This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels-Alder reaction of benzyne intermediates.The method achieves very good to excellent yields ...This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels-Alder reaction of benzyne intermediates.The method achieves very good to excellent yields of the respective anthracene derivative s under mild conditions.This practical protocol is compatible with a variety of sensitive functional groups and provides access to difunctionalized bridge 1,4-adducts/9,10-adducts.展开更多
基金the National Natural Science Foundation of China(Nos.21572002,21272005)The Research Culture Funds of Anhui Normal UniversityDepartment of Human Resources of Anhui Province for financial support。
文摘This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels-Alder reaction of benzyne intermediates.The method achieves very good to excellent yields of the respective anthracene derivative s under mild conditions.This practical protocol is compatible with a variety of sensitive functional groups and provides access to difunctionalized bridge 1,4-adducts/9,10-adducts.
