A novel polymeric dye of aqueous dispersion poly[urethane-(disperse blue 14)-urethane] was synthesized based on poly(propylene glycol) (PPG), 2, 4-tolylene diisocyanate (TDI), klimethylol propionic acid (DMPA), disp...A novel polymeric dye of aqueous dispersion poly[urethane-(disperse blue 14)-urethane] was synthesized based on poly(propylene glycol) (PPG), 2, 4-tolylene diisocyanate (TDI), klimethylol propionic acid (DMPA), disperse blue 14 and triethylamine (TEA) depending on a modified acetone process. Fourier transform infrared spectroscopy (FTIR) was used to identify Lhe structure of the polymeric dye, indicating an obvious carbonyl stretching absorption in disperse blue 14. The polymer was also characterized by the analysis of DSC, TGA, WAXD and UV-Vis spectroscopy.展开更多
文摘A novel polymeric dye of aqueous dispersion poly[urethane-(disperse blue 14)-urethane] was synthesized based on poly(propylene glycol) (PPG), 2, 4-tolylene diisocyanate (TDI), klimethylol propionic acid (DMPA), disperse blue 14 and triethylamine (TEA) depending on a modified acetone process. Fourier transform infrared spectroscopy (FTIR) was used to identify Lhe structure of the polymeric dye, indicating an obvious carbonyl stretching absorption in disperse blue 14. The polymer was also characterized by the analysis of DSC, TGA, WAXD and UV-Vis spectroscopy.