The Fe-based amorphous alloy coatings with different porosities were deposited on Q235 steel substrates by means of atmospheric plasma spraying(APS).The as-sprayed coatings were remelted by the facility of a Nd:YAG la...The Fe-based amorphous alloy coatings with different porosities were deposited on Q235 steel substrates by means of atmospheric plasma spraying(APS).The as-sprayed coatings were remelted by the facility of a Nd:YAG laser to further enhance their compactness and bonding strength via orthogonal experiment design.The effects of laser remelting on the microstructure,phase compositions and mechanical properties of the as-sprayed coatings were investigated by optical microscopy,scanning electron microscope,X-ray diffraction and Vickers microhardness tester.The corrosion performance of the coatings was evaluated by both potential dynamic measurements(PDM)and electrochemical impedance spectroscopy(EIS)in a 10%NaOH solution.The results indicate that laser power of 700 W,scanning velocity of 4 mm/s,beam size of 3 mm and porosity of 1.19%are the optimized remelting process parameters.The laser-remelted coatings exhibite more homogenous structure as strong metallurgical bonding to substrates.The amorphous phases in the as-sprayed coatings crystallize toα-Fe,Fe2Si,Fe3.5B,and Fe2W phases for the high temperature and rapid solidification in the remelting process.The microhardness values of as-sprayed are in the range of 700-800 HV0.1,while the microhardness values of the remelted coatings are enhanced slightly to 750-850 HV0.1.Both PDM and EIS analysis results show that the remelted coatings exhibite relatively excellent corrosion resistance compared with the stainless steel 1Cr18Ni9Ti,however the corrosion resistance of the remelted coatings is inferior to the as-sprayed amorphous coatings.展开更多
基金National Natural Science Foundation of China(50805104)
文摘The Fe-based amorphous alloy coatings with different porosities were deposited on Q235 steel substrates by means of atmospheric plasma spraying(APS).The as-sprayed coatings were remelted by the facility of a Nd:YAG laser to further enhance their compactness and bonding strength via orthogonal experiment design.The effects of laser remelting on the microstructure,phase compositions and mechanical properties of the as-sprayed coatings were investigated by optical microscopy,scanning electron microscope,X-ray diffraction and Vickers microhardness tester.The corrosion performance of the coatings was evaluated by both potential dynamic measurements(PDM)and electrochemical impedance spectroscopy(EIS)in a 10%NaOH solution.The results indicate that laser power of 700 W,scanning velocity of 4 mm/s,beam size of 3 mm and porosity of 1.19%are the optimized remelting process parameters.The laser-remelted coatings exhibite more homogenous structure as strong metallurgical bonding to substrates.The amorphous phases in the as-sprayed coatings crystallize toα-Fe,Fe2Si,Fe3.5B,and Fe2W phases for the high temperature and rapid solidification in the remelting process.The microhardness values of as-sprayed are in the range of 700-800 HV0.1,while the microhardness values of the remelted coatings are enhanced slightly to 750-850 HV0.1.Both PDM and EIS analysis results show that the remelted coatings exhibite relatively excellent corrosion resistance compared with the stainless steel 1Cr18Ni9Ti,however the corrosion resistance of the remelted coatings is inferior to the as-sprayed amorphous coatings.
