A simple method to synthesize luminescent λ^(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphino...A simple method to synthesize luminescent λ^(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphinocarboranylaldehydes with an electron-deficient alkyne,respectively.Similar results were obtained with the imino analogues.展开更多
基金the National Natural Science Foundation of China(Nos.21672193,21272218)Ministry of Industry and Information Technology of the People's Republic of China(No.Z135060009002)+1 种基金111 Project(No.D20003)Zhengzhou University of China for financial support of this research。
文摘A simple method to synthesize luminescent λ^(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphinocarboranylaldehydes with an electron-deficient alkyne,respectively.Similar results were obtained with the imino analogues.
