Owing to the advantages of high operating voltage,environmental benignity,and low cost,potassium-based dual-ion batteries(KDIBs)have been considered as a potential candidate for large-scale energy storage.However,KDIB...Owing to the advantages of high operating voltage,environmental benignity,and low cost,potassium-based dual-ion batteries(KDIBs)have been considered as a potential candidate for large-scale energy storage.However,KDIBs generally suffer from poor cycling performance and unsatisfied capacity,and inactive components of conductive agents,binders,and current collector further lower their overall capacity.Herein,we prepare coral-like carbon nanowres(CCNWs)doped with nitrogen as a binder-free anode material for K^(+)-ion storage,in which the unique coral-like porous nanostructure and amorphous/short-range-ordered composite feature are conducive to enhancing the structural stability,to facilitating the ion transfer and to boosting the full utilization of active sites during potassiation/de-potassiation process.As a result,the CCNW anode possesses a hybrid K^(+)-storage mechanism of diffusive behavior and capacitive adsorption,and stably delivers a high capacity of 276 mAh g^(-1)at 50 mA g^(-1),good rate capability up to 2 A g^(-1),and long-term cycling stability with 93%capacity retention after 2000 cycles at 1 A g^(-1).Further,assembling this CCNW anode with an environmentally benign expanded graphite(EG)cathode yields a proof-of-concept KDIB,which shows a high specific capacity of 134.4 mAh g^(-1)at 100 mA g^(-1),excellent rate capability of 106.5 mAh g^(-1)at 1 A g^(-1),and long-term cycling stability over 1000 cycles with negligible capacity loss.This study provides a feasible approach to developing high-performance anodes for potassium-based energy storage devices.展开更多
This study is a continuation of our previous work. In this experiment, transparent tin-doped indium oxide (ITO) fork electrodes with different width and spacing were coated on the glass substrates. The used dust parti...This study is a continuation of our previous work. In this experiment, transparent tin-doped indium oxide (ITO) fork electrodes with different width and spacing were coated on the glass substrates. The used dust particle size was smaller than 180 mesh. The effects of the electrode width, the electrode spacing, voltage, frequency, waveform, and the duty ratio on the dust removal efficiency were studied. The obtained optimum conditions of dust removal were as follows: voltage was 1500 V, frequency was 15 Hz, square wave, 10% duty ratio, the electrode width was 0.5 mm, electrodes spacing was 1.3 mm. Our previous experimental results show that the dust removal efficiency would be up to 95%. But in this experiment, under the optimum conditions, the dust removal efficiency could be up to 99%.展开更多
Beginning in 2000,China initiated a series of large-scale ecological restoration projects to address the dual challenges posed by socioeconomic development and extreme climate events.This study employed Vine Copula fu...Beginning in 2000,China initiated a series of large-scale ecological restoration projects to address the dual challenges posed by socioeconomic development and extreme climate events.This study employed Vine Copula functions to develop a probabilistic assessment model for vegetation loss,quantitatively evaluating how ecological engineering implementation has modified vegetation vulnerability to compound drought-heat stress across China.We analysed temporal changes in vegetation vulnerability associated with project implementation to assess the effectiveness of different ecological engineering initiatives in reducing vegetation vulnerability.The results revealed that(1) Following ecological engineering implementation,the positive correlation between the kernel normalized difference vegetation index(KNDVI) and standardized soil moisture index(SSMI) strengthened significantly(P <0.05),whereas the relationship with the standardized temperature index(STI) shifted from negative to positive,suggesting that ecological engineering substantially modulates vegetation responses to elevated temperature and water deficit.(2) Under compound drought-heat conditions,drought intensity governed primarily vegetation vulnerability dynamics,with drought intensification increasing vulnerability by approximately 10% compared with only 2.6% under high-temperature stress.Ecological engineering had significant effects on vegetation vulnerability(P<0.001),although with pronounced regional heterogeneity:southern China experienced the most substantial improvements,whereas central Inner Mongolia and the Xizang Autonomous Region experienced increased vulnerability following project implementation.(3) Different ecological restoration project types demonstrated varying efficacy in terms of reducing vegetation vulnerability under compound drought-heat conditions.The Rocky Desertification Comprehensive Control Program in Southwest Karst Areas,the Pearl River Basin Shelterbelt Development Program,and the Yangtze River Basin Shelterbelt Development Program consistently reduced the vegetation loss probability across diverse compound drought-heat scenarios(0.29,0.26,and 0.20,respectively),whereas the Sanjiangyuan Ecological Conservation and Restoration Program showed marginal increases in vulnerability(0.01).Therefore,a comprehensive understanding of vegetation vulnerability to compound drought-heat stress from an ecological engineering perspective and a rigorous evaluation of restoration benefits will provide critical scientific foundations for mitigating ecosystem degradation and enhancing ecosystem resilience.展开更多
Graphene aerogels are desirable for energy storage and conversion, as catalysis supports, and as adsorbents for environmental remediation. To produce graphene aerogels with low density, while maintaining high electric...Graphene aerogels are desirable for energy storage and conversion, as catalysis supports, and as adsorbents for environmental remediation. To produce graphene aerogels with low density, while maintaining high electrical conductivity and strong mechanic performance, we synthesized graphene aerogels by the magnesiothermic reduction of a freeze-dried graphene oxide （GO） self-assembly and subsequent etching of the formed MgO in acid solution. The reduced graphene oxide （rGO） aerogel samples exhibited densities as low as 1.1 mg·cm^-3. The rGO aerogel was very resilient, exhibiting full recoveryeven after being compressed by strains of up to 80%; its elastic modulus （E） scaled with density （p） as E-p^2. The rGO aerogels also exhibited high conductivities （e.g., 27.7 S·m^-1 at 3.6 mg·cm^-3） and outperformed many rGO aerogels fabricated by other reduction processes. Such outstanding properties were ascribed to the microstructures inherited from the freeze-dried GO self-assembly and the magnesiothermic reduction process.展开更多
V^(4+)-rich V_(2)O_(5)/carbon aerogel(V^(4+)-V_(2)O_(5)/CA)composites were synthesized as electrode materials for supercapacitors via in-situ hydrolysis-condensation processing.Carbon aerogel(CA)promotes the depositio...V^(4+)-rich V_(2)O_(5)/carbon aerogel(V^(4+)-V_(2)O_(5)/CA)composites were synthesized as electrode materials for supercapacitors via in-situ hydrolysis-condensation processing.Carbon aerogel(CA)promotes the deposition of amorphous vanadium oxide and catalyzes the crystallization of V^(4+)-rich V_(2)O_(5)nanosheets at much reduced temperature.With a uniform distribution of V_(2)O_(5)nanosheets in CA,the special structure provides a large specific area and reactive sites.CA also synergistically improves the electrical conductivity and structural integrity.In addition,rich V^(4+) would enhance the intrinsic electrical conductivity of V_(2)O_(5),promote ion diffusion and catalyze the electrochemical reactions.Consequently,V^(4+)-V_(2)O_(5)/CA exhibits much enhanced specific capacitance(405 F g^(-1) at 0.5 A g^(-1)),high energy density(56 W h kg^(-1) with a power density of 250 W kg^(-1))and long cycle life(96%capacitance retention after 40,000 cycles).展开更多
Co_(2)VO_(4) with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts and batteries.However,high metal-metal interactions make it challenging to maintain high reactivit...Co_(2)VO_(4) with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts and batteries.However,high metal-metal interactions make it challenging to maintain high reactivity as well as increase the conductivity and stability of supercapacitors.In this work,spinel-structured CoZn_(0.5)V_(1.5)O_(4) with a high specific surface area was synthesized through an ion-exchange process from the metal-organic frameworks of zinc-cobalt.Density functional theory calculations indicate that the replacement of transition metal by Zn can decrease the interaction between the transition metals,leading to a downshift in the π^(∗)-orbitals(V-O)and half-filled a_(1g) orbitals near the Fermi level,thus increasing the conductivity and stability of CoZn_(0.5)V_(1.5)O_(4).As a supercapacitor electrode,CoZn_(0.5)V_(1.5)O_(4) exhibits high cycling durability(99.4% capacitance retention after 18,000 cycles)and specific capacitance(1100mFcm^(-2) at 1mAcm^(-2)).This work provides the possibility of designing octahedral and tetrahedral sites in transition metal oxides to improve their electrochemical performance.展开更多
Oct4 is a key component of the pluripotency regulatory network,and its reciprocal interaction with Cdx2 has been shown to be a determinant of either the self-renewal of embryonic stem cells(ESCs)or their differentiati...Oct4 is a key component of the pluripotency regulatory network,and its reciprocal interaction with Cdx2 has been shown to be a determinant of either the self-renewal of embryonic stem cells(ESCs)or their differentiation into trophoblast.Oct4 of maternal origin is postulated to play critical role in defining totipotency and inducing pluripotency during embryonic development.However,the genetic elimination of maternal Oct4 using a Cre-lox approach in mouse revealed that the establishment of totipotency in maternal Oct4–depleted embryos was not affected,and that these embryos could complete full-term development without any obvious defect.These results indicate that Oct4 is not essential for the initiation of pluripotency,in contrast to its critical role in maintaining pluripotency.This conclusion is further supported by the formation of Oct4-GFP–and Nanog-expressing inner cell masses(ICMs)in embryos with complete inactivation of both maternal and zygotic Oct4 expression and the reprogramming of fibroblasts into fully pluripotent cells by Oct4-deficient oocytes.展开更多
KMT2D,a H3K4me1 methyltransferase primarily regulating enhancers,is a leading cause of KABUKI syndrome.This multisystem disorder leads to craniofacial and cognitive abnormalities,possibly through neural crest and neur...KMT2D,a H3K4me1 methyltransferase primarily regulating enhancers,is a leading cause of KABUKI syndrome.This multisystem disorder leads to craniofacial and cognitive abnormalities,possibly through neural crest and neuronal lineages.However,the impacted cell-of-origin and molecular mechanism of KMT2D during the development of KABUKI disease remains unknown.Here we have optimized a brain organoid model to investigate neural crest and neuronal differentiation.To pinpoint KMT2D's enhancer target,we developed a genome-wide cis-regulatory element explorer(GREE)based on single-cell multiomic integration.Single cell RNA-seq revealed that KMT2D-knockout(KO)and patient-derived organoids exhibited neural crest deformities and GABAergic overproduction.Mechanistically,GREE identified that KMT2D targets a roof-plate-like niche cell and activates the niche cell-specific WNT3A enhancer,providing the microenvironment for neural crest and neuronal development.Interestingly,KMT2D-mutated mice displayed decreased WNT3A expression in the diencephalon roof plate,indicating impaired niche cell function.Deleting the WNT3A enhancer in the organoids presented phenotypic similarities to KMT2D-depletion,emphasizing the WNT3A enhancer as the predominant target of KMT2D.Conversely,reactivating WNT signaling in KMT2D-KO rescued the lineage defects by restoring the microenvironment.Overall,our discovery of KMT2D's primary target provides insights for reconciling complex phenotypes of KABUKI syndrome and establishes a new paradigm for dissecting the mechanisms of genetic disorders from genotype to phenotype.展开更多
Vanadium nitride(VN)-based materials have been investigated as negative electrode materials for supercapacitors(SCs)owing to their high theoretical capacitances and suitable negative potential windows.However,viable V...Vanadium nitride(VN)-based materials have been investigated as negative electrode materials for supercapacitors(SCs)owing to their high theoretical capacitances and suitable negative potential windows.However,viable VNbased negative electrode materials suffer from irreversible electrochemical oxidation of the soluble vanadium species,leading to rapid capacitance fading when operated in aqueous electrolytes.Developing a versatile approach to enhance the stability of VN in aqueous electrolytes is still a challenge.Here,an interface engineering strategy is developed to intentionally introduce surface nanolayers of vanadium oxides(VO_(x))as a reactive template on the VN surface to formulate welldesigned polypyrrole@VNO(Ppy@VNO)core-shell nanowires(NWs)incorporated into a 3D porous N-doped graphene(NG)hybrid aerogel as a durable negative electrode for SCs.Experimental and theoretical investigations reveal that the in-situ constructed Ppy@VNO core-shell host can offer more efficient pathways for rapid electron/ion transport and accessible electroactive sites.Most importantly,a reversible surface redox reaction is realized through the transformation of the valence state of V,and a long cyclic stability is achieved.The Ppy@VNO/NG hybrid aerogel can deliver a high specific capacitance of 650 F g^(-1) at 1 A g^(-1) with approximately 70.7%capacitance retention(up to the twenty-fold current density),and an excellent cycling stability without any capacitance decay after 10,000 cycles at both low and high current densities(1 and 10 A g^(-1),respectively).This work paves the way for the development of advanced electrode materials for SCs.展开更多
基金supported by the Key-Area Research and Development Program of Guangdong Province(2019B090914003)National Natural Science Foundation of China(11904379,51972329,51822210,52061160484)+2 种基金Shenzhen Science and Technology Planning Project(JCYJ20190807171803813,JCYJ2020010911562492,KQTD20161129150510559)China Postdoctoral Science Foundation(2018M643235)Guangdong Basic and Applied Basic Research Foundation(2019A1515011902,2019TX05L389)。
文摘Owing to the advantages of high operating voltage,environmental benignity,and low cost,potassium-based dual-ion batteries(KDIBs)have been considered as a potential candidate for large-scale energy storage.However,KDIBs generally suffer from poor cycling performance and unsatisfied capacity,and inactive components of conductive agents,binders,and current collector further lower their overall capacity.Herein,we prepare coral-like carbon nanowres(CCNWs)doped with nitrogen as a binder-free anode material for K^(+)-ion storage,in which the unique coral-like porous nanostructure and amorphous/short-range-ordered composite feature are conducive to enhancing the structural stability,to facilitating the ion transfer and to boosting the full utilization of active sites during potassiation/de-potassiation process.As a result,the CCNW anode possesses a hybrid K^(+)-storage mechanism of diffusive behavior and capacitive adsorption,and stably delivers a high capacity of 276 mAh g^(-1)at 50 mA g^(-1),good rate capability up to 2 A g^(-1),and long-term cycling stability with 93%capacity retention after 2000 cycles at 1 A g^(-1).Further,assembling this CCNW anode with an environmentally benign expanded graphite(EG)cathode yields a proof-of-concept KDIB,which shows a high specific capacity of 134.4 mAh g^(-1)at 100 mA g^(-1),excellent rate capability of 106.5 mAh g^(-1)at 1 A g^(-1),and long-term cycling stability over 1000 cycles with negligible capacity loss.This study provides a feasible approach to developing high-performance anodes for potassium-based energy storage devices.
文摘This study is a continuation of our previous work. In this experiment, transparent tin-doped indium oxide (ITO) fork electrodes with different width and spacing were coated on the glass substrates. The used dust particle size was smaller than 180 mesh. The effects of the electrode width, the electrode spacing, voltage, frequency, waveform, and the duty ratio on the dust removal efficiency were studied. The obtained optimum conditions of dust removal were as follows: voltage was 1500 V, frequency was 15 Hz, square wave, 10% duty ratio, the electrode width was 0.5 mm, electrodes spacing was 1.3 mm. Our previous experimental results show that the dust removal efficiency would be up to 95%. But in this experiment, under the optimum conditions, the dust removal efficiency could be up to 99%.
基金supported by the Joint Innovation and Development Project of Chongqing Natural Science Foundation(Grant No.CSTB2025NSCQ-LZX0118)the National Natural Science Foundation of China(Grant No.42201124)+1 种基金the China Postdoctoral Science Foundation(Grant No.2023M740433)the Chongqing Entrepreneurship and Innovation Support Program(Grant No.2204012976986965)。
文摘Beginning in 2000,China initiated a series of large-scale ecological restoration projects to address the dual challenges posed by socioeconomic development and extreme climate events.This study employed Vine Copula functions to develop a probabilistic assessment model for vegetation loss,quantitatively evaluating how ecological engineering implementation has modified vegetation vulnerability to compound drought-heat stress across China.We analysed temporal changes in vegetation vulnerability associated with project implementation to assess the effectiveness of different ecological engineering initiatives in reducing vegetation vulnerability.The results revealed that(1) Following ecological engineering implementation,the positive correlation between the kernel normalized difference vegetation index(KNDVI) and standardized soil moisture index(SSMI) strengthened significantly(P <0.05),whereas the relationship with the standardized temperature index(STI) shifted from negative to positive,suggesting that ecological engineering substantially modulates vegetation responses to elevated temperature and water deficit.(2) Under compound drought-heat conditions,drought intensity governed primarily vegetation vulnerability dynamics,with drought intensification increasing vulnerability by approximately 10% compared with only 2.6% under high-temperature stress.Ecological engineering had significant effects on vegetation vulnerability(P<0.001),although with pronounced regional heterogeneity:southern China experienced the most substantial improvements,whereas central Inner Mongolia and the Xizang Autonomous Region experienced increased vulnerability following project implementation.(3) Different ecological restoration project types demonstrated varying efficacy in terms of reducing vegetation vulnerability under compound drought-heat conditions.The Rocky Desertification Comprehensive Control Program in Southwest Karst Areas,the Pearl River Basin Shelterbelt Development Program,and the Yangtze River Basin Shelterbelt Development Program consistently reduced the vegetation loss probability across diverse compound drought-heat scenarios(0.29,0.26,and 0.20,respectively),whereas the Sanjiangyuan Ecological Conservation and Restoration Program showed marginal increases in vulnerability(0.01).Therefore,a comprehensive understanding of vegetation vulnerability to compound drought-heat stress from an ecological engineering perspective and a rigorous evaluation of restoration benefits will provide critical scientific foundations for mitigating ecosystem degradation and enhancing ecosystem resilience.
基金This work was supported Foundation for Returned Education of China, Key by the Scientific Research Scholars, the Ministry of Basic Research Projects of Science and Technology Commission of Shanghai （No.11JC1412900）, and the National Science Foundation of China program （Nos. 21271140, 51472182）.
文摘Graphene aerogels are desirable for energy storage and conversion, as catalysis supports, and as adsorbents for environmental remediation. To produce graphene aerogels with low density, while maintaining high electrical conductivity and strong mechanic performance, we synthesized graphene aerogels by the magnesiothermic reduction of a freeze-dried graphene oxide （GO） self-assembly and subsequent etching of the formed MgO in acid solution. The reduced graphene oxide （rGO） aerogel samples exhibited densities as low as 1.1 mg·cm^-3. The rGO aerogel was very resilient, exhibiting full recoveryeven after being compressed by strains of up to 80%; its elastic modulus （E） scaled with density （p） as E-p^2. The rGO aerogels also exhibited high conductivities （e.g., 27.7 S·m^-1 at 3.6 mg·cm^-3） and outperformed many rGO aerogels fabricated by other reduction processes. Such outstanding properties were ascribed to the microstructures inherited from the freeze-dried GO self-assembly and the magnesiothermic reduction process.
基金support from the National Natural Science Foundation of China(51872204,52072261,and 22011540379)Shanghai Sailing Program(21YF1430900)+2 种基金the National Key Research and Development Program of China(2017YFA0204600)Shanghai Social Development Science and Technology Project(20dz1201800)supported by the National Natural Science Foundation(1803256)。
文摘V^(4+)-rich V_(2)O_(5)/carbon aerogel(V^(4+)-V_(2)O_(5)/CA)composites were synthesized as electrode materials for supercapacitors via in-situ hydrolysis-condensation processing.Carbon aerogel(CA)promotes the deposition of amorphous vanadium oxide and catalyzes the crystallization of V^(4+)-rich V_(2)O_(5)nanosheets at much reduced temperature.With a uniform distribution of V_(2)O_(5)nanosheets in CA,the special structure provides a large specific area and reactive sites.CA also synergistically improves the electrical conductivity and structural integrity.In addition,rich V^(4+) would enhance the intrinsic electrical conductivity of V_(2)O_(5),promote ion diffusion and catalyze the electrochemical reactions.Consequently,V^(4+)-V_(2)O_(5)/CA exhibits much enhanced specific capacitance(405 F g^(-1) at 0.5 A g^(-1)),high energy density(56 W h kg^(-1) with a power density of 250 W kg^(-1))and long cycle life(96%capacitance retention after 40,000 cycles).
基金supported by the National Natural Science Foundation of China(51872204,52072261 and 22011540379)the National Key Research and Development Program of China(2017YFA0204600)+1 种基金Shanghai Social Development Science and Technology Project(20dz1201800)Shanghai Sailing Program(21YF1430900).
文摘Co_(2)VO_(4) with Co tetrahedrons and octahedrons of transition metal oxides has achieved progress in electrocatalysts and batteries.However,high metal-metal interactions make it challenging to maintain high reactivity as well as increase the conductivity and stability of supercapacitors.In this work,spinel-structured CoZn_(0.5)V_(1.5)O_(4) with a high specific surface area was synthesized through an ion-exchange process from the metal-organic frameworks of zinc-cobalt.Density functional theory calculations indicate that the replacement of transition metal by Zn can decrease the interaction between the transition metals,leading to a downshift in the π^(∗)-orbitals(V-O)and half-filled a_(1g) orbitals near the Fermi level,thus increasing the conductivity and stability of CoZn_(0.5)V_(1.5)O_(4).As a supercapacitor electrode,CoZn_(0.5)V_(1.5)O_(4) exhibits high cycling durability(99.4% capacitance retention after 18,000 cycles)and specific capacitance(1100mFcm^(-2) at 1mAcm^(-2)).This work provides the possibility of designing octahedral and tetrahedral sites in transition metal oxides to improve their electrochemical performance.
基金This research was supported by the Max Planck Society,DFG grant SI 1695/1-2(SPP1356)NIH grant R01HD059946-01 from the Eunice Kennedy Shriver National Institute of Child Health&Human Development.We thank Areti Malapetsas for final editing。
文摘Oct4 is a key component of the pluripotency regulatory network,and its reciprocal interaction with Cdx2 has been shown to be a determinant of either the self-renewal of embryonic stem cells(ESCs)or their differentiation into trophoblast.Oct4 of maternal origin is postulated to play critical role in defining totipotency and inducing pluripotency during embryonic development.However,the genetic elimination of maternal Oct4 using a Cre-lox approach in mouse revealed that the establishment of totipotency in maternal Oct4–depleted embryos was not affected,and that these embryos could complete full-term development without any obvious defect.These results indicate that Oct4 is not essential for the initiation of pluripotency,in contrast to its critical role in maintaining pluripotency.This conclusion is further supported by the formation of Oct4-GFP–and Nanog-expressing inner cell masses(ICMs)in embryos with complete inactivation of both maternal and zygotic Oct4 expression and the reprogramming of fibroblasts into fully pluripotent cells by Oct4-deficient oocytes.
基金supported by National Science Foundation of China(32225012)National Key R&D Program of China(2019YFA0110200)+5 种基金Health@Inno HK Program launched by Innovation Technology Commission of the Hong Kong SAR,China,Youth Innovation Promotion Association,Chinese Academy of Sciences(Jie Wang),National Science Foundation of China(32000414,32000503,and 32000501)The Science and Technology Program of Guangzhou 201804020052 and 202102021039the Pearl River Talent Recruitment Program(2021ZT09Y233)Basic Research Project of Guangzhou Institutes of Biomedicine and Health,Chinese Academy of Sciences,(GIBHBRP23-01,GIBHBRP23-02)Frontier Science Research Program of the CAS ZDBS-LY-SM007Science and Technology Planning Project of Guangdong Province,China(2023B1212060050 and 2023B1212120009)。
文摘KMT2D,a H3K4me1 methyltransferase primarily regulating enhancers,is a leading cause of KABUKI syndrome.This multisystem disorder leads to craniofacial and cognitive abnormalities,possibly through neural crest and neuronal lineages.However,the impacted cell-of-origin and molecular mechanism of KMT2D during the development of KABUKI disease remains unknown.Here we have optimized a brain organoid model to investigate neural crest and neuronal differentiation.To pinpoint KMT2D's enhancer target,we developed a genome-wide cis-regulatory element explorer(GREE)based on single-cell multiomic integration.Single cell RNA-seq revealed that KMT2D-knockout(KO)and patient-derived organoids exhibited neural crest deformities and GABAergic overproduction.Mechanistically,GREE identified that KMT2D targets a roof-plate-like niche cell and activates the niche cell-specific WNT3A enhancer,providing the microenvironment for neural crest and neuronal development.Interestingly,KMT2D-mutated mice displayed decreased WNT3A expression in the diencephalon roof plate,indicating impaired niche cell function.Deleting the WNT3A enhancer in the organoids presented phenotypic similarities to KMT2D-depletion,emphasizing the WNT3A enhancer as the predominant target of KMT2D.Conversely,reactivating WNT signaling in KMT2D-KO rescued the lineage defects by restoring the microenvironment.Overall,our discovery of KMT2D's primary target provides insights for reconciling complex phenotypes of KABUKI syndrome and establishes a new paradigm for dissecting the mechanisms of genetic disorders from genotype to phenotype.
基金financially supported by the National Natural Science Foundation of China (52002059 and 51872204)the Belt&Road Young Scientist Exchanges Project of Science and Technology Commission Foundation of Shanghai (20520741000)+3 种基金Shanghai Belt and Road Joint Laboratory of Advanced Fiber and Lowdimension Materials (Donghua University)(18520750400)the Fundamental Research Funds for the Central Universities (20D110631)DHU Distinguished Young Professor Program (LZA2019001)the Open Research Fund of Shanghai Center for High Performance Fibers and Composites and Center for Civil Aviation Composites of Donghua University
文摘Vanadium nitride(VN)-based materials have been investigated as negative electrode materials for supercapacitors(SCs)owing to their high theoretical capacitances and suitable negative potential windows.However,viable VNbased negative electrode materials suffer from irreversible electrochemical oxidation of the soluble vanadium species,leading to rapid capacitance fading when operated in aqueous electrolytes.Developing a versatile approach to enhance the stability of VN in aqueous electrolytes is still a challenge.Here,an interface engineering strategy is developed to intentionally introduce surface nanolayers of vanadium oxides(VO_(x))as a reactive template on the VN surface to formulate welldesigned polypyrrole@VNO(Ppy@VNO)core-shell nanowires(NWs)incorporated into a 3D porous N-doped graphene(NG)hybrid aerogel as a durable negative electrode for SCs.Experimental and theoretical investigations reveal that the in-situ constructed Ppy@VNO core-shell host can offer more efficient pathways for rapid electron/ion transport and accessible electroactive sites.Most importantly,a reversible surface redox reaction is realized through the transformation of the valence state of V,and a long cyclic stability is achieved.The Ppy@VNO/NG hybrid aerogel can deliver a high specific capacitance of 650 F g^(-1) at 1 A g^(-1) with approximately 70.7%capacitance retention(up to the twenty-fold current density),and an excellent cycling stability without any capacitance decay after 10,000 cycles at both low and high current densities(1 and 10 A g^(-1),respectively).This work paves the way for the development of advanced electrode materials for SCs.
