This study focuses on the geology,geochemistry,zircon U-Pb geochronology and tectonic settings of the three types of seamount basalts from the Xingshuwa subduction accretionary complex in the Xar Moron area,eastern ma...This study focuses on the geology,geochemistry,zircon U-Pb geochronology and tectonic settings of the three types of seamount basalts from the Xingshuwa subduction accretionary complex in the Xar Moron area,eastern margin of the Central Asian Orogenic Belt(CAOB).The seamount remnants are composed of carbonate’cap’sediments,large volumes of pillow and massive basalts,carbonate breccia slope facies and radiolarian cherts.Group 1 basalts are characterized by high contents of P2 O5 and TiO2 with alkaline affinity and LREE enrichment,indicating that they are derived from intraplate magma.Group 2 basalts display N-MORB LREE depletion patterns,indicating that they were formed at a mid-ocean ridge.Group 3 basalts have shown distinct Nb depletion and high Th/Yb ratios,indicating that they were generated in an island arc tectonic setting.The zircon U-Pb age of Group 1 basalt sample XWT18-131 is 576.4±9.4 Ma,suggesting that the oceanic island seamount was the product of intraplate magmatism related to a mantle plume or’hot spot’in the late Neoproterozoic.The zircon U-Pb age of Group 2 basalt sample XWT18-132 is 483±22 Ma,indicating that the Paleo-Asian Ocean(PAO)was continuously expanding in the Early Ordovician.The zircon U-Pb age of Group 3 basalt sample XWT18-101 is 240.5±8.2 Ma,suggesting that this area underwent the evolutionary path of ocean-continent transition,developing towards continentalization during the Middle Triassic.Thus,we believe that there was both mantle plume-related intraplate magmatism and intraoceanic subduction during the evolution of the PAO,the CAOB possibly being an evolutionary model of an intraoceanic subduction and mantle plume magmatism complex.展开更多
Varying the flow rate of natural gas from 50 to 80 to 120 l/h, isotropic pyrocarbon produced by hot wall chemical vapor deposition at 1000 ℃ were examined by X-ray diffraction and Raman spectroscopy. The X-ray data w...Varying the flow rate of natural gas from 50 to 80 to 120 l/h, isotropic pyrocarbon produced by hot wall chemical vapor deposition at 1000 ℃ were examined by X-ray diffraction and Raman spectroscopy. The X-ray data were evaluated by Scherrer equation, and the intensity ratio of D to G band derived from Raman data was used to evaluate the lateral extension of isotropic pyrocarbon. The experimental results show that the d002-spacing of isotropic pyroearbon decreases from 0.3499 nm to 0.3451 nm, while the stack height increases from 6.5 to 8.4 nm with the increase of flow rate of natural gas. The intensity ratio of D to G band and lateral extension of isotropie pyrocarbon increases with natural gas flow rate increasing. After heat treatment, all the crystallite parameters (stack height, lateral extension, and d002-spacing) decrease, indicating the improvement of the arrangement of the basic structural units of isotropic pyrocarbon.展开更多
Carbon nanotubes(CNTs) were deposited uniformly on carbon cloth by electrophoretic deposition(EPD). Thereafter, CNT-doped clothes were stacked and densified by pyrocarbon via chemical vapor infiltration to fabrica...Carbon nanotubes(CNTs) were deposited uniformly on carbon cloth by electrophoretic deposition(EPD). Thereafter, CNT-doped clothes were stacked and densified by pyrocarbon via chemical vapor infiltration to fabricate two-dimensional(2 D) carbon/carbon(C/C) composites. Effects of EPD CNTs on interlaminar shear performance and mode Ⅱ interlaminar fracture toughness(GⅡc) of 2 D C/C composites were investigated. Results showed that EPD CNTs were uniformly covered on carbon fibers, acting as a porous coating. Such a CNT coating can obviously enhance the interlaminar shear strength and GⅡc of 2 D C/C composites. With increaing EPD CNTs, the interlaminar shear strength and GⅡc of 2 D C/C composites increase greatly and then decrease, both of which run up to their maximum values, i e, 13.6 MPa and 436.0 J·m-2, when the content of EPD CNTs is 0.54 wt%, 2.27 and 1.45 times of the baseline. Such improvements in interlaminar performance of 2 D C/C composites are mainly beneficial from their increased cohesion of interlaminar matrix, which is caused not only by the direct reinforcing effect of EPD CNT network but also by the capacity of EPD CNTs to refine pyrocarbon matrix and induce multilayered microstructures that greatly increase the crack propagation resistance through "crack-blocking and-deflecting mechanisms".展开更多
基金financially supported by the Inner Mongolia Autonomous Region Geological and Mineral Exploration Fund(Grant Nos.2017-YS01,2020-YS01)。
文摘This study focuses on the geology,geochemistry,zircon U-Pb geochronology and tectonic settings of the three types of seamount basalts from the Xingshuwa subduction accretionary complex in the Xar Moron area,eastern margin of the Central Asian Orogenic Belt(CAOB).The seamount remnants are composed of carbonate’cap’sediments,large volumes of pillow and massive basalts,carbonate breccia slope facies and radiolarian cherts.Group 1 basalts are characterized by high contents of P2 O5 and TiO2 with alkaline affinity and LREE enrichment,indicating that they are derived from intraplate magma.Group 2 basalts display N-MORB LREE depletion patterns,indicating that they were formed at a mid-ocean ridge.Group 3 basalts have shown distinct Nb depletion and high Th/Yb ratios,indicating that they were generated in an island arc tectonic setting.The zircon U-Pb age of Group 1 basalt sample XWT18-131 is 576.4±9.4 Ma,suggesting that the oceanic island seamount was the product of intraplate magmatism related to a mantle plume or’hot spot’in the late Neoproterozoic.The zircon U-Pb age of Group 2 basalt sample XWT18-132 is 483±22 Ma,indicating that the Paleo-Asian Ocean(PAO)was continuously expanding in the Early Ordovician.The zircon U-Pb age of Group 3 basalt sample XWT18-101 is 240.5±8.2 Ma,suggesting that this area underwent the evolutionary path of ocean-continent transition,developing towards continentalization during the Middle Triassic.Thus,we believe that there was both mantle plume-related intraplate magmatism and intraoceanic subduction during the evolution of the PAO,the CAOB possibly being an evolutionary model of an intraoceanic subduction and mantle plume magmatism complex.
基金Funded by the National Natural Science Foundation of China(Nos.50832004 and 50972120)the Program of Introducing Talents of Discipline to University(No.B080404)
文摘Varying the flow rate of natural gas from 50 to 80 to 120 l/h, isotropic pyrocarbon produced by hot wall chemical vapor deposition at 1000 ℃ were examined by X-ray diffraction and Raman spectroscopy. The X-ray data were evaluated by Scherrer equation, and the intensity ratio of D to G band derived from Raman data was used to evaluate the lateral extension of isotropic pyrocarbon. The experimental results show that the d002-spacing of isotropic pyroearbon decreases from 0.3499 nm to 0.3451 nm, while the stack height increases from 6.5 to 8.4 nm with the increase of flow rate of natural gas. The intensity ratio of D to G band and lateral extension of isotropie pyrocarbon increases with natural gas flow rate increasing. After heat treatment, all the crystallite parameters (stack height, lateral extension, and d002-spacing) decrease, indicating the improvement of the arrangement of the basic structural units of isotropic pyrocarbon.
基金Funded by the National Natural Science Foundation of China(Nos.51432008,51202194 and 51502242)the Fund of the State Key Laboratory of Solidification Processing in NWPU(No.SKLSP201637)the Key Grant Project of the Chinese Ministry of Education(No.313047)
文摘Carbon nanotubes(CNTs) were deposited uniformly on carbon cloth by electrophoretic deposition(EPD). Thereafter, CNT-doped clothes were stacked and densified by pyrocarbon via chemical vapor infiltration to fabricate two-dimensional(2 D) carbon/carbon(C/C) composites. Effects of EPD CNTs on interlaminar shear performance and mode Ⅱ interlaminar fracture toughness(GⅡc) of 2 D C/C composites were investigated. Results showed that EPD CNTs were uniformly covered on carbon fibers, acting as a porous coating. Such a CNT coating can obviously enhance the interlaminar shear strength and GⅡc of 2 D C/C composites. With increaing EPD CNTs, the interlaminar shear strength and GⅡc of 2 D C/C composites increase greatly and then decrease, both of which run up to their maximum values, i e, 13.6 MPa and 436.0 J·m-2, when the content of EPD CNTs is 0.54 wt%, 2.27 and 1.45 times of the baseline. Such improvements in interlaminar performance of 2 D C/C composites are mainly beneficial from their increased cohesion of interlaminar matrix, which is caused not only by the direct reinforcing effect of EPD CNT network but also by the capacity of EPD CNTs to refine pyrocarbon matrix and induce multilayered microstructures that greatly increase the crack propagation resistance through "crack-blocking and-deflecting mechanisms".