This study is primary to develop relevant techniques for the bearing of wind turbine, such as the intelligent monitoring system, the performance assessment, future trend prediction and possible fault classification et...This study is primary to develop relevant techniques for the bearing of wind turbine, such as the intelligent monitoring system, the performance assessment, future trend prediction and possible fault classification etc. The main technique of system monitoring and diagnosis is divided into three algorithms, such as the performance assessment, performance prediction and fault diagnosis, respectively. Among them, the Logistic Regression (LR) is adopted to assess the bearing performance condition, the Autoregressive Moving Average (ARMA) is adopted to predict the future variation trend of bearing, and the Support Vector Machine (SVM) is adopted to classify and diagnose the possible fault of bearing. Through testing, this intelligent monitoring system can achieve real-time vibration monitoring, current performance assessment, future performance trend prediction and possible fault classification for the bearing of wind turbine. The monitor and analysis data and knowledge not only can be used as the basis of predictive maintenance, but also can be stored in the database for follow-up off-line analysis and used as the reference for improvement of operation parameter and wind turbine system design.展开更多
Herein,we report the first example showing the reversible on-off switching of spin-crossover(SCO)property by solid state photochemical[2+2]reaction.The ultraviolet(UV)light-induced[2+2]cycloaddition reaction of 3-spy ...Herein,we report the first example showing the reversible on-off switching of spin-crossover(SCO)property by solid state photochemical[2+2]reaction.The ultraviolet(UV)light-induced[2+2]cycloaddition reaction of 3-spy ligands in a twodimensional(2D)Hofmann-type framework[Fe(3-spy)_(2){Pd(CN)_(4)}](1,3-spy=3-styrylpyridine),which shows a hysteretic twostep SCO behavior,gives a 3D Hofmann-type framework[Fe(rctt-3-ppcb){Pd(CN)_(4)}](2,rctt-3-ppcb=rctt-1,3-bis(3-pyridyl)-2,4-bis(phenyl)cyclobutane,r=reference group,c=cis and t=trans)accompanied with the disappearing of SCO properties.Moreover,upon heating at 250℃ for 12 h,the rctt-3-ppcb ligand in 2 could be partially dedimerized to 3-spy with 68%completion through single-crystal-to-single-crystal(SCSC)transformation,giving the annealing complexes[Fe(3-spy)1.36(rctt-3-ppcb)0.32{Pd(CN)_(4)}](3)which display an incomplete SCO behavior.The 2■3 interconversion is successfully achieved via continuous UV irradiation and thermal annealing,demonstrating the effectiveness of photochemical[2+2]reaction on switching on-off SCO properties.展开更多
文摘This study is primary to develop relevant techniques for the bearing of wind turbine, such as the intelligent monitoring system, the performance assessment, future trend prediction and possible fault classification etc. The main technique of system monitoring and diagnosis is divided into three algorithms, such as the performance assessment, performance prediction and fault diagnosis, respectively. Among them, the Logistic Regression (LR) is adopted to assess the bearing performance condition, the Autoregressive Moving Average (ARMA) is adopted to predict the future variation trend of bearing, and the Support Vector Machine (SVM) is adopted to classify and diagnose the possible fault of bearing. Through testing, this intelligent monitoring system can achieve real-time vibration monitoring, current performance assessment, future performance trend prediction and possible fault classification for the bearing of wind turbine. The monitor and analysis data and knowledge not only can be used as the basis of predictive maintenance, but also can be stored in the database for follow-up off-line analysis and used as the reference for improvement of operation parameter and wind turbine system design.
基金supported by the National Key Research and Development Program of China(2018YFA0306001)the Nas tional Natural Sciences Foundation of China(21773316,21801258,21821003)the Pearl River Talent Plan of Guangdong(2017BT01C161)。
文摘Herein,we report the first example showing the reversible on-off switching of spin-crossover(SCO)property by solid state photochemical[2+2]reaction.The ultraviolet(UV)light-induced[2+2]cycloaddition reaction of 3-spy ligands in a twodimensional(2D)Hofmann-type framework[Fe(3-spy)_(2){Pd(CN)_(4)}](1,3-spy=3-styrylpyridine),which shows a hysteretic twostep SCO behavior,gives a 3D Hofmann-type framework[Fe(rctt-3-ppcb){Pd(CN)_(4)}](2,rctt-3-ppcb=rctt-1,3-bis(3-pyridyl)-2,4-bis(phenyl)cyclobutane,r=reference group,c=cis and t=trans)accompanied with the disappearing of SCO properties.Moreover,upon heating at 250℃ for 12 h,the rctt-3-ppcb ligand in 2 could be partially dedimerized to 3-spy with 68%completion through single-crystal-to-single-crystal(SCSC)transformation,giving the annealing complexes[Fe(3-spy)1.36(rctt-3-ppcb)0.32{Pd(CN)_(4)}](3)which display an incomplete SCO behavior.The 2■3 interconversion is successfully achieved via continuous UV irradiation and thermal annealing,demonstrating the effectiveness of photochemical[2+2]reaction on switching on-off SCO properties.
