Mg_(x)(Ni_(0.8)La_(0.2))_(100-x),where x=60,70,80,exhibiting a nanocrystalline microstructure,were prepared through the crystallization of amorphous alloys.The investigation encompassed the phase constitution,grain si...Mg_(x)(Ni_(0.8)La_(0.2))_(100-x),where x=60,70,80,exhibiting a nanocrystalline microstructure,were prepared through the crystallization of amorphous alloys.The investigation encompassed the phase constitution,grain size,microstructural stability,and hydrogen storage properties.Crystallization kinetics,along with in-situ high-energy XRD characterization,revealed a concentrated and synchronous crystallization of Mg_(2)Ni and RE-Mg-Ni ternary phases with the increase in La and Ni content.The attributed synchronous crystallization process was found to be a result of the close local affinity of Mg_(2)Ni and RE-Mg-Ni ternary phases,as assessed by the thermodynamic Miedema model.Significant secondary phase pinning effect,arising from the high likelihood of well-matching phase structures between Mg_(2)Ni,LaMg_(2)Ni,and LaMgNi_(4),was validated through both the edge-to-edge matching model prediction and experimental observation.Thefine and homogeneous microstructure was shown to be a consequence of fast crystallization kinetics and the secondary phase pinning effect.Improved activation performance and cycling stability were observed,stemming from grain refinement and excellent microstructural stability.Our study provides insights into mechanism of grain refinement of nanocrystalline microstructure tailored by phase constitution and crystallization kinetics in the amorphous-crystallization route.We also demonstrate the potential of material design guided by phase equilibria and crystallographic predictions to improve nanocrystalline with excellent microstructural stability.展开更多
目的探讨双能量虚拟去钙成像(VNCa)CT对中轴性脊柱关节炎相关骶髂关节炎病人骨髓水肿的诊断价值。材料与方法这项前瞻性研究连续收集2016年4月—2017年12月期间47例受试者[年龄14~41岁,平均27岁(男28例,年龄14~37岁,平均24岁;女19例,年...目的探讨双能量虚拟去钙成像(VNCa)CT对中轴性脊柱关节炎相关骶髂关节炎病人骨髓水肿的诊断价值。材料与方法这项前瞻性研究连续收集2016年4月—2017年12月期间47例受试者[年龄14~41岁,平均27岁(男28例,年龄14~37岁,平均24岁;女19例,年龄17~41岁,平均29岁)],行双能CT和3.0 T MRI检查。展开更多
The microwave absorbents of Fe and C nanoparticles as magnetic loss and dielectric loss material respectively were composited with the polyvinyl alcohol(PVA)as binder by spray granulation method,The electromagnetic pa...The microwave absorbents of Fe and C nanoparticles as magnetic loss and dielectric loss material respectively were composited with the polyvinyl alcohol(PVA)as binder by spray granulation method,The electromagnetic parameters of Fe and C composite particles were analyzed by vector network.The complex permittivity and magnetic permeability of Fe and C composite particles matched well with increasing C nanoparticle content,and then the microwave loss property was improved.A minimum reflection loss(RL)of-42.7 dB at 3.68 GHz for a composite with 4.6 mm in thickness can be obtained when the content ratio of the C nanoparticles,the modified Fe nanoparticles and the PVA is 21:49:30(Sample 3).展开更多
基金supported by National Natural Science Foundation of China(51761034,51961032,51962028 and 52261041)Innovation Foundation of Inner Mongolia University of Science and Technology(2019YQL03)+2 种基金Major Science and Technology Project of Inner Mongolia(2021ZD0029)Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region(NJYT23005,NJYT23007)Program for Innovative Research Team in Universities of Inner Mongolia Autonomous Region(NMGIRT2401).
文摘Mg_(x)(Ni_(0.8)La_(0.2))_(100-x),where x=60,70,80,exhibiting a nanocrystalline microstructure,were prepared through the crystallization of amorphous alloys.The investigation encompassed the phase constitution,grain size,microstructural stability,and hydrogen storage properties.Crystallization kinetics,along with in-situ high-energy XRD characterization,revealed a concentrated and synchronous crystallization of Mg_(2)Ni and RE-Mg-Ni ternary phases with the increase in La and Ni content.The attributed synchronous crystallization process was found to be a result of the close local affinity of Mg_(2)Ni and RE-Mg-Ni ternary phases,as assessed by the thermodynamic Miedema model.Significant secondary phase pinning effect,arising from the high likelihood of well-matching phase structures between Mg_(2)Ni,LaMg_(2)Ni,and LaMgNi_(4),was validated through both the edge-to-edge matching model prediction and experimental observation.Thefine and homogeneous microstructure was shown to be a consequence of fast crystallization kinetics and the secondary phase pinning effect.Improved activation performance and cycling stability were observed,stemming from grain refinement and excellent microstructural stability.Our study provides insights into mechanism of grain refinement of nanocrystalline microstructure tailored by phase constitution and crystallization kinetics in the amorphous-crystallization route.We also demonstrate the potential of material design guided by phase equilibria and crystallographic predictions to improve nanocrystalline with excellent microstructural stability.
文摘目的探讨双能量虚拟去钙成像(VNCa)CT对中轴性脊柱关节炎相关骶髂关节炎病人骨髓水肿的诊断价值。材料与方法这项前瞻性研究连续收集2016年4月—2017年12月期间47例受试者[年龄14~41岁,平均27岁(男28例,年龄14~37岁,平均24岁;女19例,年龄17~41岁,平均29岁)],行双能CT和3.0 T MRI检查。
基金the support from the National Natural Science Foundation of China(No.51171033)the Fundamental Research Funds for the Central Universities(DUT15LAB05,DUT16LAB03)
文摘The microwave absorbents of Fe and C nanoparticles as magnetic loss and dielectric loss material respectively were composited with the polyvinyl alcohol(PVA)as binder by spray granulation method,The electromagnetic parameters of Fe and C composite particles were analyzed by vector network.The complex permittivity and magnetic permeability of Fe and C composite particles matched well with increasing C nanoparticle content,and then the microwave loss property was improved.A minimum reflection loss(RL)of-42.7 dB at 3.68 GHz for a composite with 4.6 mm in thickness can be obtained when the content ratio of the C nanoparticles,the modified Fe nanoparticles and the PVA is 21:49:30(Sample 3).
