A series of coordination gold(Ⅲ),palladium(Ⅱ),and platinum(Ⅱ)complexes with a luminescent iminophosphorane ligand derived from 8-aminoquinoline[Ph_(3)PvN-C_(9)H_(6)N](1)have been synthesized and structurally charac...A series of coordination gold(Ⅲ),palladium(Ⅱ),and platinum(Ⅱ)complexes with a luminescent iminophosphorane ligand derived from 8-aminoquinoline[Ph_(3)PvN-C_(9)H_(6)N](1)have been synthesized and structurally characterized.The coordination palladium(Ⅱ)and platinum(Ⅱ)compounds can evolve further,under appropriate conditions,to give stable cyclometalated endo species[M{κ_(3)-C,N,N-C_(6)H_(4)(PPh_(2)vN-8-C_(9)H_(6)N)}Cl](M=Pd,Pt)by C-H activation of the phenyl group of the PPh_(3)fragment.展开更多
基金Research at Brooklyn College was supported by a grant from the National Institute of General Medical Sciences(NIGMS),SC2GM082307a grant from the National Cancer Institute(NCI),1SC1CA182844(M.C.)+1 种基金the MINECO“Ministerio de Ciencia y Economía”(CTQ2011-22589)Gobierno de Aragón(Dpto.de Ciencia,Tecnología y Universidad)for financial support(J.J.).
文摘A series of coordination gold(Ⅲ),palladium(Ⅱ),and platinum(Ⅱ)complexes with a luminescent iminophosphorane ligand derived from 8-aminoquinoline[Ph_(3)PvN-C_(9)H_(6)N](1)have been synthesized and structurally characterized.The coordination palladium(Ⅱ)and platinum(Ⅱ)compounds can evolve further,under appropriate conditions,to give stable cyclometalated endo species[M{κ_(3)-C,N,N-C_(6)H_(4)(PPh_(2)vN-8-C_(9)H_(6)N)}Cl](M=Pd,Pt)by C-H activation of the phenyl group of the PPh_(3)fragment.
