We investigated the plasmon-exciton interactions in an individual gold nanorod(GNR)with monolayer MoS2 at room temperature with the single-particle spectroscopy technique.To control the plasmon-exciton interaction,we ...We investigated the plasmon-exciton interactions in an individual gold nanorod(GNR)with monolayer MoS2 at room temperature with the single-particle spectroscopy technique.To control the plasmon-exciton interaction,we tuned the local surface plasmon resonance of an individual GNR in-situ by employing the photothermal reshaping effect.The scattering spectra of the GNR-MoS2 hybrids exhibited two dips at the frequencies of the A and B excitons of monolayer MoS2,which were caused by the plasmon-induced resonance energy transfer effect.The resonance energy transfer rate increased when the surface plasmon resonance of the nanorod matched well with the exciton transition energy.Also,we demonstrated that the plasmon-enhanced fluorescence process dominated the photoluminescence of the GNR-MoS2 hybrid.These results provide a flexible way to control the plasmon-exciton interaction in an all-solid-state operating system at room temperature.展开更多
To have effective water resource management,the distributed hydrological models are commonly applied for supporting the decision-making processes.Among different inputs,the spatial distributed rainfall plays significa...To have effective water resource management,the distributed hydrological models are commonly applied for supporting the decision-making processes.Among different inputs,the spatial distributed rainfall plays significant role in those model simulations.Many interpolation methods have been developed for generating distributed rainfall based on measurement samples.However,depending on the catchment characteristics and data availability,the suitable interpolation algorithm is case-dependent.This paper presents one operational approach for determining the resonable interpolation algorithm in a complex large catchment(Var catchment,France).Based on the daily rainfall data(2008–2014)collected from 16 stations in the Var catchment,six different interpolation approaches including:inverse distance weight(IDW),spline,kriging with linear and spherical semi-variogram models and geographically weighted regression considering elevation effects and the combined impacts of elevation and distance to the sea were tested.Integrated the results of statistical and modeling assessments,the 400m resolution distributed rainfall generated by IDW algorithm shows high preference in generating distributed rainfall in the Var catchment.Moreover,the strategy described in the article also shows promising acceptability for other catchments.展开更多
The properties of high entropy pyrochlore have been studied extensively,but there is no consistent conclusion on its radiation tolerance.Besides,the mechanism of the high entropy effect on the radiation tolerance of p...The properties of high entropy pyrochlore have been studied extensively,but there is no consistent conclusion on its radiation tolerance.Besides,the mechanism of the high entropy effect on the radiation tolerance of pyrochlore is still unclear.In this work,combined with experiments and calculations of pyrochlores with similar cationic radius ratios,the A-site and B-site high entropy effects on structural evolution under irradiation are analyzed.In situ irradiation experiments were carried out on A-site high entropy pyrochlores such as(La_(0.2)Nd_(0.2)Sm_(0.2)Gd_(0.2)Er_(0.2))_(2)Zr_(2)O_(7),B-site Gd_(2)(Ti_(1/3)Sn_(1/3)Zr_(1/3))_(2)O_(7),and ternary pyrochlore Sm_(2)Zr_(2)O_(7) and Gd_(2)Sn_(2)O_(7) for comparison.The A-site high entropy pyrochlore can maintain a stable structure under high fluence irradiation like corresponding ternary pyrochlore,demonstrated by high angle annular dark field scanning transmission electron microscopy(HAADF-STEM),energy dispersive spectroscopy(EDS)mapping and Raman spectrum.The additional irradiation experiments on A-site high entropy pyrochlores(La_(1/3)Nd_(1/3)Gd_(1/3))_(2)Zr_(2)O_(7) and(Nd_(1/3)Sm_(1/3)Gd_(1/3))_(2)Zr_(2)O_(7) also confirm the similarity under irradiation between A-site high entropy and ternary pyrochlores.However,the B-site high entropy pyrochlore Gd_(2)(Ti_(1/3)Sn_(1/3)Zr_(1/3))_(2)O_(7) becomes amorphous at exceptionally low irradiation fluences,indicating a significantly distinct radiation tolerance compared with the A-site high entropy.The difference between the A-site and B-site high entropy effect is analyzed from cationic lattice distortion,bond strength,and inner electron binding energy by first-principles calculations.The results reveal the role and mechanism of the high entropy effect in pyrochlores and lay a foundation for material design and future applications.展开更多
Singularities in the spectra of open systems, known as exceptional points(EPs), have been shown to exhibit nontrivial topological properties and enhanced sensitivities. Here, we propose a novel approach to realize the...Singularities in the spectra of open systems, known as exceptional points(EPs), have been shown to exhibit nontrivial topological properties and enhanced sensitivities. Here, we propose a novel approach to realize the EPs in a plasmon-exciton hybrid system and explore their applications in enhanced nanoscale sensing technology.We consider a plasmon-exciton system composed of a gold nanorod and a monolayer WSe_(2). By controlling the geometric parameters of the nano-hybrid system, we obtain simultaneous coalescence of the resonance frequencies and loss rates of the hybrid system, which is a unique feature of EPs. Numerical simulations show its application in enhanced nanoscale sensing for environmental refractive indices. Our work opens the way to a new class of sensors based on EP-enhanced sensing, with intrinsic nanoscale sensitivity due to the sub-diffractionlimit size of the plasmon-exciton nano-hybrid system.展开更多
Solid-state high-order harmonic generation(HHG)presents a promising approach for achieving controllable broadband coherent light sources and dynamically detecting materials.In this study,we demonstrate the alloptical ...Solid-state high-order harmonic generation(HHG)presents a promising approach for achieving controllable broadband coherent light sources and dynamically detecting materials.In this study,we demonstrate the alloptical control of HHG in a strongly correlated system,vanadium dioxide(VO2),through photo-carrier doping.It has been discovered that HHG can be efficiently modified using a pump laser,achieving modulation depths approaching 100%(extinction ratio≥40 dB)on femtosecond timescales.Quantitative analysis reveals that the driving forces behind pump-dependent HHG are attributed to two distinct many-body dynamics:the scatteringinduced dephasing and the insulator-to-metal transition(IMT)caused by photo-induced electron shielding.These two dynamics play a crucial role in defining the intensity and transient response of the HHG.Furthermore,we demonstrate that it is possible to quantitatively extract the metallic phase fraction from time-resolved HHG(tr-HHG)signals throughout the IMT.This study highlights the benefits of utilizing many-body dynamics for controlling HHG and underscores the necessity for further theoretical research on HHG in strongly correlated systems.展开更多
基金This work was supported by the National Key Research and Development Program of China(grant No.2018YFB2200401)the National Natural Science Foundation of China(grant Nos.91950111,61521004 and 11527901).
文摘We investigated the plasmon-exciton interactions in an individual gold nanorod(GNR)with monolayer MoS2 at room temperature with the single-particle spectroscopy technique.To control the plasmon-exciton interaction,we tuned the local surface plasmon resonance of an individual GNR in-situ by employing the photothermal reshaping effect.The scattering spectra of the GNR-MoS2 hybrids exhibited two dips at the frequencies of the A and B excitons of monolayer MoS2,which were caused by the plasmon-induced resonance energy transfer effect.The resonance energy transfer rate increased when the surface plasmon resonance of the nanorod matched well with the exciton transition energy.Also,we demonstrated that the plasmon-enhanced fluorescence process dominated the photoluminescence of the GNR-MoS2 hybrid.These results provide a flexible way to control the plasmon-exciton interaction in an all-solid-state operating system at room temperature.
基金National Key Research and Development Program of China,Grant/Award Number:2023YFC3006702。
文摘To have effective water resource management,the distributed hydrological models are commonly applied for supporting the decision-making processes.Among different inputs,the spatial distributed rainfall plays significant role in those model simulations.Many interpolation methods have been developed for generating distributed rainfall based on measurement samples.However,depending on the catchment characteristics and data availability,the suitable interpolation algorithm is case-dependent.This paper presents one operational approach for determining the resonable interpolation algorithm in a complex large catchment(Var catchment,France).Based on the daily rainfall data(2008–2014)collected from 16 stations in the Var catchment,six different interpolation approaches including:inverse distance weight(IDW),spline,kriging with linear and spherical semi-variogram models and geographically weighted regression considering elevation effects and the combined impacts of elevation and distance to the sea were tested.Integrated the results of statistical and modeling assessments,the 400m resolution distributed rainfall generated by IDW algorithm shows high preference in generating distributed rainfall in the Var catchment.Moreover,the strategy described in the article also shows promising acceptability for other catchments.
基金supported by the National Natural Science Foundation of China(Grant Nos.12275009,12192280,and 11935004)the National Magnetic Confinement Fusion Energy Research Project(No.2021YFE031100).
文摘The properties of high entropy pyrochlore have been studied extensively,but there is no consistent conclusion on its radiation tolerance.Besides,the mechanism of the high entropy effect on the radiation tolerance of pyrochlore is still unclear.In this work,combined with experiments and calculations of pyrochlores with similar cationic radius ratios,the A-site and B-site high entropy effects on structural evolution under irradiation are analyzed.In situ irradiation experiments were carried out on A-site high entropy pyrochlores such as(La_(0.2)Nd_(0.2)Sm_(0.2)Gd_(0.2)Er_(0.2))_(2)Zr_(2)O_(7),B-site Gd_(2)(Ti_(1/3)Sn_(1/3)Zr_(1/3))_(2)O_(7),and ternary pyrochlore Sm_(2)Zr_(2)O_(7) and Gd_(2)Sn_(2)O_(7) for comparison.The A-site high entropy pyrochlore can maintain a stable structure under high fluence irradiation like corresponding ternary pyrochlore,demonstrated by high angle annular dark field scanning transmission electron microscopy(HAADF-STEM),energy dispersive spectroscopy(EDS)mapping and Raman spectrum.The additional irradiation experiments on A-site high entropy pyrochlores(La_(1/3)Nd_(1/3)Gd_(1/3))_(2)Zr_(2)O_(7) and(Nd_(1/3)Sm_(1/3)Gd_(1/3))_(2)Zr_(2)O_(7) also confirm the similarity under irradiation between A-site high entropy and ternary pyrochlores.However,the B-site high entropy pyrochlore Gd_(2)(Ti_(1/3)Sn_(1/3)Zr_(1/3))_(2)O_(7) becomes amorphous at exceptionally low irradiation fluences,indicating a significantly distinct radiation tolerance compared with the A-site high entropy.The difference between the A-site and B-site high entropy effect is analyzed from cationic lattice distortion,bond strength,and inner electron binding energy by first-principles calculations.The results reveal the role and mechanism of the high entropy effect in pyrochlores and lay a foundation for material design and future applications.
基金National Key Research and Development Program of China (2018YFB2200401)National Natural Science Foundation of China (11527901, 11974031,12174009, 61521004, 91950111)。
文摘Singularities in the spectra of open systems, known as exceptional points(EPs), have been shown to exhibit nontrivial topological properties and enhanced sensitivities. Here, we propose a novel approach to realize the EPs in a plasmon-exciton hybrid system and explore their applications in enhanced nanoscale sensing technology.We consider a plasmon-exciton system composed of a gold nanorod and a monolayer WSe_(2). By controlling the geometric parameters of the nano-hybrid system, we obtain simultaneous coalescence of the resonance frequencies and loss rates of the hybrid system, which is a unique feature of EPs. Numerical simulations show its application in enhanced nanoscale sensing for environmental refractive indices. Our work opens the way to a new class of sensors based on EP-enhanced sensing, with intrinsic nanoscale sensitivity due to the sub-diffractionlimit size of the plasmon-exciton nano-hybrid system.
基金National Key Research and Development Program of China(2022YFA1604301,2023YFA1406801)National Natural Science Foundation of China(12174011,12404393,92250305).
文摘Solid-state high-order harmonic generation(HHG)presents a promising approach for achieving controllable broadband coherent light sources and dynamically detecting materials.In this study,we demonstrate the alloptical control of HHG in a strongly correlated system,vanadium dioxide(VO2),through photo-carrier doping.It has been discovered that HHG can be efficiently modified using a pump laser,achieving modulation depths approaching 100%(extinction ratio≥40 dB)on femtosecond timescales.Quantitative analysis reveals that the driving forces behind pump-dependent HHG are attributed to two distinct many-body dynamics:the scatteringinduced dephasing and the insulator-to-metal transition(IMT)caused by photo-induced electron shielding.These two dynamics play a crucial role in defining the intensity and transient response of the HHG.Furthermore,we demonstrate that it is possible to quantitatively extract the metallic phase fraction from time-resolved HHG(tr-HHG)signals throughout the IMT.This study highlights the benefits of utilizing many-body dynamics for controlling HHG and underscores the necessity for further theoretical research on HHG in strongly correlated systems.
