The chemical composition obviously affects the surface wettability of a three-dimensional(3D)graphene material apart from its surface energy and microstructure.In the hydrothermal preparation,the heteroatom doping cha...The chemical composition obviously affects the surface wettability of a three-dimensional(3D)graphene material apart from its surface energy and microstructure.In the hydrothermal preparation,the heteroatom doping changes the chemical composition and wettability of the 3D graphene material.To realize the controllable surface wettability of graphene materials,aminobenzene sulfonic acid(ABSA)was selected as a typical doping agent for the preparation of nitrogen and sulfur co-doped 3D graphene foam(SNGF)using a hydrothermal method.Different from using o-ABSA or p-ABSA as the dopant,SNGF with tunable surface wettability is obtained only when m-ABSA is used.This result indicates that the substituent position of-SO3H group in the benzene ring of ABSA is rather important for the tunable wettability.This work provides some theo retical foundations for dopant selection and some new insights in manipulating the properties of 3D graphene foams by adjusting the configuration of dopants.展开更多
Here,we show a cost-effective and environmentally friendly method for synthesizing iminofuranones using visible light and the photocatalyst 2-bromoanthraquinone.Our approach uses only oxygen as the oxidant,avoiding th...Here,we show a cost-effective and environmentally friendly method for synthesizing iminofuranones using visible light and the photocatalyst 2-bromoanthraquinone.Our approach uses only oxygen as the oxidant,avoiding the need for additional transition metals and strong oxidizing agents.By employing a mixed solvent system of DMF and CHCl_(3) under ambient conditions,we have achieved highly diastereoselective conversions of various 2-vinyl benzamides and alkenyl amides into functionalized iminoisobenzofuranones and iminofuranones.This versatile process is broadly applicable and enables late-stage structural modifications of complex substrates with bioactive moieties.展开更多
The stability of lead halide perovskite quantum dots （PQDs） was improved by embedding them in carboxybenzene microcrystals. The resulting needle-shaped mixed microcrystals preserved the strong photoluminescence of t...The stability of lead halide perovskite quantum dots （PQDs） was improved by embedding them in carboxybenzene microcrystals. The resulting needle-shaped mixed microcrystals preserved the strong photoluminescence of the PQDs. Compared with previously reported polystyrene-encapsulated PQDs, the carboxybenzene crystals were robust and protected the dots from moisture and photodegradation. The enhanced stability was attributed to the tight matrix of carboxybenzene microcrystals, which protected the PQDs from moisture. This versatile strategy protected various QDs, including all-inorganic PQDs and chalcogenide QDs （e.g., CdSe/ZnS QDs and CuInS/ZnS QDs）. It provides a facile and versatile method of protecting PQDs and may enable applications in solid-state systems with high color quality requirements such as displays, lasers, and light emitting diodes.展开更多
Perovskite nanocrystals （NCs）, which have emerged as a new class of phosphors with superb luminescence properties and bandgaps that can be easily tuned using chemical methods, have generated tremendous interest for ...Perovskite nanocrystals （NCs）, which have emerged as a new class of phosphors with superb luminescence properties and bandgaps that can be easily tuned using chemical methods, have generated tremendous interest for a wide variety of applications where colloidal quantum dots have been very successful as carrier sources. In this study, self-assembled films of CsPbBr3 NCs were produced via drop casting of colloidal NCs onto glassy carbon electrodes （GCEs） to form an NC film-modified electrode. The possible fabrication process of the CsPbBr3 NCs films was discussed. We further studied the anodic electrochemiluminescence （ECL） behavior of the perovskite CsPbBr3 NCs film using cyclic voltammetry with tripropylamine （TPA） as a coreactant, and a possible ECL mechanism was proposed. Briefly, TPA was oxidized to produce strongly reducing radical spedes, which can react with electrochemically oxidized CsPbBr3 NCs to generate excited CsPbBr3 NCs＊ capable of light emission. The relative stability of the ECL emission of the CsPbBr3 NC films under aqueous conditions was also investigated, and it was found that they showed operational stability over the first three hours, indicating suitable reliability for application as sensing materials. The results suggested that semiconducting perovskite NCs have great potential for application in the ECL field.展开更多
基金the National Natural Science Foundation of China(No.21675133)。
文摘The chemical composition obviously affects the surface wettability of a three-dimensional(3D)graphene material apart from its surface energy and microstructure.In the hydrothermal preparation,the heteroatom doping changes the chemical composition and wettability of the 3D graphene material.To realize the controllable surface wettability of graphene materials,aminobenzene sulfonic acid(ABSA)was selected as a typical doping agent for the preparation of nitrogen and sulfur co-doped 3D graphene foam(SNGF)using a hydrothermal method.Different from using o-ABSA or p-ABSA as the dopant,SNGF with tunable surface wettability is obtained only when m-ABSA is used.This result indicates that the substituent position of-SO3H group in the benzene ring of ABSA is rather important for the tunable wettability.This work provides some theo retical foundations for dopant selection and some new insights in manipulating the properties of 3D graphene foams by adjusting the configuration of dopants.
基金the National Natural Science Foundation of China(No.21502086)Natural Science Foundation of Fujian Province(Nos.2022J01902 and 2019J01744)+1 种基金Key Project of Foundation of Fujian Province(No.2020J02044)Natural Science Foundation of Zhangzhou City(No.ZZ2021J13).
文摘Here,we show a cost-effective and environmentally friendly method for synthesizing iminofuranones using visible light and the photocatalyst 2-bromoanthraquinone.Our approach uses only oxygen as the oxidant,avoiding the need for additional transition metals and strong oxidizing agents.By employing a mixed solvent system of DMF and CHCl_(3) under ambient conditions,we have achieved highly diastereoselective conversions of various 2-vinyl benzamides and alkenyl amides into functionalized iminoisobenzofuranones and iminofuranones.This versatile process is broadly applicable and enables late-stage structural modifications of complex substrates with bioactive moieties.
文摘The stability of lead halide perovskite quantum dots （PQDs） was improved by embedding them in carboxybenzene microcrystals. The resulting needle-shaped mixed microcrystals preserved the strong photoluminescence of the PQDs. Compared with previously reported polystyrene-encapsulated PQDs, the carboxybenzene crystals were robust and protected the dots from moisture and photodegradation. The enhanced stability was attributed to the tight matrix of carboxybenzene microcrystals, which protected the PQDs from moisture. This versatile strategy protected various QDs, including all-inorganic PQDs and chalcogenide QDs （e.g., CdSe/ZnS QDs and CuInS/ZnS QDs）. It provides a facile and versatile method of protecting PQDs and may enable applications in solid-state systems with high color quality requirements such as displays, lasers, and light emitting diodes.
基金This research was financially supported by the National Natural Science Foundation of China （No. 21675133）, the Marine high-tech industry development projects of Fujian Province （No. 2015-19）. We thank Professor John Hodgkiss of the City University of Hong Kong for polishing the English.
文摘Perovskite nanocrystals （NCs）, which have emerged as a new class of phosphors with superb luminescence properties and bandgaps that can be easily tuned using chemical methods, have generated tremendous interest for a wide variety of applications where colloidal quantum dots have been very successful as carrier sources. In this study, self-assembled films of CsPbBr3 NCs were produced via drop casting of colloidal NCs onto glassy carbon electrodes （GCEs） to form an NC film-modified electrode. The possible fabrication process of the CsPbBr3 NCs films was discussed. We further studied the anodic electrochemiluminescence （ECL） behavior of the perovskite CsPbBr3 NCs film using cyclic voltammetry with tripropylamine （TPA） as a coreactant, and a possible ECL mechanism was proposed. Briefly, TPA was oxidized to produce strongly reducing radical spedes, which can react with electrochemically oxidized CsPbBr3 NCs to generate excited CsPbBr3 NCs＊ capable of light emission. The relative stability of the ECL emission of the CsPbBr3 NC films under aqueous conditions was also investigated, and it was found that they showed operational stability over the first three hours, indicating suitable reliability for application as sensing materials. The results suggested that semiconducting perovskite NCs have great potential for application in the ECL field.
