High atomic economy is an aspirational target of the construction functional organic molecules,which is one of the core contents of green chemistry.The visible-light-driven copper-catalyzed synthesis of hydroxamates f...High atomic economy is an aspirational target of the construction functional organic molecules,which is one of the core contents of green chemistry.The visible-light-driven copper-catalyzed synthesis of hydroxamates from dioxazolones has been reported.This reaction possesses high atom economy,a catalyst loading as low as 5 mol%,mild reaction conditions,and a broad substrate scope with excellent yields.A mechanistic study reveals that cleavage of C-O bond might be involved in the reaction.展开更多
文摘High atomic economy is an aspirational target of the construction functional organic molecules,which is one of the core contents of green chemistry.The visible-light-driven copper-catalyzed synthesis of hydroxamates from dioxazolones has been reported.This reaction possesses high atom economy,a catalyst loading as low as 5 mol%,mild reaction conditions,and a broad substrate scope with excellent yields.A mechanistic study reveals that cleavage of C-O bond might be involved in the reaction.
