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Switching on thermal and light-induced spin crossover by desolvation of[Fe(3-bpp)_(2)](XO_(4))_(2)·solvent(X=Cl,Re)compounds
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作者 Abdelhak Djemel Olaf Stefanczyk +5 位作者 Cédric Desplanches Kunal Kumar Rachid Delimi farouk benaceur Shin-ichi Ohkoshi Guillaume Chastanet 《Inorganic Chemistry Frontiers》 2021年第13期3210-3221,共12页
Thermal desolvation is a very attractive method for the post-synthetic modification of the physicochemical properties of switchable materials.In this field of research,special attention has been paid to the possibilit... Thermal desolvation is a very attractive method for the post-synthetic modification of the physicochemical properties of switchable materials.In this field of research,special attention has been paid to the possibility of modifying the thermo-and photo-induced spin crossover(SCO)properties of metal complexes as they can act as solvent sensors.Two new[Fe(3-bpp)_(2)](ClO_(4))_(2)·2.5H_(2)O·MeOH(1·sol)and[Fe(3-bpp)_(2)](ReO_(4))_(2)·3H_(2)O(_(2)·sol)compounds. 展开更多
关键词 metal complexes post synthetic modification physicochemical properties light induced spin crossover thermal desolvation spin crossover solvent sensorstwo
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Defense and senescence interplay in legume nodules
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作者 Fathi Berrabah farouk benaceur +5 位作者 Chaoyan Yin Dawei Xin Ke´vin Magne Marie Garmier Veronique Gruber Pascal Ratet 《Plant Communications》 SCIE CSCD 2024年第4期112-126,共15页
Immunity and senescence play a crucial role in the functioning of the legume symbiotic nodules.The miss-regulation of one of these processes compromises the symbiosis leading to death of the endosymbiont and the arres... Immunity and senescence play a crucial role in the functioning of the legume symbiotic nodules.The miss-regulation of one of these processes compromises the symbiosis leading to death of the endosymbiont and the arrest of the nodule functioning.The relationship between immunity and senescence has been exten-sively studied in plant organs where a synergistic response can be observed.However,the interplay be-tween immunity and senescence in the symbiotic organ is poorly discussed in the literature and these phe-nomena are often mixed up.Recent studies revealed that the cooperation between immunity and senescence is not always observed in the nodule,suggesting complex interactions between these two pro-cesses within the symbiotic organ.Here,we discuss recent results on the interplay between immunity and senescence in the nodule and the specificities of this relationship during legume-rhizobium symbiosis. 展开更多
关键词 immunity SENESCENCE SYMBIOSIS NODULES legumes RHIZOBIA
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