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1,4-Bis(2-nitrobenzylidene) thiosemicarbazide as Effective Corrosion Inhibitor for Mild Steel 被引量:3
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作者 P.Mohan g.paruthimal kalaignan 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2013年第11期1096-1100,共5页
The inhibition efficiency of 1,4-bis (2-nitrobenzylidene) thiosemicarbazide (BBTS) on the corrosion of mild steel in 1 mol/L HCI was investigated by potentiodynamic polarization and electrochemical impedance metho... The inhibition efficiency of 1,4-bis (2-nitrobenzylidene) thiosemicarbazide (BBTS) on the corrosion of mild steel in 1 mol/L HCI was investigated by potentiodynamic polarization and electrochemical impedance methods. Inhibition efficiency (IE), corrosion rate and surface coverage were evaluated at different concentrations of BBTS. The results of the investigation showed that this compound had good inhibiting properties for mild steel corrosion in hydrochloric acid and BBTS was a mixed-type inhibitor. BBTS chemisorbed at the electrode surface obeyed Langmuir adsorption isotherm and formed a stable surface complex on the mild steel surface. The synergistic effect of halide ion in acid solution suggested a co-adsorption of BBTS inhibitor by the adsorbed iodide ion. 展开更多
关键词 Acid inhibition POLARIZATION Langmuir adsorption Electrochemical impedance spectroscopy (EIS)
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直流、单向脉冲和换向脉冲法制备镍-钴-碳化钨复合镀层的比较(英文)
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作者 Ranjith Bose g.paruthimal kalaignan K.N.Srinivasan 《电镀与涂饰》 CAS CSCD 北大核心 2013年第3期9-13,共5页
在醋酸盐镀液体系中采用直流(DC)、单向脉冲电流(PC)和换向脉冲电流(PRC)3种方法制备了Ni-Co-WC复合镀层。采用扫描电镜及电化学阻抗谱(EIS)表征了镀层的微观组织及耐蚀性。结果表明,镀层的微观结构及性能受镀层中WC含量的影响很大。在... 在醋酸盐镀液体系中采用直流(DC)、单向脉冲电流(PC)和换向脉冲电流(PRC)3种方法制备了Ni-Co-WC复合镀层。采用扫描电镜及电化学阻抗谱(EIS)表征了镀层的微观组织及耐蚀性。结果表明,镀层的微观结构及性能受镀层中WC含量的影响很大。在最佳WC含量的情况下,镀层的显微硬度及耐蚀性都明显提高。与PC和DC法制备的复合镀层相比,PRC法制备的复合镀层具有更致密的表面,更高的显微硬度以及更好的耐蚀性。 展开更多
关键词 镍-钴合金 碳化钨 复合镀层 显微硬度 电化学 表面形貌
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