The contact between contaminant and washing solution is a fundamental factor that limits the contaminant removal efficiency of chemical washing.In this study,the magnetization technique was employed to improve the phy...The contact between contaminant and washing solution is a fundamental factor that limits the contaminant removal efficiency of chemical washing.In this study,the magnetization technique was employed to improve the physicochemical properties of ethylene diamine tetraacetic acid(EDTA)solutions for the removal of lead(Pb)and cadmium(Cd)from a contaminated clayey soil.Furthermore,EDTA concentration,magnetization strength,and magnetization time were varied as parameters for enhancing the contact between contaminant and washing solution to improve remediation efficiency.The results showed that after magnetization,the viscosities,surface tensions,and contact angles of EDTA solutions decreased,whereas the electrical conductivity and pH increased.In particular,the viscosities of high-concentration EDTA solutions increased with increasing magnetic field strength and magnetization time.The magnetized EDTA solutions increased the maximum removal rates of Cd and Pb by 64.46% and 35.49%,respectively,compared to the unmagnetized EDTA solutions.The results highlighted the efficient metal removal by magnetized washing solutions due to the better contact between the washing solutions and the contaminants.The magnetic-enhanced soil washing method was proven to be efficient,cost-effective,and easily implementable for enhancing heavy metal removal.This study provides a valuable reference for improving the efficiency of chemical washing for heavy metal-contaminated clayey soils.展开更多
Rational interface engineering via regulating the anchoring groups between molecular catalysts and light-absorbing semiconductors is essential and emergent to stabilize the semiconductor/molecular complex interaction ...Rational interface engineering via regulating the anchoring groups between molecular catalysts and light-absorbing semiconductors is essential and emergent to stabilize the semiconductor/molecular complex interaction and facilitate the photocarriers transport,thus realizing highly active and stable photoelectrochemical(PEC)water splitting.In this mini review,following a showcasing of the fundamental details of hybrid PEC systems containing semiconductor photoelectrodes and molecular catalysts for water splitting,the state-of-the-art progress of anchoring group regulation at semiconductor/molecular complex interface for efficient and stable PEC water splitting,as well as its effect on charge transfer kinetics,are comprehensively reviewed.Finally,potential research directions aimed at building high-efficiency hybrid PEC water splitting systems are summarized.展开更多
Layered rocks(LR)exhibit inherent anisotropic stiffness and strength induced by oriented rough weakness planes,along with stress induced anisotropy and friction related plastic deformation occurs during loading.Furthe...Layered rocks(LR)exhibit inherent anisotropic stiffness and strength induced by oriented rough weakness planes,along with stress induced anisotropy and friction related plastic deformation occurs during loading.Furthermore,microcracks located in intact rock matrix(IRM)of LR are also critically important for friction and damage dissipation processes.In this paper,we first present a novel multiscale friction-damage(MFD)model using a two-step Mori-Tanaka homogenization scheme,with the aim of describing the multiscale friction-damage mechanics in LR.Physically,the initiation and propagation of flaws at different scales(i.e.microcracks and weakness planes)induced damage,and the plastic deformation is closely associated with frictional sliding along these flaws.In the thermodynamics framework,the macroscopic stress-strain relations,the local driving forces respectively conjuncted with flaws propagation and plastic deformation are derived.An analytical macroscopic strength criterion is subsequently deduced,which takes into account the variation of inclination angle and confining pressure.Notably,the failure mechanisms of IRM shearing and weakness planes sliding are inherent included in the criterion.As an original contribution,a new multisurface semi-implicit return mapping algorithm(MSRM)is developed to integrate the proposed MFD model.The robustness of MSRM algorithm is assessed by numerical tests with different loading steps sizes and convergence conditions.Finally,the effectiveness of the MFD model is confirmed using data from experiments under conventional triaxial compression,all main features of mechanical behaviors of LR are well captured by the proposed model,including initial anisotropy,stress-induced anisotropy and strain hardening/softening.展开更多
The Haerbin-Dalian Passenger Dedicated Line is the first high-speed railway constructed in the seasonally frozen ground regions of northeastern China. Frost heave diseases occurred in the first winter of its operation...The Haerbin-Dalian Passenger Dedicated Line is the first high-speed railway constructed in the seasonally frozen ground regions of northeastern China. Frost heave diseases occurred in the first winter of its operation （between October 2012 and January 2013）, and frost heave was observed mainly in the roadbed fills that were considered not susceptible to frost heave. This paper proposes applying two special pavements -- black pavement and insulation-black pavement -- to improve the thermal regime of the roadbed. Three numerical models of the roadbed temperature field were built based on the field con- ditions of the Changchun section （D3K692＋840 to D3K692＋860）. The results show that： （1） Compared with cement pave- ment, black pavement and insulation-black pavement could reduce the freezing index at the roadbed surface by 37% and 64%, respectively, which could influence the maximum frozen depth; （2） the maximum frozen depths under the black pavement and insulation-black pavement were respectively 1.3-1.4 m and 1 m. Compared with cement pavement, they could reduce the maximum frozen depth by 0.4 m and 0.7-0.8 m, respectively, which would reduce the permitted amount of frost heave by 4 mm and 7-8 ram, which would meet the deformation limit established by the Code for Design on Special Subgrade of Railway; （3） the freezing periods of the black pavement and the insulation-black pavement were, respectively, approximately four months and two months. Compared with cement pavement, they could reduce the freezing period by approximately 19 days and 40 days, respectively, and delay the initial freezing time by 9 days and 18 days; and （4） compared with cement pavement, black pavement and black-insulation pavement could reduce the frozen areas of roadbeds in the cold season, which suggests that these two special pavements could provide better thermal stability for roadbeds.展开更多
For the purpose of enhancing air convection and controlling solar radiation, a new crushed-rock slope embankment design combined with a sun-shade measure is proposed. A newly designed embankment was constructed in the...For the purpose of enhancing air convection and controlling solar radiation, a new crushed-rock slope embankment design combined with a sun-shade measure is proposed. A newly designed embankment was constructed in the Tuotuohe section of the Qinghai-Tibet Railway and a field-testing experiment was carried out to determine its convection and temperature characteristics. The results show that distinct air convection occurred in the crushed-rock layer of the new embankment, especially in cold seasons, which was enhanced when it flowed upwards along the slope. This preliminarily indicated that the new design of the embankment slope was good for reinforcing air convection in the crushed-rock layer. The frequent fluctuations of the convection speed and the environmental wind speed were in good agreement, suggesting that the convection in the crushed rock primarily came from the ambient wind. It was also preliminarily determined that the new embankment had a better cooling effect and sun-shade effect for decreasing the temperature of the embankment slope compared with a traditional crushed-rock slope embankment, and the mean temperature difference between them was up to 1.7 °C. The mean annual temperature at the bottom boundary of the crushed-rock layer was obviously lower than that at the top boundary, and heat flux calculation showed that the shallow soil beneath the embankment slope was weakly releasing heat, all of which indicated that the new embankment slope design was beneficial to the thermal stability of the embankment. This study is helpful in providing some references for improved engineering design and maintenance of roadbeds in permafrost regions.展开更多
Permafrost thickness under identical climates in cold regions can vary significantly because it is severely affected by climate change, topography, soil physical and thermal properties, and geothermal conditions. This...Permafrost thickness under identical climates in cold regions can vary significantly because it is severely affected by climate change, topography, soil physical and thermal properties, and geothermal conditions. This study numerically in- vestigates the response of ground thermal regime and talik development processes to permafrost with different thicknesses under a thermokarst lake on the Qinghai-Tibet Plateau. On the basis of observed data and information from a representative monitored lake in the Beiluhe Basin, we used a heat transfer model with phase change under a cylindrical coordinate system to conduct three simulation cases with permafrost thicknesses of 45 m, 60 m, and 75 m, respectively. The simulated results indicate that increases in permafrost thickness not only strongly retarded the open talik formation time, but also delayed the permafrost lateral thaw process after the formation of open talik. Increasing the permafrost thickness by 33.3% and 66.7% led to open talik formation time increases of 83.66% and 207.43%, respectively, and resulted in increases in the lateral thaw duration of permafrost under the modeled thermokarst lake by 28.86% and 46.54%, respectively, after the formation of the open taliks.展开更多
Under the rapidly warming climate in the Arctic and high mountain areas,permafrost is thawing,leading to various hazards at a global scale.One common permafrost hazard termed retrogressive thaw slump(RTS)occurs extens...Under the rapidly warming climate in the Arctic and high mountain areas,permafrost is thawing,leading to various hazards at a global scale.One common permafrost hazard termed retrogressive thaw slump(RTS)occurs extensively in ice-rich permafrost areas.Understanding the spatial and temporal distributive features of RTSs in a changing climate is crucial to assessing the damage to infrastructure and decision-making.To this end,we used a machine learning-based model to investigate the environmental factors that could lead to RTS occurrence and create a susceptibility map for RTS along the Qinghai-Tibet Engineering Corridor(QTEC)at a local scale.The results indicate that extreme summer climate events(e.g.,maximum air temperature and rainfall)contributes the most to the RTS occurrence over the flat areas with fine-grained soils.The model predicts that 13%(ca.22,948 km^(2))of the QTEC falls into high to very high susceptibility categories under the current climate over the permafrost areas with mean annual ground temperature at 10 m depth ranging from-3 to-1℃.This study provides insights into the impacts of permafrost thaw on the stability of landscape,carbon stock,and infrastructure,and the results are of value for engineering planning and maintenance.展开更多
This paper is a meta-analysis of recent domestic and foreign research on freezing-thawing effects on concrete durability. The main theories on the mechanisms of freeze-thaw damage to concrete are introduced： the hydr...This paper is a meta-analysis of recent domestic and foreign research on freezing-thawing effects on concrete durability. The main theories on the mechanisms of freeze-thaw damage to concrete are introduced： the hydrostatic pressure theory, the osmotic pressure theory, the critical water saturation degree theory, the dual mechanism theory, and the micro-ice-crystal lens model theory. The influence laws of freezing-thawing on the mechanical properties of concrete are summarized, and countermeasures to improve concrete durability in freezing-thawing circumstances are presented. This work provides valuable references for future engineering constructions in cold regions.展开更多
Most of the thermokarst lakes are spread appreciably in Beiluhe Basin,Qinghai-Tibet Plateau,China,where ice-rich permafrost exists.Two typical thermokarst lakes with differing area and depth were examined to ascertain...Most of the thermokarst lakes are spread appreciably in Beiluhe Basin,Qinghai-Tibet Plateau,China,where ice-rich permafrost exists.Two typical thermokarst lakes with differing area and depth were examined to ascertain their age.We obtained lake-bottom samples of 50 cm length from lake BLH-A and 25 cm length from lake BLH-B.Environmental 137 Cs and 210 Pb and radiocarbon age dating techniques were applied to the 50 cm and 25 cm samples,respectively.The results indicate that the initiation of BLH-A is about 800-900 a B.P.,and approximately 1,450±30 a B.P.to 2,230±30 a B.P.for BLH-B.These results will provide scientific bases for sedimentological study and thermokarst activity in Beiluhe Basin.展开更多
The Eighth International Symposium on Permafrost Engineering was held in Xi’an,China,October 2009.The major topics discussed in the symposium included:permafrost engineering(involving design,construction and evaluati...The Eighth International Symposium on Permafrost Engineering was held in Xi’an,China,October 2009.The major topics discussed in the symposium included:permafrost engineering(involving design,construction and evaluation);mitigation of frost hazards in the regions affected by seasonally frozen ground;properties of frozen soils,model development and their applications;frost hazards and periglacial environments in mountain and plateau regions;climatic,environmental and cryospheric changes;and permafrost hydrology,cold regions water resources and land uses.The papers submitted to the symposium and lectures during the meeting represented some new developments of research on cold region engineering and environment.Here we summarized the works of the symposium in topics including:Permafrost engineering;General geocryology;Properties of frozen soils:model development and their applications;And climatic,environmental and cryospheric changes.During the symposium,the attendees pointed out that future studies should pay more attention to theoretical study and engineering mechanism study,and also on interaction between climate change and cold region environments and their engineering affects.展开更多
Photocatalytic water oxidation based on semiconductors usually suffers from poor charge transfer from the bulk to the interface,which is necessary for oxygen generation.Here,we construct a hybrid artificial photosynth...Photocatalytic water oxidation based on semiconductors usually suffers from poor charge transfer from the bulk to the interface,which is necessary for oxygen generation.Here,we construct a hybrid artificial photosynthesis system for photocatalytic water oxidation.The system consists of BiVO4as the light harvester,a transitional metal complex(M(dca)2,M=Co,Ni,dca:dicyanamide)as the water oxidation catalyst,and S2O82?as a sacrificial electron acceptor.The system exhibits enhanced oxygen evolution activity when M(dca)2is introduced.The BiVO4/Co(dca)2and Bi‐VO4/Ni(dca)2systems exhibit excellent oxygen evolution rates of508.1and297.7μmol/(h·g)compared to the pure BiVO4which shows a photocatalytic oxygen evolution rate of252.2μmol/(h·g)during6h of photocatalytic reaction.Co(dca)2is found to be more effective than Ni(dca)2as a water oxidation catalyst.The enhanced photocatalytic performance is ascribed to the M(dca)2‐engineered BiVO4/electrolyte interface energetics,and to the M(dca)2‐catalyzed surface water oxidation.These two factors lead to a decrease in the energy barrier for hole transfer from the bulk to the surface of BiVO4,which promotes the water oxidation kinetics.展开更多
0 INTRODUCTION The Sixth Assessment Report of the Intergovernmental Panel on Climate Change(IPCC AR6)indicated that the global surface temperature had risen by approximately 1.09℃compared to the 1850-1900 average ove...0 INTRODUCTION The Sixth Assessment Report of the Intergovernmental Panel on Climate Change(IPCC AR6)indicated that the global surface temperature had risen by approximately 1.09℃compared to the 1850-1900 average over the past decade(IPCC,2021).The warming rate of air temperature in polar and high-elevation permafrost regions was found to be about two times higher than the average global warming rate(Liu et al.,2023;Hu et al.,2021).展开更多
A thermokarst lake is defined as a lake occupying a closed depression formed by ground settlement following thawing of ice-rich permafrost or the melting of massive ice. As it is the most visible morphologic landscape...A thermokarst lake is defined as a lake occupying a closed depression formed by ground settlement following thawing of ice-rich permafrost or the melting of massive ice. As it is the most visible morphologic landscape developed during the process of permafrost degradation, we reviewed recent literature on thermokarst studies, and summarized the main study topics as： development and temporal evolution, carbon release, and ecological and engineering influence of thermokarst lakes. The climate warming, forest fires, surface water pooling, geotectonic fault and anthropogenic activity are the main influencing factors that cause an increase of ground temperatures and melting of ice-rich permafrost, resulting in thermokarst lake formation. Normally a thermokarst lake develops in 3–5 stages from initiation to permafrost recovery. Geo-rectified aerial photographs and remote sensing images show that thermokarst lakes have been mainly experiencing the process of shrinkage or disappearance in most regions of the Arctic, while both lake numbers and areas on the Qinghai-Tibet Plateau have increased. Field studies and modeling indicates that carbon release from thermokarst lakes can feedback significantly to global warming, thus enhancing our understanding of the influences of thermokarst lakes on the ecological environment, and on regional groundwater through drainage. Based on field monitoring and numerical simulations, infrastructure stability can be affected by thermal erosion of nearby thermokarst lakes. This review was undertaken to enhance our understanding of thermokarst lakes, and providing references for future comprehensive studies on thermokarst lakes.展开更多
One of the main construction problems in permafrost regions is protecting permafrost thermal stability. Although ventilating ducts and crushed-rock layers were successfully used in railway embankment construction, the...One of the main construction problems in permafrost regions is protecting permafrost thermal stability. Although ventilating ducts and crushed-rock layers were successfully used in railway embankment construction, their effects might not meet large-width expressway requirements. The convection-intensifying composite embankment composed of perforated ventilation ducts and crushed-rock layers was numerically studied to investigate its cooling effects. Adopting a numerical model, the temperature fields for two kinds of composite embankment with and without air doors were analyzed considering air flow and heat transfer characteristics in porous media. The results show that wind velocity in the crushed-rock zone is intensified by the perforated ventilation duct. The underlying permafrost temperature obviously decreases, and the 0 °C isotherm position rises significantly due to composite embankment. The composite embankment with air doors is more effective than that without air doors. Therefore, the new convection-intensifying composite embankment is potentially a highly efficient cooling measure for construction in permafrost regions.展开更多
Wind is a great source of renewable energy in western Alaska.Consistent winds blow across the barren tundra underlain by warm permafrost in the winter season,when the energy demand is the highest.Foundation engineerin...Wind is a great source of renewable energy in western Alaska.Consistent winds blow across the barren tundra underlain by warm permafrost in the winter season,when the energy demand is the highest.Foundation engineering in warm permafrost has always been a challenge in wind energy development.Degrading warm permafrost poses engineering issues to design,construction,and operation of wind turbines.This paper describes the foundation design of a wind turbine built in western Alaska.It presents a system for response monitoring and load assessment,and data collected from September 2013 to March 2014.The dynamic properties are assessed based on the monitoring data,and seasonal changes in the dynamic properties of the turbine tower-foundation system and likely resonance between the spinning blades and the tower structure are discussed.These analyses of a wind turbine in warm permafrost are valuable for designing or retrofitting of foundations in warm permafrost.展开更多
Alpine soil infiltration process is an important part of the hydrological characteristics of alpine soil in permafrost. This research is carried out in the source region of the Yellow River where the permafrost is sev...Alpine soil infiltration process is an important part of the hydrological characteristics of alpine soil in permafrost. This research is carried out in the source region of the Yellow River where the permafrost is severely degraded, using various methods for choosing typical sample areas, and to experiment, study and simulate the soil water curve, soil saturated hydraulic conductivity, soil infiltration and soil moisture under different characteristics of degraded vegetation. The results indicate that the empirical equation θ=AS-B, proposed by Gradner and Visser, is very reliable in simulating the soil moisture curve; soil saturated hydraulic conductivity and soil infiltration are significantly different under different vegetation coverage： in the soil surface within 0-10 cm, the saturated hydraulic conductivity and infiltration intensity of Black Beach are the strongest; respectively, in soil layers below 30 cm, vegetation has almost no impacts on the saturated hydraulic conductivity, infiltration intensity and soil moisture content. Significant reduction of soil moisture occurs in soil surfaces with degraded vegetation. The more serious the degradation, the more water loss, and it can be up to 38.6% in the worst situation. Soil moisture of developed vegetation root systems in depths within 10-20 cm has the greatest impact on the soil environment, and the loss of moisture induces difficulty in the restoration of degraded meadows. Through a comparative study, the Kostiakov infiltration equationf（t） = at-b is more applicable for studies on the process of soil moisture infiltration of the alpine meadow in the source region of the Yellow River.展开更多
The drying process is a critical step in lithium-ion battery manufacturing,as it significantly impacts the porous structure and component distribution of electrodes.Despite its importance,the understanding of heat and...The drying process is a critical step in lithium-ion battery manufacturing,as it significantly impacts the porous structure and component distribution of electrodes.Despite its importance,the understanding of heat and mass transfer interactions across solid,liquid,and vapor phases remains incomplete.This review aims to provide a comprehensive overview of the heat and mass transfer processes involved in electrode drying,elucidating the underlying mechanisms and parameters that impact electrode quality.Following the showcasing of the electrode drying mechanism,the heat and mass transfer process is introduced.After a brief review of the influence of drying parameters,especially the drying temperature and rate,recent advances in simulation models at different scales are highlighted.In addition,AI-based modeling and optimization approaches relevant to the drying process are summarized,capturing the most recent advancements in digital electrode manufacturing.Finally,future challenges and research directions for further optimization of the drying process to ensure even component distribution and optimal electrode quality are discussed.By providing state-of-the-art strategies for optimized heat and mass transfer,this review could guide industrial production and ultimately enhance lithium-ion battery performance.展开更多
In the mountainous permafrost area,most thaw slumps are distributed in north or northeast-facing shady slope areas.It is commonly known that there is a heterogeneity in permafrost between diferent slope aspects,but th...In the mountainous permafrost area,most thaw slumps are distributed in north or northeast-facing shady slope areas.It is commonly known that there is a heterogeneity in permafrost between diferent slope aspects,but there has been a lack of detailed measured data to quantitatively evaluate their relationships,and in-depth understandings on how the slope aspects are linked to the distribution of thaw slumps.This study examined the heterogenous thermal regime,soil moisture content,and surface radiation at two slope sites with opposing aspects in a warming permafrost region on the Qinghai-Tibet Plateau(QTP).The results indicate that similar air temperatures(T_(a))were monitored on the two slopes,but there were signifcant diferences in ground temperature and moisture content in the active layer from 2016 to 2021.The sunny slope exhibited a higher mean annual ground surface temperature(T_(s)),and over the fve years the mean annual temperature at the top of permafrost was 1.3–1.4℃warmer on the sunny slope than the shady slope.On the contrary,the near-surface soil moisture content was about 10–13%lower on the sunny slope(~22–27%)than the shady slope(~35–38%)during the thawing season(June–September).Radiation data indicate that signifcantly higher shortwave downward radiation(DR)appeared at the sunny slope site.However,due to the greater surface albedo,the net radiation(Rn)was lower on the sunny slope.Slope aspect also afects the ground ice content due to its infuence on ground temperature,freeze-thaw cycles,and soil moisture.Shady slopes have a shallower burial of ice-rich permafrost compared to sunny slopes.The results highlight greatly diferent near-surface ground thermal conditions at the two slope sites with diferent aspects in a mountainous permafrost region.This helps identify the slope-related causes of increasing thaw slumps and provides a basis for predicting their future development.展开更多
The Qinghai-Xizang Railway has been operating safely for 16 years in the permafrost zone and the railroad subgrade is generally stable by adopting the cooling roadbed techniques.However,settlement caused by the degrad...The Qinghai-Xizang Railway has been operating safely for 16 years in the permafrost zone and the railroad subgrade is generally stable by adopting the cooling roadbed techniques.However,settlement caused by the degradation of subgrade permafrost in the embankment-bridge transition sections(EBTS)is one of the most representative and severe distresses.A feld survey on 440 bridges(including 880 EBTSs)was carried out employing terrestrial laser scanning and ground-penetrating radar for comprehensively assessing all EBTSs in the permafrost zone.The results show that the types of distresses of EBTSs were diferential settlement,upheaval mounds of the protection-cone slopes,subsidence of the protection-cone slopes,surface cracks of the protection cones and longitudinal and transverse dislocation of the wing walls.The occurrence rates of these distresses were 78.93,3.47,11.56,3.36,21.18 and 4.56%,respectively.The most serious problem was diferential settlement,and the average diferential settlement amount(ADSA)was 15.3 cm.Furthermore,the relationships between diferential settlement and 11 infuencing factors were examined.The results indicate that ADSA is greater on the northern side of a bridge than on the southern side and on the sunny slope than on the shady slope.It is also greater in the high-temperature permafrost region than in the low-temperature permafrost region and in the high-ice content area than in the low-ice content area.The EBTSs are more infuenced by ice content than by ground temperature.The ADSA increases when the embankment height increases,the particle size of subgrade soil decreases and the surface vegetation cover decreases.展开更多
基金the financial support from the National Natural Science Foundation of China(Nos.42471155,U2004181,and 41371092)partially supported by the Natural Science Foundation of Heilongjiang Province,China(No.LH2024D025)+2 种基金the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry,China(No.SKLFSE201917)the Key Scientific and Technological Project of Henan Province,China(No.192102310503)the National Key Scientific and Technological Project of Henan Province Office of Education,China(No.14B170007)。
文摘The contact between contaminant and washing solution is a fundamental factor that limits the contaminant removal efficiency of chemical washing.In this study,the magnetization technique was employed to improve the physicochemical properties of ethylene diamine tetraacetic acid(EDTA)solutions for the removal of lead(Pb)and cadmium(Cd)from a contaminated clayey soil.Furthermore,EDTA concentration,magnetization strength,and magnetization time were varied as parameters for enhancing the contact between contaminant and washing solution to improve remediation efficiency.The results showed that after magnetization,the viscosities,surface tensions,and contact angles of EDTA solutions decreased,whereas the electrical conductivity and pH increased.In particular,the viscosities of high-concentration EDTA solutions increased with increasing magnetic field strength and magnetization time.The magnetized EDTA solutions increased the maximum removal rates of Cd and Pb by 64.46% and 35.49%,respectively,compared to the unmagnetized EDTA solutions.The results highlighted the efficient metal removal by magnetized washing solutions due to the better contact between the washing solutions and the contaminants.The magnetic-enhanced soil washing method was proven to be efficient,cost-effective,and easily implementable for enhancing heavy metal removal.This study provides a valuable reference for improving the efficiency of chemical washing for heavy metal-contaminated clayey soils.
基金support of the Natural Science Foundation of Shaanxi Province(2023-JC-QN-0415)the Special Project on Functional Materials from Shaanxi Provincial Department of Finance(0801YC2305)+1 种基金the Talent Project from Northwest Institute for Non-ferrous Metal Research(YK2310)the National Natural Science Foundation of China(52225606 and 52304334).
文摘Rational interface engineering via regulating the anchoring groups between molecular catalysts and light-absorbing semiconductors is essential and emergent to stabilize the semiconductor/molecular complex interaction and facilitate the photocarriers transport,thus realizing highly active and stable photoelectrochemical(PEC)water splitting.In this mini review,following a showcasing of the fundamental details of hybrid PEC systems containing semiconductor photoelectrodes and molecular catalysts for water splitting,the state-of-the-art progress of anchoring group regulation at semiconductor/molecular complex interface for efficient and stable PEC water splitting,as well as its effect on charge transfer kinetics,are comprehensively reviewed.Finally,potential research directions aimed at building high-efficiency hybrid PEC water splitting systems are summarized.
基金jointly supported by Science and Technology Projects in Guangzhou(Grant No.SL2023A04J01079)Zhejiang ProvincialWater Conservancy Science and Technology Plan Project(Grant No.RC2405)Thematic Five of the Second Scientific Expedition of Qinghai-Tibet Plateau(Grant No.2019QZKK0905).
文摘Layered rocks(LR)exhibit inherent anisotropic stiffness and strength induced by oriented rough weakness planes,along with stress induced anisotropy and friction related plastic deformation occurs during loading.Furthermore,microcracks located in intact rock matrix(IRM)of LR are also critically important for friction and damage dissipation processes.In this paper,we first present a novel multiscale friction-damage(MFD)model using a two-step Mori-Tanaka homogenization scheme,with the aim of describing the multiscale friction-damage mechanics in LR.Physically,the initiation and propagation of flaws at different scales(i.e.microcracks and weakness planes)induced damage,and the plastic deformation is closely associated with frictional sliding along these flaws.In the thermodynamics framework,the macroscopic stress-strain relations,the local driving forces respectively conjuncted with flaws propagation and plastic deformation are derived.An analytical macroscopic strength criterion is subsequently deduced,which takes into account the variation of inclination angle and confining pressure.Notably,the failure mechanisms of IRM shearing and weakness planes sliding are inherent included in the criterion.As an original contribution,a new multisurface semi-implicit return mapping algorithm(MSRM)is developed to integrate the proposed MFD model.The robustness of MSRM algorithm is assessed by numerical tests with different loading steps sizes and convergence conditions.Finally,the effectiveness of the MFD model is confirmed using data from experiments under conventional triaxial compression,all main features of mechanical behaviors of LR are well captured by the proposed model,including initial anisotropy,stress-induced anisotropy and strain hardening/softening.
基金supported by the National Science and Technology Support Program (No. 2014BAG05B03)the National Key Basic Research Program of China (973 Program) (No. 2012CB026106)the Program for Innovative Research Group of the Natural Science Foundation of China (No. 41121061)
文摘The Haerbin-Dalian Passenger Dedicated Line is the first high-speed railway constructed in the seasonally frozen ground regions of northeastern China. Frost heave diseases occurred in the first winter of its operation （between October 2012 and January 2013）, and frost heave was observed mainly in the roadbed fills that were considered not susceptible to frost heave. This paper proposes applying two special pavements -- black pavement and insulation-black pavement -- to improve the thermal regime of the roadbed. Three numerical models of the roadbed temperature field were built based on the field con- ditions of the Changchun section （D3K692＋840 to D3K692＋860）. The results show that： （1） Compared with cement pave- ment, black pavement and insulation-black pavement could reduce the freezing index at the roadbed surface by 37% and 64%, respectively, which could influence the maximum frozen depth; （2） the maximum frozen depths under the black pavement and insulation-black pavement were respectively 1.3-1.4 m and 1 m. Compared with cement pavement, they could reduce the maximum frozen depth by 0.4 m and 0.7-0.8 m, respectively, which would reduce the permitted amount of frost heave by 4 mm and 7-8 ram, which would meet the deformation limit established by the Code for Design on Special Subgrade of Railway; （3） the freezing periods of the black pavement and the insulation-black pavement were, respectively, approximately four months and two months. Compared with cement pavement, they could reduce the freezing period by approximately 19 days and 40 days, respectively, and delay the initial freezing time by 9 days and 18 days; and （4） compared with cement pavement, black pavement and black-insulation pavement could reduce the frozen areas of roadbeds in the cold season, which suggests that these two special pavements could provide better thermal stability for roadbeds.
基金supported by the Western Project Program of the Chinese Academy of Sciences (No. KZCX2-XB3-19)the National Key Basic Research Program of China, 973 Program (No. 2012CB026101)
文摘For the purpose of enhancing air convection and controlling solar radiation, a new crushed-rock slope embankment design combined with a sun-shade measure is proposed. A newly designed embankment was constructed in the Tuotuohe section of the Qinghai-Tibet Railway and a field-testing experiment was carried out to determine its convection and temperature characteristics. The results show that distinct air convection occurred in the crushed-rock layer of the new embankment, especially in cold seasons, which was enhanced when it flowed upwards along the slope. This preliminarily indicated that the new design of the embankment slope was good for reinforcing air convection in the crushed-rock layer. The frequent fluctuations of the convection speed and the environmental wind speed were in good agreement, suggesting that the convection in the crushed rock primarily came from the ambient wind. It was also preliminarily determined that the new embankment had a better cooling effect and sun-shade effect for decreasing the temperature of the embankment slope compared with a traditional crushed-rock slope embankment, and the mean temperature difference between them was up to 1.7 °C. The mean annual temperature at the bottom boundary of the crushed-rock layer was obviously lower than that at the top boundary, and heat flux calculation showed that the shallow soil beneath the embankment slope was weakly releasing heat, all of which indicated that the new embankment slope design was beneficial to the thermal stability of the embankment. This study is helpful in providing some references for improved engineering design and maintenance of roadbeds in permafrost regions.
基金supported by the National Natural Science Foundation of China (NSFC) (No.41271076)the National Key Basic Research Program of China (No.2010CB951402)the Open Fund Project of the Institute of Plateau Meteorology, China Meteorological Administration (No.LPM2008019)
文摘Permafrost thickness under identical climates in cold regions can vary significantly because it is severely affected by climate change, topography, soil physical and thermal properties, and geothermal conditions. This study numerically in- vestigates the response of ground thermal regime and talik development processes to permafrost with different thicknesses under a thermokarst lake on the Qinghai-Tibet Plateau. On the basis of observed data and information from a representative monitored lake in the Beiluhe Basin, we used a heat transfer model with phase change under a cylindrical coordinate system to conduct three simulation cases with permafrost thicknesses of 45 m, 60 m, and 75 m, respectively. The simulated results indicate that increases in permafrost thickness not only strongly retarded the open talik formation time, but also delayed the permafrost lateral thaw process after the formation of open talik. Increasing the permafrost thickness by 33.3% and 66.7% led to open talik formation time increases of 83.66% and 207.43%, respectively, and resulted in increases in the lateral thaw duration of permafrost under the modeled thermokarst lake by 28.86% and 46.54%, respectively, after the formation of the open taliks.
基金funded by the National Natural Science Foundation of China(42372334)the Science and Technology Research and Development Program of the Qinghai-Tibet Group Corporation(Grant No.QZ2022-G05)。
文摘Under the rapidly warming climate in the Arctic and high mountain areas,permafrost is thawing,leading to various hazards at a global scale.One common permafrost hazard termed retrogressive thaw slump(RTS)occurs extensively in ice-rich permafrost areas.Understanding the spatial and temporal distributive features of RTSs in a changing climate is crucial to assessing the damage to infrastructure and decision-making.To this end,we used a machine learning-based model to investigate the environmental factors that could lead to RTS occurrence and create a susceptibility map for RTS along the Qinghai-Tibet Engineering Corridor(QTEC)at a local scale.The results indicate that extreme summer climate events(e.g.,maximum air temperature and rainfall)contributes the most to the RTS occurrence over the flat areas with fine-grained soils.The model predicts that 13%(ca.22,948 km^(2))of the QTEC falls into high to very high susceptibility categories under the current climate over the permafrost areas with mean annual ground temperature at 10 m depth ranging from-3 to-1℃.This study provides insights into the impacts of permafrost thaw on the stability of landscape,carbon stock,and infrastructure,and the results are of value for engineering planning and maintenance.
基金supported by the National Key Technology Support Program (No. 2014BAG05B05)the Basic Scientific Research Business from Institute of Earthquake Science, CEA (No. 2014IESLZ01)
文摘This paper is a meta-analysis of recent domestic and foreign research on freezing-thawing effects on concrete durability. The main theories on the mechanisms of freeze-thaw damage to concrete are introduced： the hydrostatic pressure theory, the osmotic pressure theory, the critical water saturation degree theory, the dual mechanism theory, and the micro-ice-crystal lens model theory. The influence laws of freezing-thawing on the mechanical properties of concrete are summarized, and countermeasures to improve concrete durability in freezing-thawing circumstances are presented. This work provides valuable references for future engineering constructions in cold regions.
基金supported by the State Key Development Program of Basic Research of China (973 Plan,2012CB026101)the Open Foundation of Key Laboratory of Highway Construction & Maintenance Technology in Permafrost Region,CCCC First Highway Consultants Co.Ltd.the Independent Project of State Key Laboratory of Frozen Soil Engineering,CAS (Grant No.SKLFSE-ZY-14)
文摘Most of the thermokarst lakes are spread appreciably in Beiluhe Basin,Qinghai-Tibet Plateau,China,where ice-rich permafrost exists.Two typical thermokarst lakes with differing area and depth were examined to ascertain their age.We obtained lake-bottom samples of 50 cm length from lake BLH-A and 25 cm length from lake BLH-B.Environmental 137 Cs and 210 Pb and radiocarbon age dating techniques were applied to the 50 cm and 25 cm samples,respectively.The results indicate that the initiation of BLH-A is about 800-900 a B.P.,and approximately 1,450±30 a B.P.to 2,230±30 a B.P.for BLH-B.These results will provide scientific bases for sedimentological study and thermokarst activity in Beiluhe Basin.
基金supported by The National Natural Science Foundation of China(Grant No.40910304019,40625004,40821001,40801024)Important Orientation Project of CAS(Grant No.KZCX2-YW-Q03-04)
文摘The Eighth International Symposium on Permafrost Engineering was held in Xi’an,China,October 2009.The major topics discussed in the symposium included:permafrost engineering(involving design,construction and evaluation);mitigation of frost hazards in the regions affected by seasonally frozen ground;properties of frozen soils,model development and their applications;frost hazards and periglacial environments in mountain and plateau regions;climatic,environmental and cryospheric changes;and permafrost hydrology,cold regions water resources and land uses.The papers submitted to the symposium and lectures during the meeting represented some new developments of research on cold region engineering and environment.Here we summarized the works of the symposium in topics including:Permafrost engineering;General geocryology;Properties of frozen soils:model development and their applications;And climatic,environmental and cryospheric changes.During the symposium,the attendees pointed out that future studies should pay more attention to theoretical study and engineering mechanism study,and also on interaction between climate change and cold region environments and their engineering affects.
基金supported by the National Natural Science Foundation of China (51672210, 51323011, 51236007)~~
文摘Photocatalytic water oxidation based on semiconductors usually suffers from poor charge transfer from the bulk to the interface,which is necessary for oxygen generation.Here,we construct a hybrid artificial photosynthesis system for photocatalytic water oxidation.The system consists of BiVO4as the light harvester,a transitional metal complex(M(dca)2,M=Co,Ni,dca:dicyanamide)as the water oxidation catalyst,and S2O82?as a sacrificial electron acceptor.The system exhibits enhanced oxygen evolution activity when M(dca)2is introduced.The BiVO4/Co(dca)2and Bi‐VO4/Ni(dca)2systems exhibit excellent oxygen evolution rates of508.1and297.7μmol/(h·g)compared to the pure BiVO4which shows a photocatalytic oxygen evolution rate of252.2μmol/(h·g)during6h of photocatalytic reaction.Co(dca)2is found to be more effective than Ni(dca)2as a water oxidation catalyst.The enhanced photocatalytic performance is ascribed to the M(dca)2‐engineered BiVO4/electrolyte interface energetics,and to the M(dca)2‐catalyzed surface water oxidation.These two factors lead to a decrease in the energy barrier for hole transfer from the bulk to the surface of BiVO4,which promotes the water oxidation kinetics.
基金supported by the National Natural Science Foundation of China(Nos.42371150,U2268216)the State Key Laboratory of Frozen Soil Engineering(No.SKLFSEZT-202116)+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Nos.2023445,2020421)the CAS Western Young Scholars Project to Dongliang Luo。
文摘0 INTRODUCTION The Sixth Assessment Report of the Intergovernmental Panel on Climate Change(IPCC AR6)indicated that the global surface temperature had risen by approximately 1.09℃compared to the 1850-1900 average over the past decade(IPCC,2021).The warming rate of air temperature in polar and high-elevation permafrost regions was found to be about two times higher than the average global warming rate(Liu et al.,2023;Hu et al.,2021).
基金support from the State Key Development Program of Basic Research of China(973 Plan,2012CB026101)the Western Project Program of theChinese Academy of Sciences(KZCX2-XB3-19)+1 种基金the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(GrantNo.41121061)the National Sci-Tech Support Plan(2014BAG05B05)
文摘A thermokarst lake is defined as a lake occupying a closed depression formed by ground settlement following thawing of ice-rich permafrost or the melting of massive ice. As it is the most visible morphologic landscape developed during the process of permafrost degradation, we reviewed recent literature on thermokarst studies, and summarized the main study topics as： development and temporal evolution, carbon release, and ecological and engineering influence of thermokarst lakes. The climate warming, forest fires, surface water pooling, geotectonic fault and anthropogenic activity are the main influencing factors that cause an increase of ground temperatures and melting of ice-rich permafrost, resulting in thermokarst lake formation. Normally a thermokarst lake develops in 3–5 stages from initiation to permafrost recovery. Geo-rectified aerial photographs and remote sensing images show that thermokarst lakes have been mainly experiencing the process of shrinkage or disappearance in most regions of the Arctic, while both lake numbers and areas on the Qinghai-Tibet Plateau have increased. Field studies and modeling indicates that carbon release from thermokarst lakes can feedback significantly to global warming, thus enhancing our understanding of the influences of thermokarst lakes on the ecological environment, and on regional groundwater through drainage. Based on field monitoring and numerical simulations, infrastructure stability can be affected by thermal erosion of nearby thermokarst lakes. This review was undertaken to enhance our understanding of thermokarst lakes, and providing references for future comprehensive studies on thermokarst lakes.
基金the financial support of the National Natural Science Foundation of China (No. 41121061)the National Basic Research Program (973) of China (Nos. 2012CB026101 and 2011CB013505)+1 种基金the Western Project Program of the Chinese Academy of Sciences (No. KZCX2-XB3-19)the Open Fund of State Key Laboratory of Frozen Soil Engineering (No. SKLFSE201209)
文摘One of the main construction problems in permafrost regions is protecting permafrost thermal stability. Although ventilating ducts and crushed-rock layers were successfully used in railway embankment construction, their effects might not meet large-width expressway requirements. The convection-intensifying composite embankment composed of perforated ventilation ducts and crushed-rock layers was numerically studied to investigate its cooling effects. Adopting a numerical model, the temperature fields for two kinds of composite embankment with and without air doors were analyzed considering air flow and heat transfer characteristics in porous media. The results show that wind velocity in the crushed-rock zone is intensified by the perforated ventilation duct. The underlying permafrost temperature obviously decreases, and the 0 °C isotherm position rises significantly due to composite embankment. The composite embankment with air doors is more effective than that without air doors. Therefore, the new convection-intensifying composite embankment is potentially a highly efficient cooling measure for construction in permafrost regions.
基金the support from the Western Project Program of the Chinese Academy of Sciences (KZCX2-XB3-19)the State Key Development Program of Basic Research of China (973 Plan, 2012CB026101)+1 种基金the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (Grant No. 41121061)the National Sci-Tech Support Plan (2014BAG05B05)
文摘Wind is a great source of renewable energy in western Alaska.Consistent winds blow across the barren tundra underlain by warm permafrost in the winter season,when the energy demand is the highest.Foundation engineering in warm permafrost has always been a challenge in wind energy development.Degrading warm permafrost poses engineering issues to design,construction,and operation of wind turbines.This paper describes the foundation design of a wind turbine built in western Alaska.It presents a system for response monitoring and load assessment,and data collected from September 2013 to March 2014.The dynamic properties are assessed based on the monitoring data,and seasonal changes in the dynamic properties of the turbine tower-foundation system and likely resonance between the spinning blades and the tower structure are discussed.These analyses of a wind turbine in warm permafrost are valuable for designing or retrofitting of foundations in warm permafrost.
基金supported by the Global Change Research Program of China (2010CB951404)in part by the Important Orientation Projects of the CAS (KZCX2-YW-Q03-04)+2 种基金The Outstanding Youth Foundation Project, National Natural ScienceFoundation of China (Grant No. 40625004)The State Key Program of National Natural Science of China (Grant No.41030741)The State Key Laboratory of Frozen Soil Engineering Open Fund (SKLFSE200804)
文摘Alpine soil infiltration process is an important part of the hydrological characteristics of alpine soil in permafrost. This research is carried out in the source region of the Yellow River where the permafrost is severely degraded, using various methods for choosing typical sample areas, and to experiment, study and simulate the soil water curve, soil saturated hydraulic conductivity, soil infiltration and soil moisture under different characteristics of degraded vegetation. The results indicate that the empirical equation θ=AS-B, proposed by Gradner and Visser, is very reliable in simulating the soil moisture curve; soil saturated hydraulic conductivity and soil infiltration are significantly different under different vegetation coverage： in the soil surface within 0-10 cm, the saturated hydraulic conductivity and infiltration intensity of Black Beach are the strongest; respectively, in soil layers below 30 cm, vegetation has almost no impacts on the saturated hydraulic conductivity, infiltration intensity and soil moisture content. Significant reduction of soil moisture occurs in soil surfaces with degraded vegetation. The more serious the degradation, the more water loss, and it can be up to 38.6% in the worst situation. Soil moisture of developed vegetation root systems in depths within 10-20 cm has the greatest impact on the soil environment, and the loss of moisture induces difficulty in the restoration of degraded meadows. Through a comparative study, the Kostiakov infiltration equationf（t） = at-b is more applicable for studies on the process of soil moisture infiltration of the alpine meadow in the source region of the Yellow River.
基金supported by the SYSU-Pengjin Joint Research Center for Advanced Energy Equipment and Intelligence(Grant No.SYSU-76280-20240426-0001)。
文摘The drying process is a critical step in lithium-ion battery manufacturing,as it significantly impacts the porous structure and component distribution of electrodes.Despite its importance,the understanding of heat and mass transfer interactions across solid,liquid,and vapor phases remains incomplete.This review aims to provide a comprehensive overview of the heat and mass transfer processes involved in electrode drying,elucidating the underlying mechanisms and parameters that impact electrode quality.Following the showcasing of the electrode drying mechanism,the heat and mass transfer process is introduced.After a brief review of the influence of drying parameters,especially the drying temperature and rate,recent advances in simulation models at different scales are highlighted.In addition,AI-based modeling and optimization approaches relevant to the drying process are summarized,capturing the most recent advancements in digital electrode manufacturing.Finally,future challenges and research directions for further optimization of the drying process to ensure even component distribution and optimal electrode quality are discussed.By providing state-of-the-art strategies for optimized heat and mass transfer,this review could guide industrial production and ultimately enhance lithium-ion battery performance.
基金This work was supported by the National Natural Science Foundation of China(42241109 and 42202297)Tsinghua University Initiative Scientific Research Program(20211080097).
基金supported by the Second Tibet Plateau Scientifc Expedition and Research Program(STEP)(Grant No.2019QZKK0905)the Gansu Province Science and Technology Major Special Projects(Grant No.22ZD6FA004)the National Natural Science Foundation of China(Grant No.41971089).
文摘In the mountainous permafrost area,most thaw slumps are distributed in north or northeast-facing shady slope areas.It is commonly known that there is a heterogeneity in permafrost between diferent slope aspects,but there has been a lack of detailed measured data to quantitatively evaluate their relationships,and in-depth understandings on how the slope aspects are linked to the distribution of thaw slumps.This study examined the heterogenous thermal regime,soil moisture content,and surface radiation at two slope sites with opposing aspects in a warming permafrost region on the Qinghai-Tibet Plateau(QTP).The results indicate that similar air temperatures(T_(a))were monitored on the two slopes,but there were signifcant diferences in ground temperature and moisture content in the active layer from 2016 to 2021.The sunny slope exhibited a higher mean annual ground surface temperature(T_(s)),and over the fve years the mean annual temperature at the top of permafrost was 1.3–1.4℃warmer on the sunny slope than the shady slope.On the contrary,the near-surface soil moisture content was about 10–13%lower on the sunny slope(~22–27%)than the shady slope(~35–38%)during the thawing season(June–September).Radiation data indicate that signifcantly higher shortwave downward radiation(DR)appeared at the sunny slope site.However,due to the greater surface albedo,the net radiation(Rn)was lower on the sunny slope.Slope aspect also afects the ground ice content due to its infuence on ground temperature,freeze-thaw cycles,and soil moisture.Shady slopes have a shallower burial of ice-rich permafrost compared to sunny slopes.The results highlight greatly diferent near-surface ground thermal conditions at the two slope sites with diferent aspects in a mountainous permafrost region.This helps identify the slope-related causes of increasing thaw slumps and provides a basis for predicting their future development.
基金supported by the Second Tibetan Plateau Scientifc Expedition and Research Program(STEP)(Grant No.2019QZKK0905)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA19070504)the Guangdong Provincial Key Laboratory of Modern Civil Engineering Technology(2021B1212040003).
文摘The Qinghai-Xizang Railway has been operating safely for 16 years in the permafrost zone and the railroad subgrade is generally stable by adopting the cooling roadbed techniques.However,settlement caused by the degradation of subgrade permafrost in the embankment-bridge transition sections(EBTS)is one of the most representative and severe distresses.A feld survey on 440 bridges(including 880 EBTSs)was carried out employing terrestrial laser scanning and ground-penetrating radar for comprehensively assessing all EBTSs in the permafrost zone.The results show that the types of distresses of EBTSs were diferential settlement,upheaval mounds of the protection-cone slopes,subsidence of the protection-cone slopes,surface cracks of the protection cones and longitudinal and transverse dislocation of the wing walls.The occurrence rates of these distresses were 78.93,3.47,11.56,3.36,21.18 and 4.56%,respectively.The most serious problem was diferential settlement,and the average diferential settlement amount(ADSA)was 15.3 cm.Furthermore,the relationships between diferential settlement and 11 infuencing factors were examined.The results indicate that ADSA is greater on the northern side of a bridge than on the southern side and on the sunny slope than on the shady slope.It is also greater in the high-temperature permafrost region than in the low-temperature permafrost region and in the high-ice content area than in the low-ice content area.The EBTSs are more infuenced by ice content than by ground temperature.The ADSA increases when the embankment height increases,the particle size of subgrade soil decreases and the surface vegetation cover decreases.
