In this work,one kind of typeⅡZnSe/CdS/ZnS core/shell/shell nanocrystals(NCs)is synthesized,and their linear and nonlinear photophysical properties are investigated.Through measurements of the temperaturedependent ph...In this work,one kind of typeⅡZnSe/CdS/ZnS core/shell/shell nanocrystals(NCs)is synthesized,and their linear and nonlinear photophysical properties are investigated.Through measurements of the temperaturedependent photoluminescence spectra of NCs,their excitonic properties,including the coefficient of the bandgap change,coupling strength of the exciton acoustic phonons,exciton longitudinal optical(LO)phonons,and LO–phonon energy are revealed.Femtosecond transient absorption spectroscopy was employed to obtain insight into ultrafast processes occurring at the interface of ZnSe and CdS,such as those involving the injection of photoinduced electrons into the CdS shell,interfacial state bleaching,and charge separation time.At the end,their multiphoton absorption spectra were determined by using the z-scan technique,which yielded a maximum twophoton absorption cross section of 3717 GM at 820 nm and three-photon absorption cross section up to 3.9×10^-77cm^6·s^2·photon^-2at 1220 nm,respectively.The photophysical properties presented here may be important for exploiting their relevant applications in optoelectronic devices and deep-tissue bioimaging.展开更多
The conjugate of R-phycoerythrin (R-PE) and C-phycocyanin (C-PC) was synthesized through a heterobifunctional coupling reagent, N-succinimidyl 3-(2-pyridyldithio) propionate. The molar ratio of R-PE to C-PC was determ...The conjugate of R-phycoerythrin (R-PE) and C-phycocyanin (C-PC) was synthesized through a heterobifunctional coupling reagent, N-succinimidyl 3-(2-pyridyldithio) propionate. The molar ratio of R-PE to C-PC was determined by absorption spectra, and the result was 2:1. The energy transfer phenomena were observed from steady-state fluorescence spectra. The calculated result showed that the energy transfer efficiency from R-PE to C-PC was 88%. The energy transfer kinetics was determined by picosecond time-resolved fluorescence spectra. The time constant of energy transfer from R-PE to C-PC was 80 ps, which was much longer than that in the rood of native phycobilisomes.展开更多
Time-integrated photoluminescence （PL） spectra between 1.2 and 2.25 eV of ZnO nanoparticles were observed at ambient temperatures when they were excited by a picosecond （ps） laser pulse at a low photon energy of 2...Time-integrated photoluminescence （PL） spectra between 1.2 and 2.25 eV of ZnO nanoparticles were observed at ambient temperatures when they were excited by a picosecond （ps） laser pulse at a low photon energy of 2.33 eV/532 rim, to show clear red shift when the excitation intensiW increased. Gaussian analysis shows that the red shift is due to increase of the relative magnitudes of the Gaussian combination in the low energy region. Temporal evolution of the dominant emissions exhibited a similar double-exponential decay process, in which the respective two distinct decay durations of 189 ps at the corresponding amplitude of 82% and 2081 ps at 18% were identified. Speculation based on the surfacestate emission due to the large surface-to-volume ratio of nanoscale materials is used to explain the phenomena.展开更多
A new model is proposed to study the interaactions among chromphores in APC trimer. Using this model, the electronic transition frequencies are calculated. The results are in good agreement with the experimental.
基金Natural Science Foundation of Guangdong Province(2018A030310637,2019A1515012094)Department of Education of Guangdong Province(2018KTSCX19)。
文摘In this work,one kind of typeⅡZnSe/CdS/ZnS core/shell/shell nanocrystals(NCs)is synthesized,and their linear and nonlinear photophysical properties are investigated.Through measurements of the temperaturedependent photoluminescence spectra of NCs,their excitonic properties,including the coefficient of the bandgap change,coupling strength of the exciton acoustic phonons,exciton longitudinal optical(LO)phonons,and LO–phonon energy are revealed.Femtosecond transient absorption spectroscopy was employed to obtain insight into ultrafast processes occurring at the interface of ZnSe and CdS,such as those involving the injection of photoinduced electrons into the CdS shell,interfacial state bleaching,and charge separation time.At the end,their multiphoton absorption spectra were determined by using the z-scan technique,which yielded a maximum twophoton absorption cross section of 3717 GM at 820 nm and three-photon absorption cross section up to 3.9×10^-77cm^6·s^2·photon^-2at 1220 nm,respectively.The photophysical properties presented here may be important for exploiting their relevant applications in optoelectronic devices and deep-tissue bioimaging.
文摘The conjugate of R-phycoerythrin (R-PE) and C-phycocyanin (C-PC) was synthesized through a heterobifunctional coupling reagent, N-succinimidyl 3-(2-pyridyldithio) propionate. The molar ratio of R-PE to C-PC was determined by absorption spectra, and the result was 2:1. The energy transfer phenomena were observed from steady-state fluorescence spectra. The calculated result showed that the energy transfer efficiency from R-PE to C-PC was 88%. The energy transfer kinetics was determined by picosecond time-resolved fluorescence spectra. The time constant of energy transfer from R-PE to C-PC was 80 ps, which was much longer than that in the rood of native phycobilisomes.
基金supported by the National Natural Science Foundation of China (Grant No.10574165)the Education Ministry of China,the Science and Technology Department of Guangdong Province,the Education Department of Guangdong Province,and the Science and Technology Department of Guangzhou City(2005A10701004)
文摘Time-integrated photoluminescence （PL） spectra between 1.2 and 2.25 eV of ZnO nanoparticles were observed at ambient temperatures when they were excited by a picosecond （ps） laser pulse at a low photon energy of 2.33 eV/532 rim, to show clear red shift when the excitation intensiW increased. Gaussian analysis shows that the red shift is due to increase of the relative magnitudes of the Gaussian combination in the low energy region. Temporal evolution of the dominant emissions exhibited a similar double-exponential decay process, in which the respective two distinct decay durations of 189 ps at the corresponding amplitude of 82% and 2081 ps at 18% were identified. Speculation based on the surfacestate emission due to the large surface-to-volume ratio of nanoscale materials is used to explain the phenomena.
文摘A new model is proposed to study the interaactions among chromphores in APC trimer. Using this model, the electronic transition frequencies are calculated. The results are in good agreement with the experimental.
