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均相和非均相催化微藻脂质提取和酯交换制备生物燃料的研究进展
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作者 Vinoth kumar Ponnumsamy Hussein E.Al-Hazmi +9 位作者 Sutha Shobana Jeyaprakash Dharmaraja Dipak Ashok Jadhav Rajesh Banu J Grzegorz Piechota Bartłomiej Igliński Vinod kumar Amit Bhatnagar Kyu-Jung Chae gopalakrishnan kumar 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第4期97-117,共21页
随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化... 随着化石燃料燃烧导致的二氧化碳排放不断加剧气候变化,且化石燃料储量日益减少,寻求可再生能源已成为一项紧迫的任务.其中,藻类衍生可持续燃料因具有成本优势和可运输性,在解决全球能源危机方面展现出广阔前景,备受关注.利用化学转化技术从微藻中提取脂质,并通过酯交换反应可以将其转化为脂肪酸甲酯,是生产绿色生物燃料的有效途径.这一过程涉及游离脂肪酸、磷脂和甘油三酯的提取,并且生产过程能耗低,成为满足日益增长的能源需求的一种理想解决方案.本文综述了微藻脂质提取和酯交换制备生物燃料的相关研究进展.首先,介绍了微藻脂质的提取方法,包括溶剂提取法、索氏提取法、布利格和戴耶法、超临界二氧化碳提取以及离子液体溶剂法等,并分析了各方法的优缺点.随后,重点阐述了酯交换技术在微藻脂质转化中的应用,包括酸碱催化、酶催化以及原位酯交换反应等,并探讨了这些技术的反应机理、催化剂选择、反应器设计以及生物油生产工艺等方面的研究进展.通过综述上述研究进展,为微藻脂质的生产和应用提供了理论指导.研究表明,通过优化催化剂种类、反应条件以及提取方法,可以有效提高微藻脂质的转化效率和生物油品质.同时,本文也指出了当前微藻脂质生产中面临的挑战,如微藻栽培和生长条件优化、高效转化技术的开发等.随着可持续能源日益受到重视,微藻脂质作为一种可再生能源具有巨大的发展潜力.未来研究应进一步关注微藻的规模化栽培、生长条件优化以及高效转化技术的研发,以提高微藻脂质的产量和品质.同时,应进一步推动和实现微藻生物燃料的实际应用,从而为应对气候变化和能源危机提供有效的解决方案. 展开更多
关键词 微藻 脂质提取 酯交换 催化 酶催化 原位技术
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C4二醇的发酵生产及其化学催化升级为高价值化学品的研究进展 被引量:1
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作者 Abhishek R.Varma Bhushan S.Shrirame +5 位作者 Sunil K.Maity Deepti Agrawal Naglis Malys Leonardo Rios-Solis gopalakrishnan kumar Vinod kumar 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2023年第9期99-126,共28页
化石资源的过度消耗导致能源和环境污染问题,迫切需要科研人员开发出可持续、低能耗、绿色低碳的化学品生产技术.生物技术利用“细胞工厂”,以生物质等可再生资料为原料生产基础化学品,是以化石资源为原料的合成方法的潜在替代方案.然而... 化石资源的过度消耗导致能源和环境污染问题,迫切需要科研人员开发出可持续、低能耗、绿色低碳的化学品生产技术.生物技术利用“细胞工厂”,以生物质等可再生资料为原料生产基础化学品,是以化石资源为原料的合成方法的潜在替代方案.然而,利用生物技术生产全系列石化产品存在其自身的局限性,因此,人们对集成/混合方法越来越感兴趣,该方法先采用生物技术对生物质升级,再通过化学催化的途径使其转化为含有活性官能团的产物.本文主要综述了C4二醇的三种重要结构异构体,2,3-、1,3-和1,4-丁二醇的生物生产方法,目前这些异构体主要通过石化路线生产,全球市场需求不断增长.首先,从集成方法的原理出发,总结了上述二醇的生物法生产现状,包括底物、微生物、发酵技术和代谢/途径工程和发酵技术.然后,全面总结了C4二醇催化升级以生产系列产物的最新研究进展,讨论了催化剂中不同活性位点对催化活性、产物选择性和催化剂稳定性的影响.此外,给出了集成方法的具体实例,解决开发C4二醇生物生产工艺的相关挑战,强调通过直接催化转化方法对其升级所存在的困难.最后,对C4二醇的发酵生产及其化学催化升级为高价值化学品的相关研究进行总结,对未来发展进行展望,并指出将生物催化和化学催化方法相结合对于拓宽生物质升级转化产物范围具有重要作用. 展开更多
关键词 丁二醇 发酵 代谢工程 多相催化 1 3-丁二烯 3-丁烯-1-醇 3-丁烯-2-醇 甲乙酮
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Hydrogen Smart-Grids: Smart Metering of Electricity from Hydrogen Fuel Cells
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作者 gopalakrishnan kumar Serhan Demirci Chiu-Yue Lin 《Journal of Sustainable Bioenergy Systems》 2013年第2期160-162,共3页
In the last decade, increasing applications of information technology (IT) within power industry has become a significant reality. As distributed power networks are gaining importance and renewables are getting a bigg... In the last decade, increasing applications of information technology (IT) within power industry has become a significant reality. As distributed power networks are gaining importance and renewables are getting a bigger ratio within energy production, Smart Grid applications have become essential, especially due to the intermittent nature of renewable energy resources. Smart Grid is a sustainable energy system that measures, checks, and controls the generation, transmission, and consumption of electrical energy in grids on all voltage levels. Smart Grid experts are driving forward the development of effective communication and information technologies for the build-up of intelligent power supply networks. Examples of these are control systems for the realization of virtual power plants, intelligent consumer data acquisition systems, and smart distribution management systems. Fuel cell-based hydrogen electricity, in comparison to other renewable energy sources, is more stable and predictable. Yet hydrogen power and smart-grids have many application points, mainly as means of energy storage. This study claims that hydrogen energy and smart-grids could also engage through an appliance of IT managed metering of hydrogen power production. Smart metering and management of hydrogen fuel cells would enable advanced planning of short-to-mid-term power productions and thus foster use of hydrogen power within distributed networks, as local community or industrial applications. 展开更多
关键词 Smart Grids FUEL Cell-Based HYDROGEN ELECTRICITY VIRTUAL Power PLANTS
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Biotechnological valorization of algal biomass:an overview
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作者 A.Naresh kumar Jeong-Jun Yoon +1 位作者 gopalakrishnan kumar Sang-Hyoun Kim 《Systems Microbiology and Biomanufacturing》 2021年第2期131-141,共11页
Algal biomass has significant advantages over terrestrial plants in terms of CO2 sequestration,biomass productivity,waste-water treatment along with multiple biobased products synthesis.Metabolic versatility and high ... Algal biomass has significant advantages over terrestrial plants in terms of CO2 sequestration,biomass productivity,waste-water treatment along with multiple biobased products synthesis.Metabolic versatility and high carbohydrate content of microalgal biomass act as a potential alternative feedstock to fossil resources and contribute towards the biobased economy growth.Effective biomass utilization would play a key role to establish sustainable bioprocess development and technology translation to the industrial community.In this framework,the present review discusses the renewable resource potential of algal biomass and its complete utilization for multiple biobased products synthesis in a closed-loop biorefinery approach.Various methods are discussed to obtain high biomass growth and pretreatments to obtain the maximum sugars solubiliza-tion.Further,combined bioprocesses were discussed for the production of biohydrogen,biomethane,bioethanol,short-chain fatty acids(SCFA),medium-chain fatty acids(MCFA),and biopolymers in a closed-loop approach. 展开更多
关键词 Algal biomass BIOREFINERY BIOECONOMY Closed loop BIOHYDROGEN
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Bioelectrochemical system-mediated waste valorization
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作者 K.Chandrasekhar A.Naresh kumar +2 位作者 Tirath Raj gopalakrishnan kumar Sang-Hyoun Kim 《Systems Microbiology and Biomanufacturing》 2021年第4期432-443,共12页
Bioelectrochemical systems(BESs)are a new and emerging technology in the field of fermentation technology.Electrical energy was provided externally to the microbial electrolysis cells(MECs)to generate hydrogen or valu... Bioelectrochemical systems(BESs)are a new and emerging technology in the field of fermentation technology.Electrical energy was provided externally to the microbial electrolysis cells(MECs)to generate hydrogen or value-added chemicals,including caustic,formic acid,acetic acid,and peroxide.Also,BES was designed to recover nutrients,metals or remove recalcitrant compounds.The variety of naturally existing microorganisms and enzymes act as a biocatalyst to induce poten-tial differences amid the electrodes.BESs can be performed with non-catalyzed electrodes(both anode and cathode)under favorable circumstances,unlike conventional fuel cells.In recent years,value-added chemical producing microbial electrosyn-thesis(MES)technology has intensely broadened the prospect for BES.An additional strategy includes the introduction of innovative technologies that help with the manufacturing of alternative materials for electrode preparation,ion-exchange membranes,and pioneering designs.Because of this,BES is emerging as a promising technology.This article deliberates recent signs of progress in BESs so far,focusing on their diverse applications beyond electricity generation and resulting performance. 展开更多
关键词 Microbial fuel cells Waste valorization Microbial electrolysis cell WASTE-TO-ENERGY Biofuels
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