Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor...Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor cooling,ignoring to achieve simultaneous cooling both indoors and outdoors,thereby weakening the overall cooling performance.Herein,a full-scale structure fabric with selective emission properties is constructed for simultaneous indoor and outdoor cooling.The fabric achieves 94%reflectance performance in the sunlight band(0.3–2.5μm)and 6%in the mid-infrared band(2.5–25μm),effectively minimizing heat absorption and radiation release obstruction.It also demonstrates 81%radiative emission performance in the atmospheric window band(8–13μm)and 25%radiative transmission performance in the mid-infrared band(2.5–25μm),providing 60 and 26 W m−2 net cooling power outdoors and indoors.In practical applications,the fabric achieves excellent indoor and outdoor human cooling,with temperatures 1.4–5.5℃ lower than typical polydimethylsiloxane film.This work proposes a novel design for the advanced radiative cooling fabric,offering significant potential to realize sustainable personal thermal management.展开更多
With the increasingly urgent demand for clean water resources and the growing emission of oily wastewater,high-flux oil/water separation materials with the special wettability are progressively desired.Cellulose nanoc...With the increasingly urgent demand for clean water resources and the growing emission of oily wastewater,high-flux oil/water separation materials with the special wettability are progressively desired.Cellulose nanocrystal(CNC)from renewable biomass has been utilized to fabricate oil/water separation membranes,but it is limited to enhancing mechanical properties.Herein,a wrinkled structure with abundant–OH is constructed on polyacrylonitrile(PAN)nanofibers via the CNC hybridization process.And then,a super-hydrophilic nano-TiO_(2)shell is anchored tightly on the surface of the fiber by wrinkles and–OH.The CNC promotes significantly the in situ growth of TiO_(2),with the TiO_(2)loading ratio of up to 5.3%.The nano-TiO_(2)shell endows the obtained film with super-hydrophilicity and underwater super-oleophobicity,resulting in a visible increase of the permeation flux for the oil/water mixture from 1483 to 11,023 L m^(−2)h^(−1).Interestingly,the hierarchical structure facilitates the demulsification for oil-in-water emulsion stabilized by surfactant,allowing the obtained membrane to exhibit eminent antifouling property and high emulsion permeability of about 3,278 L m^(−2)h^(−1).This design strategy develops next-generation anchors for targeted modification on the non-reactive substrates and provides a novel pathway for fabricating oil/water separation membranes.展开更多
基金financially supported by Heilongjiang Postdoctoral Fund(Grant No.LBH-Z24057)Outstanding Master’s and Doctoral Thesis of Longjiang in the New Era(Grant No.LJYXL2023-076).
文摘Radiative cooling fabric creates a thermally comfortable environment without energy input,providing a sustainable approach to personal thermal management.However,most currently reported fabrics mainly focus on outdoor cooling,ignoring to achieve simultaneous cooling both indoors and outdoors,thereby weakening the overall cooling performance.Herein,a full-scale structure fabric with selective emission properties is constructed for simultaneous indoor and outdoor cooling.The fabric achieves 94%reflectance performance in the sunlight band(0.3–2.5μm)and 6%in the mid-infrared band(2.5–25μm),effectively minimizing heat absorption and radiation release obstruction.It also demonstrates 81%radiative emission performance in the atmospheric window band(8–13μm)and 25%radiative transmission performance in the mid-infrared band(2.5–25μm),providing 60 and 26 W m−2 net cooling power outdoors and indoors.In practical applications,the fabric achieves excellent indoor and outdoor human cooling,with temperatures 1.4–5.5℃ lower than typical polydimethylsiloxane film.This work proposes a novel design for the advanced radiative cooling fabric,offering significant potential to realize sustainable personal thermal management.
基金the Fundamental Research Funds for the Central Universities(Grant No.2572023AW53)the Natural Science Foundation of Heilongjiang Province,China(Grant No.LH2020C039).
文摘With the increasingly urgent demand for clean water resources and the growing emission of oily wastewater,high-flux oil/water separation materials with the special wettability are progressively desired.Cellulose nanocrystal(CNC)from renewable biomass has been utilized to fabricate oil/water separation membranes,but it is limited to enhancing mechanical properties.Herein,a wrinkled structure with abundant–OH is constructed on polyacrylonitrile(PAN)nanofibers via the CNC hybridization process.And then,a super-hydrophilic nano-TiO_(2)shell is anchored tightly on the surface of the fiber by wrinkles and–OH.The CNC promotes significantly the in situ growth of TiO_(2),with the TiO_(2)loading ratio of up to 5.3%.The nano-TiO_(2)shell endows the obtained film with super-hydrophilicity and underwater super-oleophobicity,resulting in a visible increase of the permeation flux for the oil/water mixture from 1483 to 11,023 L m^(−2)h^(−1).Interestingly,the hierarchical structure facilitates the demulsification for oil-in-water emulsion stabilized by surfactant,allowing the obtained membrane to exhibit eminent antifouling property and high emulsion permeability of about 3,278 L m^(−2)h^(−1).This design strategy develops next-generation anchors for targeted modification on the non-reactive substrates and provides a novel pathway for fabricating oil/water separation membranes.
