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PREPARATION AND CHARACTERIZATION OF SPHERICAL PP/PB ALLOYS WITH MgCl_2-SUPPORTED ZIEGLER-NATTA CATALYST 被引量:12
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作者 贺爱华 Yang-wei Shi +2 位作者 guo-qing liu Wei Yao Bao-chen Huang 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2012年第5期632-641,共10页
Polypropylene (PP)/polybutene-1 (PB) alloys within reactor were prepared by MgCl2-supported Ziegler-Natta catalyst with sequential two-stage polymerization technology. First, propylene homo-polymerizations were ca... Polypropylene (PP)/polybutene-1 (PB) alloys within reactor were prepared by MgCl2-supported Ziegler-Natta catalyst with sequential two-stage polymerization technology. First, propylene homo-polymerizations were carried out to form isotactic polypropylene (iPP) particles containing active catalyst. Then, butene-1 was subsequently polymerized to form polybutene-1 phase inside the iPP particles. Finally, iPP/PB alloys with spherical shape and adjustable PB content were synthesized. The catalytic activity and catalytic stereospecificity of the Z-N catalyst in the two-stage polymerization process are discussed. The composition and physical properties of the PP alloys were characterized by FT-IR, 13C-NMR, SEM, DSC and XRD. It was found that the in-reactor PP alloys are mainly composed of PP and PB with a little amount of poly(butene- co-propylene) random copolymers and poly(butene-block-propylene) block copolymers. SEM measurements verified that the PB phases with size in the range of 300-400 nm dispersed in the PP matrix uniformly. The incorporation of PB upon the PP matrix affects the properties of final products greatly. 展开更多
关键词 Polymer blends and alloys Polymer synthesis POLYPROPYLENE In situ polymerization.
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Population recovery of the critically endangered western black crested gibbon(Nomascus concolor) in Mt. Wuliang, Yunnan, China 被引量:6
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作者 Peng-Fei Fan Lu Zhang +4 位作者 Li Yang Xia Huang Kai-Chong Shi guo-qing liu Chun-Hua Wang 《Zoological Research》 SCIE CAS CSCD 2022年第2期180-183,共4页
We conducted the third population survey of western black crested gibbons(Nomascus concolor)in Mt.Wuliang,Yunnan Province,China,from November 2020 to March 2021 following the first and second surveys conducted in 2001... We conducted the third population survey of western black crested gibbons(Nomascus concolor)in Mt.Wuliang,Yunnan Province,China,from November 2020 to March 2021 following the first and second surveys conducted in 2001 and2010,respectively.We recorded 104 gibbon groups during the current survey. 展开更多
关键词 CREST BLACK MT
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Influence of La precursors on structure and properties of CeO_2-ZrO_2-Al_2O_3 composite oxides 被引量:2
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作者 You-feng LI Yue-hui HE +1 位作者 guo-qing liu Ling-wei ZENG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第4期739-747,共9页
Three La-doped CeO2-ZrO2-Al2O3(CZA)composite oxide samples,namely,CZA-I,CZA-II and CZA-III,were prepared following a co-precipitation method in the presence of La2O3,La(NO3)3-6H2O and H[La(EDTA)]-16H2O precursors,resp... Three La-doped CeO2-ZrO2-Al2O3(CZA)composite oxide samples,namely,CZA-I,CZA-II and CZA-III,were prepared following a co-precipitation method in the presence of La2O3,La(NO3)3-6H2O and H[La(EDTA)]-16H2O precursors,respectively.When the precursor samples are sintered at 1000°C,the as-prepared composite oxides mainly exhibit the CeO2-ZrO2 cubic fluorite phase,while theγ-Al2O3 andδ-Al2O3 phases appear when the precursor samples are subjected to sintering at 1100 and 1200°C.CZA-III exhibits improved redox properties after high-temperature treatment compared with CZA-I and CZA-II.CZA-III presents the largest surface area of 97.46 m2/g among the three CZAs when the CZA-III precursor sample is sintered at 1000°C.Furthermore,the corresponding oxygen storage capacity(OSC)is the largest with value of 400.27μmol/g when CZA-III precursor sample is sintered at 1000°C.Additionally,CZA-III exhibits the best thermal stability and the highest reduction temperature.However,by increasing the sintering temperature to 1200°C,there is a dramatic decline in the properties of surface area and OSC.And a decrease for CZA-III in surface area by 58.94%and a decrease of the OSC value by 74.56%are observed. 展开更多
关键词 La precursor ceria-zirconia solid solution composite oxide texture structure redox property
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Dermatomyositis associated with gallbladder carcinoma:A case report 被引量:1
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作者 Qing-Feng Ni guo-qing liu +2 位作者 Li-Yong Pu Liang-Liang Kong Lian-Bao Kong 《World Journal of Hepatology》 CAS 2013年第4期230-233,共4页
Patients with gallbladder carcinoma can present with a variety of paraneoplastic syndromes,including Cushing's syndrome,hypercalcemia,acanthosis nigricans,bullous pemphigoid,dermatomyositis and the sign of Leser-T... Patients with gallbladder carcinoma can present with a variety of paraneoplastic syndromes,including Cushing's syndrome,hypercalcemia,acanthosis nigricans,bullous pemphigoid,dermatomyositis and the sign of Leser-Trélat.Surgical resection of the primary tumor results in resolution of these paraneoplastic syndromes.We present a 67-year old female with facial and cervical erythema who was initially diagnosed with dermatomyositis.However,an abdominal computed tomography(CT)and positron emission tomographyCT scan was suspicious for gallbladder carcinoma with lymph node metastasis.After surgical resection,her dermatomyositis was resolved.This case demonstrates that dermatomyositis may be a manifestation of preexisting gallbladder carcinoma. 展开更多
关键词 DERMATOMYOSITIS PARANEOPLASTIC SYNDROMES GALLBLADDER CARCINOMA
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基于ACO-BP NN的飞机零件橡皮囊成形起皱预测(英文) 被引量:1
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作者 张凌云 刘国庆 +1 位作者 朴小东 范作鹏 《机床与液压》 北大核心 2018年第24期48-55,共8页
利用ABAQUS/Explicit有限元分析软件对2A12-O态铝合金橡皮囊成形凸曲线弯边零件起皱现象进行分析,借助正交试验工具,进行了橡皮囊成形数值模拟试验。通过分析材料性能参数和工艺参数对凸弯边橡皮囊成形零件的影响,获取了影响凸曲线弯边... 利用ABAQUS/Explicit有限元分析软件对2A12-O态铝合金橡皮囊成形凸曲线弯边零件起皱现象进行分析,借助正交试验工具,进行了橡皮囊成形数值模拟试验。通过分析材料性能参数和工艺参数对凸弯边橡皮囊成形零件的影响,获取了影响凸曲线弯边零件起皱的主效应参数,并在此试验基础上建立了基于蚁群神经网络的起皱预测模型。在利用大量试验数据对其训练之后,使用该模型预测橡皮囊成形零件的起皱情况,同时对2A12-O态铝合金板材橡皮囊成形凸弯边零件进行工艺试验验证,结果表明:该模型能够在研究新零件成形过程中快速获得最佳成形参数,并且可以提高效率的工业,且预测误差控制在5%以内,且满足工业应用标准。 展开更多
关键词 2A12铝合金 正交试验 蚁群神经网络 橡皮成形 起皱预测
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Chemical abundance analysis of 19 barium stars 被引量:1
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作者 Guo-Chao Yang Yan-Chun Liang +10 位作者 Monique Spite Yu-Qin Chen Gang Zhao Bo Zhang guo-qing liu Yu-Juan liu Nian liu Li-Cai Deng Francois Spite Vanessa Hill Cai-Xia Zhang 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2016年第1期159-174,共16页
We aim at deriving accurate atmospheric parameters and chemical abundances of 19 barium(Ba) stars, including both strong and mild Ba stars, based on the high signal-to-noise ratio and high resolution Echelle spectra... We aim at deriving accurate atmospheric parameters and chemical abundances of 19 barium(Ba) stars, including both strong and mild Ba stars, based on the high signal-to-noise ratio and high resolution Echelle spectra obtained from the 2.16 m telescope at Xinglong station of National Astronomical Observatories, Chinese Academy of Sciences. The chemical abundances of the sample stars were obtained from an LTE, plane-parallel and line-blanketed atmospheric model by inputting the atmospheric parameters(effective temperatures Teff, surface gravities log g, metallicity [Fe/H] and microturbulence velocity ξt) and equivalent widths of stellar absorption lines. These samples of Ba stars are giants as indicated by atmospheric parameters, metallicities and kinematic analysis about UVW velocity. Chemical abundances of 17 elements were obtained for these Ba stars. Their Na, Al, α- and iron-peak elements(O, Na, Mg, Al, Si, Ca,Sc, Ti, V, Cr, Mn, Ni) are similar to the solar abundances. Our samples of Ba stars show obvious overabundances of neutron-capture(n-capture) process elements relative to the Sun. Their median abundances of[Ba/Fe], [La/Fe] and [Eu/Fe] are 0.54, 0.65 and 0.40, respectively. The Y I and Zr I abundances are lower than Ba, La and Eu, but higher than the α- and iron-peak elements for the strong Ba stars and similar to the iron-peak elements for the mild stars. There exists a positive correlation between Ba intensity and [Ba/Fe].For the n-capture elements(Y, Zr, Ba, La), there is an anti-correlation between their [X/Fe] and [Fe/H]. We identify nine of our sample stars as strong Ba stars with [Ba/Fe]〉0.6 where seven of them have Ba intensity Ba=2-5, one has Ba=1.5 and another one has Ba=1.0. The remaining ten stars are classified as mild Ba stars with 0.17〈[Ba/Fe]〈0.54. 展开更多
关键词 methods: observational - stars: abundances - stars: atmospheres - stars: chemically peculiar- stars: kinematics and dynamics - stars: late-type
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Heat treatment on phase evolution of Bi-2223 precursor powder prepared by spray pyrolysis method
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作者 Li-Jun Cui Ping-Xiang Zhang +9 位作者 Jin-Shan Li Guo Yan Yong Feng Xiang-Hong liu Jian-Feng Li Xi-Feng Pan Fan Yang Sheng-Nan Zhang Xiao-Bo Ma guo-qing liu 《Chinese Physics B》 SCIE EI CAS CSCD 2019年第4期332-336,共5页
The phase evolution of Bi-2223 precursor powder prepared by spray pyrolysis method is studied with different heat treatment parameters. The results show that the reaction temperature and phase composition of precursor... The phase evolution of Bi-2223 precursor powder prepared by spray pyrolysis method is studied with different heat treatment parameters. The results show that the reaction temperature and phase composition of precursor powder depend on heat treatment atmosphere. Phase assemblage of(Bi,Pb)-2212, AEC, CuO, and small Bi-2201 can be obtained by heat-treated in N2-0.1%O_2 atmosphere. For precursor powder, there is sufficient reaction process at 770℃, and the dimension of Bi-2212 phase increases rapidly with the increase of heat treatment temperature and time. The dimension of AEC phase also increases by extending heat treatment time. As a balance among phase assemblage, dimension of particle and adequate reaction, a reasonable precursor powder can be obtained by heat-treated at 770℃ for 12 h–16 h in N2-0.1%O_2 atmosphere. Critical current of 37-filament Bi-2223 tape is about 120 A, which confirms that these heat treatment parameters are reasonable. 展开更多
关键词 BI-2223 phase evolution HEAT treatment SPRAY PYROLYSIS
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Thickening progression mechanism of silica fume-oil well cement composite system at high temperatures
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作者 Hang Zhang Miao-Miao Hu +7 位作者 Peng-Peng Li guo-qing liu Qing-Lu Chang Jie Cao Ming liu Wen-Hua Xu Xiu-Jian Xia Jin-Tang Guo 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2793-2805,共13页
This work studied the thickening progression mechanism of the silica fume-oil well cement composite system at high temperatures(110-180.C)in order to provide a theoretical guidance for the rational application of sili... This work studied the thickening progression mechanism of the silica fume-oil well cement composite system at high temperatures(110-180.C)in order to provide a theoretical guidance for the rational application of silica fume in the cementing engineering.Results showed that silica fume seldom affected the thickening progression of oil well cement slurry at 110-120.C,but when temperature reached above130.C,it would aggravate the bulging degree of thickening curves and significantly extend the thickening time,meanwhile causing the abnormal“temperature-based thickening time reversal”and“dosage-based thickening time reversal”phenomena in the range of 130-160.C and 170-180.C respectively.At 130-160.C,the thickening time of oil well cement slurry was mainly associated with the generation rate of calcium hydroxide(CH)crystal.The introduced silica fume would be attracted to the cement minerals'surface that were hydrating to produce CH and agglomerate together to form an“adsorptive barrier”to hinder further hydration of the inner cement minerals.This“adsorptive barrier”effect strengthened with the rising temperature which extended the thickening time and caused the occurrence of the“temperature-based thickening time reversal”phenomenon.At 170-180.C,the pozzolanic activity of silica fume significantly enhanced and considerable amount of C-S-H was generated,thus the“temperature-based thickening time reversal”vanished and the“dosage-based thickening time reversal”was presented. 展开更多
关键词 Silica fume Oil well cement Thickening time reversal Pozzolanic reaction Adsorptive barrier CH and C-S-H
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The genus Glaucopterum Wagner(Hemiptera: Miridae: Phylinae) from China, with description of two new species
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作者 Xiao-Ming Li guo-qing liu 《Zoological Systematics》 CSCD 北大核心 2014年第3期388-394,共7页
Three species of mirid genus Glaucopterum from China are presented of which Glaucopterum nitrarium sp. nov. and G. shanxiense sp. nov. are described as new. A key toChinese species is offered. Photographs of the dorsa... Three species of mirid genus Glaucopterum from China are presented of which Glaucopterum nitrarium sp. nov. and G. shanxiense sp. nov. are described as new. A key toChinese species is offered. Photographs of the dorsal habitus and illustrations of the genitalia are provided. All type specimens are deposited in Institute of Entomology, Nankai University, Tianjin, China. 展开更多
关键词 HEMIPTERA MIRIDAE PHYLINAE Glaucopterum new species China.
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Fully relativistic many-body perturbation energies,transition properties,and lifetimes of lithium-like iron Fe XXIV
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作者 李双 赵敏 +2 位作者 刘国庆 胡昌宝 潘国柱 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第10期90-99,共10页
Employing the advanced relativistic configuration interaction(RCI)combined with the many-body perturbation theory(RMBPT)method,we report energies and lifetime values for the lowest 35 energy levels from the(1s^(2))nl ... Employing the advanced relativistic configuration interaction(RCI)combined with the many-body perturbation theory(RMBPT)method,we report energies and lifetime values for the lowest 35 energy levels from the(1s^(2))nl configurations(where the principal quantum number n=2–6 and the angular quantum number l=0,...,n-1)of lithium-like iron Fe XXIV,as well as complete data on the transition wavelengths,radiative rates,absorption oscillator strengths,and line strengths between the levels.Both the allowed(E1)and forbidden(magnetic dipole M1,magnetic quadrupole M2,and electric quadrupole E2)ones are reported.Through detailed comparisons with previous results,we assess the overall accuracies of present RMBPT results to be likely the most precise ones to date.Configuration interaction effects are found to be very important for the energies and radiative properties for the ion.The present RMBPT results are valuable for spectral line identification,plasma modeling,and diagnosing. 展开更多
关键词 relativistic many-body perturbation multi-reference configuration radiative rates LIFETIME
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Abundance analysis of Barium stars
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作者 guo-qing liu Yan-Chun Liang Li-Cai Deng 《Chinese Journal of Astronomy and Astrophysics》 CSCD 2009年第4期431-448,共18页
We obtain the chemical abundances of six barium stars and two CH subgiant stars based on the high signal-to-noise ratio and high resolution EcheUe spectra. The neu-Iron capture process elements Y, Zr, Ba, La and Eu sh... We obtain the chemical abundances of six barium stars and two CH subgiant stars based on the high signal-to-noise ratio and high resolution EcheUe spectra. The neu-Iron capture process elements Y, Zr, Ba, La and Eu show obvious overabundances relative to the Sun, for example, their [Ba/Fe] values are from 0.45 to 1.27. Other elements, including Na, Mg, A1, Si, Ca, Sc, Ti, V, Cr, Mn and Ni, show comparable abundances to the Solar ones, and their [Fe/H] covers a range from -0.40 to 0.21, which means they belong to the Galactic disk. The predictions of the theoretical model of wind accretion for binary systems can explain the observed abundance patterns of the neutron capture process elements in these stars, which means that their overabundant heavy-elements could be caused by accreting the ejecta of AGB stars, the progenitors of present-day white dwarf companions in binary systems. 展开更多
关键词 STARS abundances-stars atmospheres-stars chemically peculiar-stars evolution-binaries SPECTROSCOPIC
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Timing analysis of the black hole candidate EXO 1846–031 with Insight-HXMT monitoring
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作者 He-Xin liu Yue Huang +118 位作者 Guang-Cheng Xiao Qing-Cui Bu Jin-Lu Qu Shu Zhang Shuang-Nan Zhang Shu-Mei Jia Fang-Jun Lu Xiang Ma Lian Tao Wei Zhang Li Chen Li-Ming Song Ti-Pei Li Yu-Peng Xu Xue-Lei Cao Yong Chen Cong-Zhan liu Ce Cai Zhi Chang Gang Chen Tian-Xiang Chen Yi-Bao Chen Yu-Peng Chen Wei Cui Wei-Wei Cui Jing-Kang Deng Yong-Wei Dong Yuan-Yuan Du Min-Xue Fu Guan-Hua Gao He Gao Min Gao Ming-Yu Ge Yu-Dong Gu Ju Guan Cheng-Cheng Guo Da-Wei Han Jia Huo Lu-Hua Jiang Wei-Chun Jiang Jing Jin Yong-Jie Jin Ling-Da Kong Bing Li Cheng-Kui Li Gang Li Mao-Shun Li Wei Li Xian Li Xiao-Bo Li Xu-Fang Li Yang-Guo Li Zheng-Wei Li Xiao-Hua Liang Jing-Yuan Liao Bai-Sheng liu guo-qing liu Hong-Wei liu Xiao-Jing liu Yi-Nong liu Bo Lu Xue-Feng Lu Qi Luo Tao Luo Bin Meng Yi Nang Jian-Yin Nie Ge Ou Na Sai Ren-Cheng Shang Xin-Ying Song Liang Sun Ying Tan You-Li Tuo Chen Wang Guo-Feng Wang Juan Wang Ling-Jun Wang Weng-Shuai Wang Yu-Sa Wang Xiang-Yang Wen Bai-Yang Wu Bo-Bing Wu Mei Wu Shuo Xiao Shao-Lin Xiong He Xu Jia-Wei Yang Sheng Yang Yan-Ji Yang Yi-Jung Yang Qi-Bin Yi Qian-Qing Yin Yuan You Ai-Mei Zhang Cheng-Mo Zhang Fan Zhang Hong-Mei Zhang Juan Zhang Tong Zhang Wan-Chang Zhang Wen-Zhao Zhang Yi Zhang Yi-Fei Zhang Yong-Jie Zhang Yuan-Hang Zhang Yue Zhang Zhao Zhang Zhi Zhang Zi-Liang Zhang Hai-Sheng Zhao Xiao-Fan Zhao Shi-Jie Zheng Yao-Guang Zheng Deng-Ke Zhou Jian-Feng Zhou Yu-Xuan Zhu Ren-Lin Zhuang Yue Zhu 《Research in Astronomy and Astrophysics》 SCIE CAS CSCD 2021年第3期193-204,共12页
We present the observational results from a detailed timing analysis of the black hole candidate EXO 1846-031 during its outburst in 2019 with the observations of Insight-HXMT,NICER and MAXI.This outburst can be class... We present the observational results from a detailed timing analysis of the black hole candidate EXO 1846-031 during its outburst in 2019 with the observations of Insight-HXMT,NICER and MAXI.This outburst can be classified roughly into four different states.Type-C quasi-periodic oscillations(QPOs)observed by NICER(about 0.1-6 Hz)and Insight-HXMT(about 0.7-8 Hz)are also reported in this work.Meanwhile,we study various physical quantities related to QPO frequency.The QPO rms-frequency relationship in the energy band 1-10 keV indicates that there is a turning pointing in frequency around2 Hz,which is similar to that of GRS 1915+105.A possible hypothesis for the relationship above may be related to the inclination of the source,which may require a high inclination to explain it.The relationships between QPO frequency and QPO rms,hardness,total fractional rms and count rate have also been found in other transient sources,which can indicate that the origin of type-C QPOs is non-thermal. 展开更多
关键词 X-ray binaries black hole candidate QPO EXO 1846–031
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Combustion Characteristics and Kinetics of Anthracite Blending with Pine Sawdust
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作者 guo-qing liu Qing-cai liu +3 位作者 Xiao-qing WANG Fei MENG Shan REN Zhen-peng JI 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2015年第9期812-817,共6页
The combustion characteristics and kinetics of anthracite,pine sawdust and their blends were investigated under combustion condition by thermogravimetric analysis,respectively.The fractions of pine sawdust in the blen... The combustion characteristics and kinetics of anthracite,pine sawdust and their blends were investigated under combustion condition by thermogravimetric analysis,respectively.The fractions of pine sawdust in the blended samples were set to be 30%,50%,and 80%.The results showed that the ignition and burnout temperatures of pine sawdust were lower and the maximum combustion rate was higher than those of anthracite.With the increase of pine sawdust content,the ignition temperature and burnout temperature of the blends decreased,while the maximum mass loss rate and the combustible index of the blends increased;that is,the comprehensive combustion property became better.The kinetic parameters for the blends combustion under air condition were calculated based on experimental results using Coats-Redfern model.When the pine sawdust content varied in the range of 30%-80%,the combustion processes of these blends could be divided into two stages and the combustion reactions belong to the first-order reaction.The values of apparent activation energy at two individual stages decreased from 68.78to47.28kJ·mol-1 and from 113.53 to 46.43kJ·mol-1,respectively. 展开更多
关键词 pine sawdust anthracite thermogravimetric analysis combustion characteristics apparent activation energy
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Research progress of yoga in symptom management of cancer patients
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作者 guo-qing liu Jing-Yi Han +1 位作者 Wen-Jing Song Ying Wang 《TMR Non-Drug Therapy》 2022年第2期29-33,共5页
The survival rate of cancer patients is rising,but the treatment of cancer will bring a series of physiological and psychological symptoms to patients,which will seriously affect the quality of life of patients.As a c... The survival rate of cancer patients is rising,but the treatment of cancer will bring a series of physiological and psychological symptoms to patients,which will seriously affect the quality of life of patients.As a complementary and alternative therapy,yoga is more and more used in symptom management and quality of life improvement of cancer patients.This paper introduces the overview,implementation methods and application status of yoga,summarizes the application effect of yoga in the symptom management of cancer patients,analyzes the shortcomings in the application process at this stage,and puts forward the prospect,in order to provide a reference for the better application of yoga in the symptom management of cancer patients in the future. 展开更多
关键词 YOGA CANCER symptom management REVIEW
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