The work aims to investigate the formation and transformation mechanism of non-basal texture in the extruded Mg alloys.With this purpose a pure Mg as reference and eight Mg-Gd binary alloys with the Gd concentration r...The work aims to investigate the formation and transformation mechanism of non-basal texture in the extruded Mg alloys.With this purpose a pure Mg as reference and eight Mg-Gd binary alloys with the Gd concentration ranging from 0.5 wt.%to 18 wt.%were prepared for extrusion.This study shows that the basal fiber texture in pure Mg transited into RE(rare earth)texture in diluted Mg-Gd alloys and into the abnormal C-texture in high-concentration Mg-Gd alloys.In pure Mg,discontinuous dynamic recrystallization plays a predominant role during the extrusion process,resulting in the formation of a typical basal fiber texture.Alloying with high concentration of Gd impedes the dynamic recrystallization process,facilitating the heterogeneous nucleation of shear bands as well as the dynamic recrystallization within shear bands.Dynamic recrystallized grains within shear bands nucleate with a similar orientation to the host deformed parent grains and gradually tilt their c-axis to the extrusion direction during growth by absorbing dislocations,leading to the formation of either the REtexture orientation or the C-texture orientation,depending on the stored energy within shear bands.The analysis aided by IGMA and TEM characterization reveals that the shear bands originate from the extensive but heterogeneous activation of pyramidal I slip.Tensile tests illustrate a close correlation between the fracture elongation and texture types.A comprehensive understanding of the formation and transformation mechanism of different texture components in Mg alloys holds significant importance for the design of high-performance Mg alloys by texture engineering.展开更多
YSi alloy is a promising candidate as oxidation resistant coatings for both the bond coat of environmental barrier coatings(EBCs)and anti-ablation coatings at a high temperature of∼1300℃.In this study,a one-step mul...YSi alloy is a promising candidate as oxidation resistant coatings for both the bond coat of environmental barrier coatings(EBCs)and anti-ablation coatings at a high temperature of∼1300℃.In this study,a one-step multi-compositional oxidation by rapid heating oxidation mode is proposed to reduce the oxidation rate by 3.6 times compared to conventional slow heating oxidation mode.Results show that preferentially formed Y_(2)O_(3) oxide initiates a multi-step oxidation,produces a cracking and porous oxides,and thereby resulting in a fast oxidation with pesting.The one-step multi-compositional oxidation with a compact and dense Y_(2)Si_(2)O_(7)scale contributes to the much better oxidation resistance for rapid heating oxidation mode of YSi alloy.The stable formation of Y_(2)Si_(2)O_(7)scale is comprehensively understood by the energy barrier,charge density and electronic level based on density functional theory.This study demonstrates a promising application of YSi alloy by rapid heating oxidation mode.展开更多
基金funding from the National Natural Science Foundation of China under Grant No 52275327。
文摘The work aims to investigate the formation and transformation mechanism of non-basal texture in the extruded Mg alloys.With this purpose a pure Mg as reference and eight Mg-Gd binary alloys with the Gd concentration ranging from 0.5 wt.%to 18 wt.%were prepared for extrusion.This study shows that the basal fiber texture in pure Mg transited into RE(rare earth)texture in diluted Mg-Gd alloys and into the abnormal C-texture in high-concentration Mg-Gd alloys.In pure Mg,discontinuous dynamic recrystallization plays a predominant role during the extrusion process,resulting in the formation of a typical basal fiber texture.Alloying with high concentration of Gd impedes the dynamic recrystallization process,facilitating the heterogeneous nucleation of shear bands as well as the dynamic recrystallization within shear bands.Dynamic recrystallized grains within shear bands nucleate with a similar orientation to the host deformed parent grains and gradually tilt their c-axis to the extrusion direction during growth by absorbing dislocations,leading to the formation of either the REtexture orientation or the C-texture orientation,depending on the stored energy within shear bands.The analysis aided by IGMA and TEM characterization reveals that the shear bands originate from the extensive but heterogeneous activation of pyramidal I slip.Tensile tests illustrate a close correlation between the fracture elongation and texture types.A comprehensive understanding of the formation and transformation mechanism of different texture components in Mg alloys holds significant importance for the design of high-performance Mg alloys by texture engineering.
基金financially supported by the Aero En-gine Corporation of China Industry-University-Research Coopera-tion Project(NO.HFZL2019CXY015)the Natural Science Foun-dation of Suzhou(No.SYG202103).
文摘YSi alloy is a promising candidate as oxidation resistant coatings for both the bond coat of environmental barrier coatings(EBCs)and anti-ablation coatings at a high temperature of∼1300℃.In this study,a one-step multi-compositional oxidation by rapid heating oxidation mode is proposed to reduce the oxidation rate by 3.6 times compared to conventional slow heating oxidation mode.Results show that preferentially formed Y_(2)O_(3) oxide initiates a multi-step oxidation,produces a cracking and porous oxides,and thereby resulting in a fast oxidation with pesting.The one-step multi-compositional oxidation with a compact and dense Y_(2)Si_(2)O_(7)scale contributes to the much better oxidation resistance for rapid heating oxidation mode of YSi alloy.The stable formation of Y_(2)Si_(2)O_(7)scale is comprehensively understood by the energy barrier,charge density and electronic level based on density functional theory.This study demonstrates a promising application of YSi alloy by rapid heating oxidation mode.
