evaluate the imaging effect on different sample surfaces. The results show NaYF4:Yb3+/Eu3+(with 2% Li+) has great application prospects in anti-counterfeiting recognition.
基金support from the National Natural Science Foundation of China(NSFC,No.21702019)and Advanced Catalysis and Green Manufacturing Collaborative Innovation Center,Changzhou UniversityHaibo Ge,Mazen Elsaid and Chong Liu acknowledge NSF(No.CHE-2029932),Robert A.Welch Foundation(No.D-2034-20200401),and the Texas Tech University for financial support.
文摘Thioether skeletons are widely present in drugs,natural products,functional materials,and life science.In the past decade,the selective C–H functionalization of thioethers has been extensively studied to construct novel thioether derivatives.This mini-review systematically introduces the recent advances in the field of the directα-C(sp^(3))-H functionalization of thioethers.
