We employed oxygen plasma treatment to activate the PTFE surface and introduce oxygencontaining polar groups(-OH,C-O,C=O),thereby enhancing surface energy and interfacial reactivity.We subsequently composited the modi...We employed oxygen plasma treatment to activate the PTFE surface and introduce oxygencontaining polar groups(-OH,C-O,C=O),thereby enhancing surface energy and interfacial reactivity.We subsequently composited the modified PTFE(PTFE-O)with graphene oxide(GO),enabling tight interactions between the two phases through hydrogen bonding and van der Waals forces.Comprehensive characterizations,including XPS,FTIR,SEM,and contact angle analysis,confirmed the successful surface modification and uniform dispersion of GO.The optimized PTFE-O/GO composite exhibits a low resistivity of 2.41×10^(3)Ω·cm under a compression pressure of 2 MPa,demonstrating markedly improved conductivity and antistatic performance.These findings provide an effective route for constructing conductive PTFE-based composites and offer new insights into interface-engineered antistatic polymer materials.展开更多
基金Funded by the Key Scientific and Technological Project of Zhejiang Provincial Administration for Market Regulation(No.ZD2024004)the National Natural Science Foundation of China(Nos.62304214 and 62304213)+2 种基金the Natural Science Foundation of Zhejiang Province(No.LQ23E020006)the Chunhui Project Foun-dation of the Education Department of China(No.HZKY20220198)the Fundamental Research Funds for the Provincial Universities of Zhejiang(Nos.2021YW35,2021YW36 and 2022YW62)。
文摘We employed oxygen plasma treatment to activate the PTFE surface and introduce oxygencontaining polar groups(-OH,C-O,C=O),thereby enhancing surface energy and interfacial reactivity.We subsequently composited the modified PTFE(PTFE-O)with graphene oxide(GO),enabling tight interactions between the two phases through hydrogen bonding and van der Waals forces.Comprehensive characterizations,including XPS,FTIR,SEM,and contact angle analysis,confirmed the successful surface modification and uniform dispersion of GO.The optimized PTFE-O/GO composite exhibits a low resistivity of 2.41×10^(3)Ω·cm under a compression pressure of 2 MPa,demonstrating markedly improved conductivity and antistatic performance.These findings provide an effective route for constructing conductive PTFE-based composites and offer new insights into interface-engineered antistatic polymer materials.