The metal triazole(MTA)-based MOFs were found to preferentially adsorb O-rich species,which had enhanced electrocatalytic oxygen reduction reactions(ORR)and stabilized the O-containing species during the discharge and...The metal triazole(MTA)-based MOFs were found to preferentially adsorb O-rich species,which had enhanced electrocatalytic oxygen reduction reactions(ORR)and stabilized the O-containing species during the discharge and charge processes in Li-O_(2)battery.However,the MOFs exhibited low electron conductivity and poor electron transfer interface in the electrocatalysis,limiting the electrocatalytic activity.To address this issue,a nanocomposite with the Co-MTA-coated carbon nano tubes(Co-MTA-C)was constructed,which formed the three-dimensional conductivity network connected with the intersecting carbon nano tube(CNT).In this composite,the electron-rich Co-MTA interacted with the highly conductive CNT,resulting in a charge redistribution.Optimized the electronic structure of the Co center through compositional modifications presented a high valence compared to the pure MOFs.In situ X-ray absorption spectroscopy revealed a direct reaction of Co sites with intermediates such as LiO_(x),leading to the formation of nanosheet array discharge products.The battery based on optimized CoMTA-C demonstrated fast kinetics and superior stability,with a low overpotential of 1.13 V,high specific capacity of 9057 mAh g^(-1),and long-term durability of 600 cycles.It provides a facile and effective strategy for enhancing the electrocatalytic performance through rational tuning of high-conductivity substances.展开更多
The rapid growth of neutron flux has driven the development of^(3)He-free neutron detectors to satisfy the requirements of the neutron scattering instruments under construction or planned at the China Spallation Neutr...The rapid growth of neutron flux has driven the development of^(3)He-free neutron detectors to satisfy the requirements of the neutron scattering instruments under construction or planned at the China Spallation Neutron Source(CSNS).Position-sensitive neutron detectors with a high counting rate and large area play an important role in the instruments performing neutron measurements in or close to the direct beam.The ceramic gas-electron-multiplier(GEM)detector serves as a promising solution,and considerable work has been done using the small-area GEM neutron detectors.In this article,we designed and constructed a detector prototype utilizing ceramic GEM foils with an effective area of about307 mm×307 mm.To evaluate and investigate their basic characteristics,the Monte Carlo(MC)tool FLUKA was employed and several neutron beam tests were conducted at CSNS.The simulated spatial resolution was basically in agreement with the measured value of 2.50±0.01 mm(FWHM).The wavelength spectra measurement was verified through comparisons with a commercial beam monitor.In addition,a detection efficiency of 4.7±0.1%was achieved for monoenergetic neutrons of 1.59 A wavelength.This is consistent with the simulated result.The results indicate that the large-area ceramic GEM detector is a good candidate to implement neutron beam measurements.Its efficiency can be improved in a cascading manner to approach that reached by traditional^(3)He detectors.展开更多
Objective:This study aimed to develop and evaluate a novel software tool for robust analysis of the Visually Enhanced Vestibular-Ocular Reflex(VVOR)and video head impulse test(vHIT)saccades.Methods:A retrospective stu...Objective:This study aimed to develop and evaluate a novel software tool for robust analysis of the Visually Enhanced Vestibular-Ocular Reflex(VVOR)and video head impulse test(vHIT)saccades.Methods:A retrospective study was conducted on 94 patients with Meniere’s Disease(MD),unilateral vestibular hypofunction(UVH),and vestibular migraine(VM).The MATLAB-based VVOR Analysis System and Saccades All in One software were utilized for data processing.New techniques,VVOR_diff and VVOR_cycle,were deployed for saccade parameter extraction.Results:Saccade incidence rates,examined through vHIT,VVOR_diff,and VVOR_cycle,exhibited distinct patterns in MD,UVH,and VM patients.Frequent instances of multiple saccades within a single cycle were noted on the affected side in MD and UVH patients.Statistically significant differences in saccade gain and incidence rates between the affected and unaffected sides were evident in MD and UVH patients.Notably,high inter-method and intra-method correlations suggested consistency across different methods and potential interactions within one.Conclusion:The software proved effective in extracting saccades and reducing noise in VVOR data,thereby enhancing the evaluation of vestibular function and potentially improving diagnostic accuracy for vestibular disorders.展开更多
基金financially supported by the National Natural Science Foundations of China(No.12304037)the Interdisciplinary Intelligence Super Computer Center of BNUZH
文摘The metal triazole(MTA)-based MOFs were found to preferentially adsorb O-rich species,which had enhanced electrocatalytic oxygen reduction reactions(ORR)and stabilized the O-containing species during the discharge and charge processes in Li-O_(2)battery.However,the MOFs exhibited low electron conductivity and poor electron transfer interface in the electrocatalysis,limiting the electrocatalytic activity.To address this issue,a nanocomposite with the Co-MTA-coated carbon nano tubes(Co-MTA-C)was constructed,which formed the three-dimensional conductivity network connected with the intersecting carbon nano tube(CNT).In this composite,the electron-rich Co-MTA interacted with the highly conductive CNT,resulting in a charge redistribution.Optimized the electronic structure of the Co center through compositional modifications presented a high valence compared to the pure MOFs.In situ X-ray absorption spectroscopy revealed a direct reaction of Co sites with intermediates such as LiO_(x),leading to the formation of nanosheet array discharge products.The battery based on optimized CoMTA-C demonstrated fast kinetics and superior stability,with a low overpotential of 1.13 V,high specific capacity of 9057 mAh g^(-1),and long-term durability of 600 cycles.It provides a facile and effective strategy for enhancing the electrocatalytic performance through rational tuning of high-conductivity substances.
基金Project supported by the National Key R&D Program of China(Grant No.2023YFC2206502)the National Natural Science Foundation of China(Grant Nos.12175254 and 12227810)+1 种基金Guangdong Major Project of Basic and Applied Basic Research(Grant No.2023B0303000003)Guangdong Provincial Key Laboratory of Advanced Particle Detection Technology(Grant No.2024B1212010005)。
文摘The rapid growth of neutron flux has driven the development of^(3)He-free neutron detectors to satisfy the requirements of the neutron scattering instruments under construction or planned at the China Spallation Neutron Source(CSNS).Position-sensitive neutron detectors with a high counting rate and large area play an important role in the instruments performing neutron measurements in or close to the direct beam.The ceramic gas-electron-multiplier(GEM)detector serves as a promising solution,and considerable work has been done using the small-area GEM neutron detectors.In this article,we designed and constructed a detector prototype utilizing ceramic GEM foils with an effective area of about307 mm×307 mm.To evaluate and investigate their basic characteristics,the Monte Carlo(MC)tool FLUKA was employed and several neutron beam tests were conducted at CSNS.The simulated spatial resolution was basically in agreement with the measured value of 2.50±0.01 mm(FWHM).The wavelength spectra measurement was verified through comparisons with a commercial beam monitor.In addition,a detection efficiency of 4.7±0.1%was achieved for monoenergetic neutrons of 1.59 A wavelength.This is consistent with the simulated result.The results indicate that the large-area ceramic GEM detector is a good candidate to implement neutron beam measurements.Its efficiency can be improved in a cascading manner to approach that reached by traditional^(3)He detectors.
基金supported by grants from National Science and Technology Ministry Key Research and Development Program–Project(2022YFC2402703).
文摘Objective:This study aimed to develop and evaluate a novel software tool for robust analysis of the Visually Enhanced Vestibular-Ocular Reflex(VVOR)and video head impulse test(vHIT)saccades.Methods:A retrospective study was conducted on 94 patients with Meniere’s Disease(MD),unilateral vestibular hypofunction(UVH),and vestibular migraine(VM).The MATLAB-based VVOR Analysis System and Saccades All in One software were utilized for data processing.New techniques,VVOR_diff and VVOR_cycle,were deployed for saccade parameter extraction.Results:Saccade incidence rates,examined through vHIT,VVOR_diff,and VVOR_cycle,exhibited distinct patterns in MD,UVH,and VM patients.Frequent instances of multiple saccades within a single cycle were noted on the affected side in MD and UVH patients.Statistically significant differences in saccade gain and incidence rates between the affected and unaffected sides were evident in MD and UVH patients.Notably,high inter-method and intra-method correlations suggested consistency across different methods and potential interactions within one.Conclusion:The software proved effective in extracting saccades and reducing noise in VVOR data,thereby enhancing the evaluation of vestibular function and potentially improving diagnostic accuracy for vestibular disorders.
