The Yellow River(YR),China’s second-longest river,remains understudied regarding its greenhouse gases(GHGs)emissions,particularly the impacts of urban drainage ditches and wastewater treatment facilities on regional ...The Yellow River(YR),China’s second-longest river,remains understudied regarding its greenhouse gases(GHGs)emissions,particularly the impacts of urban drainage ditches and wastewater treatment facilities on regional GHGs dynamics.This study investigated methane(CH_(4))and carbon dioxide(CO_(2))concentrations,fluxes and stable carbon isotopes(δ^(13)C-CH_(4)and δ^(13)C-CO_(2))across six main stream,three ditches,and one wastewater treatment site along the upper Lanzhou section of the YR,spanning from the urban entrance(36.176°N,103.449°E)to the exit of Lanzhou city(36.056°N,104.020°E).Measured CH_(4)diffusion fluxes in mainstem sites ranged from 0.01 to 2.58 mmol·m^(−2)·d^(−1)(mean:0.36 mmol·m^(−2)·d^(−1)),while ebullitive fluxes(gas bubbles)ranged from 0.01 to 18.89 mmol·m^(−2)·d^(−1)(mean:0.90 mmol·m^(−2)·d^(−1)).CO_(2)diffusion fluxes varied between 9.16–92.80 mmol·m^(−2)·d^(−1)(averaged:39.11 mmol·m^(−2)·d^(−1))at these locations.Ebullition(bubble)fluxes accounted for 53.1%±22.4%(range:9.0%to 98.4%)to total CH_(4)emissions(diffusion plus ebullition),with peak fluxes occurring during summer,indicating its significance as a CH_(4)transport mechanism.Notably,both diffusion CH_(4)and CO_(2)fluxes and ebullitive CH_(4)rates at ditch sites substantially exceeded those in mainstream reaches.The lowest CH_(4)and highest CO_(2)concentrations were observed at a wastewater treatment site,likely resulting from the removal of high organic loads.Acetoclastic methanogenesis—the process converting acetate-derived methyl groups to CH_(4)—was identified as the dominant production pathway in both mainstream and ditch environments.CH_(4)and CO_(2)flux magnitudes in the upper YR(Lanzhou section)were comparable to those observed in subtropical Yangtze River tributaries.These results demonstrate that anthropogenic influences significantly enhance CO_(2)/CH_(4)emissions,and the lateral exports of dissolved carbon(DIC and DOC)in the main stream site was quantified.,which cannot be overlooked.The findings emphasize the critical need to account for pronounced spatiotemporal variations in arid-region GHG fluxes to improve basin-scale estimates for the YR.展开更多
Carbonaceous matter has an important impact on glacial retreat in the Tibetan Plateau,further affecting the water resource supply.However,the related studies on carbonaceous matter are still scarce in Geladaindong(GLD...Carbonaceous matter has an important impact on glacial retreat in the Tibetan Plateau,further affecting the water resource supply.However,the related studies on carbonaceous matter are still scarce in Geladaindong(GLDD)region,the source of the Yangtze River.Therefore,the concentration,source and variations of carbonaceous matter at Ganglongjiama(GLJM)glacier in GLDD region were investigated during the melting period in 2017,which could deepen our understanding on carbonaceous matter contribution to glacier melting.The results showed that dissolved organic carbon(DOC)concentration of snowpit samples(283±200μg/L)was much lower than that of precipitation samples(624±361μg/L),indicating that large parts of DOC could be rapidly leached from the snowpit during the melting process.In contrast,refractory black carbon(rBC)concentration measured by Single Particle Soot Photometer of snowpit samples(4.27±3.15μg/L)was much higher than that of precipitation samples(0.97±0.49μg/L).Similarly,DOC with high mass absorption cross-section measured at 365 nm value was also likely to enrich in snowpit during the melting process.In addition,it was found that both r BC and DOC with high light-absorbing ability began to leach from the snowpit when melting process became stronger.Therefore,rBC and DOC with high light-absorbing ability exhibited similar behavior during the melting process.Based on relationship among DOC,rBC and K^+ in precipitation,the main source of carbonaceous matter in GLJM glacier was biomass burning during the study period.展开更多
Rivers are critical links in the carbon and nitrogen cycle in aquatic,terrestrial,and atmospheric environments.Here riverine carbon and nitrogen exports in nine large rivers on the Tibetan Plateau—the＂Water Tower of...Rivers are critical links in the carbon and nitrogen cycle in aquatic,terrestrial,and atmospheric environments.Here riverine carbon and nitrogen exports in nine large rivers on the Tibetan Plateau—the＂Water Tower of Asia＂—were investigated in the monsoon season from 2013 to 2015.Compared with the world average,concentrations of dissolved inorganic carbon（DIC,30.7 mg/L）were high in river basins of the plateau due to extensive topographic relief and intensive water erosion.Low concentrations of dissolved organic carbon（DOC,1.16 mg/L）were likely due to the low temperature and unproductive land vegetation environments.Average concentrations of riverine DIN（0.32 mg/L）and DON（0.35 mg/L）on the Tibetan Plateau were close to the world average.However,despite its predominantly pristine environment,discharge from agricultural activities and urban areas of the plateau has raised riverine N export.In addition,DOC/DON ratio（C/N,~6.5）in rivers of the Tibetan Plateau was much lower than the global average,indicating that dissolved organic carbon in the rivers of this region might be more bioavailable.Therefore,along with global warming and anthropogenic activities,increasing export of bioavailable riverine carbon and nitrogen from rivers of the Tibetan Plateau can be expected in the future,which will possibly influence the regional carbon and nitrogen cycle.展开更多
As an important component of carbonaceous matters,dissolved organic carbon(DOC)can absorb and scatter the solar radiation at ultraviolet and blue wavelengths.The wet deposition process has great impact on the con-cent...As an important component of carbonaceous matters,dissolved organic carbon(DOC)can absorb and scatter the solar radiation at ultraviolet and blue wavelengths.The wet deposition process has great impact on the con-centration and light absorption ability of precipitation DOC,affecting the climatic effect caused by DOC in the atmosphere.In this study,light absorption and fluorescence characteristics of precipitation DOC was investigated in the central Tibetan Plateau(TP).The results showed that the mean DOC concentration and mass absorption cross-section measured at 365 nm(MAC_(365))in Tanggula(TGL)station were 0.59±0.42 mg/L and 0.37±0.19 m^(2)/g,respectively,while both values showed much higher volatilities than those of aerosols.DOC concentrations had significant negative correlation with the precipitation amount,while MAC_(365)values increase with the precipitation amount in TGL station.Therefore,DOC with high light-absorbing ability was preferred to be retained in the atmosphere during wet deposition.In this study,precipitation DOC contained three fluorescent components(one humic-like component and two tyrosine-like components)mainly from local biomass burning sources.DOC concentration showed a negative relationship with MAC_(365)value in TGL station.The wet deposition of DOC with low light-absorbing ability can reduce the strong negative radiative forcing caused by secondary organic aerosol due to high proportion of DOC in secondary organic carbon.Similar phenomenon was also found in Nam Co,Lulang and Everest stations of previous study,which may have a potential impact on radiative forcing in the atmosphere of TP.展开更多
Seepage-type gas hydrate accumulation in subsea shallow formations involves complicated thermohydro-solid coupling processes and matching problem between various accumulation elements.Theformation physical properties ...Seepage-type gas hydrate accumulation in subsea shallow formations involves complicated thermohydro-solid coupling processes and matching problem between various accumulation elements.Theformation physical properties control local natural gas migration pathway and thus the final reservoircharacteristics of hydrates.In this paper,a novel mixed-flux model for gas hydrate accumulation isestablished and then used to simulate the process of methane gas migration into the shallow stratum toform a hydrate reservoir.The effects of reservoir heterogeneity and gas source conditions on the distribution of pore fluid and hydrate accumulation are examined.The simulation results show thatreservoir heterogeneity is conducive to the retention and lateral migration of CH4 in a hydrate stabilityzone.CH4 can contact more pore water to form a large hydrate reserve,but the formed hydrate is oftendispersed.Low-permeability layers enhance the trapping of CH4 and form a uniform and large hydratesaturation.Besides,gas source conditions have an important impact on the hydrate accumulation inreservoirs.Large gas flux,small pore water flux,continuous gas supply,high content of heavy components in natural gas,and numerous gas source points contribute to large amounts of hydrates generationin a certain time period.The presented work will deepen our understanding of the controls of natural gashydrate systems in subea shallow formations.展开更多
基金funded by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0950000)the NSFC(Grant No.42201155+2 种基金4240114742201137)the State Key Laboratory of Cryospheric Science and Frozen Soil Engineering(CSFSE-ZQ-2410).
文摘The Yellow River(YR),China’s second-longest river,remains understudied regarding its greenhouse gases(GHGs)emissions,particularly the impacts of urban drainage ditches and wastewater treatment facilities on regional GHGs dynamics.This study investigated methane(CH_(4))and carbon dioxide(CO_(2))concentrations,fluxes and stable carbon isotopes(δ^(13)C-CH_(4)and δ^(13)C-CO_(2))across six main stream,three ditches,and one wastewater treatment site along the upper Lanzhou section of the YR,spanning from the urban entrance(36.176°N,103.449°E)to the exit of Lanzhou city(36.056°N,104.020°E).Measured CH_(4)diffusion fluxes in mainstem sites ranged from 0.01 to 2.58 mmol·m^(−2)·d^(−1)(mean:0.36 mmol·m^(−2)·d^(−1)),while ebullitive fluxes(gas bubbles)ranged from 0.01 to 18.89 mmol·m^(−2)·d^(−1)(mean:0.90 mmol·m^(−2)·d^(−1)).CO_(2)diffusion fluxes varied between 9.16–92.80 mmol·m^(−2)·d^(−1)(averaged:39.11 mmol·m^(−2)·d^(−1))at these locations.Ebullition(bubble)fluxes accounted for 53.1%±22.4%(range:9.0%to 98.4%)to total CH_(4)emissions(diffusion plus ebullition),with peak fluxes occurring during summer,indicating its significance as a CH_(4)transport mechanism.Notably,both diffusion CH_(4)and CO_(2)fluxes and ebullitive CH_(4)rates at ditch sites substantially exceeded those in mainstream reaches.The lowest CH_(4)and highest CO_(2)concentrations were observed at a wastewater treatment site,likely resulting from the removal of high organic loads.Acetoclastic methanogenesis—the process converting acetate-derived methyl groups to CH_(4)—was identified as the dominant production pathway in both mainstream and ditch environments.CH_(4)and CO_(2)flux magnitudes in the upper YR(Lanzhou section)were comparable to those observed in subtropical Yangtze River tributaries.These results demonstrate that anthropogenic influences significantly enhance CO_(2)/CH_(4)emissions,and the lateral exports of dissolved carbon(DIC and DOC)in the main stream site was quantified.,which cannot be overlooked.The findings emphasize the critical need to account for pronounced spatiotemporal variations in arid-region GHG fluxes to improve basin-scale estimates for the YR.
基金supported by the National Nature Science Foundation of China(Nos.41630754,41675130)the State Key Laboratory of Cryospheric Science(No.SKLCS-ZZ-2019)project funded by China Postdoctoral Science Foundation(No.2018M631215)
文摘Carbonaceous matter has an important impact on glacial retreat in the Tibetan Plateau,further affecting the water resource supply.However,the related studies on carbonaceous matter are still scarce in Geladaindong(GLDD)region,the source of the Yangtze River.Therefore,the concentration,source and variations of carbonaceous matter at Ganglongjiama(GLJM)glacier in GLDD region were investigated during the melting period in 2017,which could deepen our understanding on carbonaceous matter contribution to glacier melting.The results showed that dissolved organic carbon(DOC)concentration of snowpit samples(283±200μg/L)was much lower than that of precipitation samples(624±361μg/L),indicating that large parts of DOC could be rapidly leached from the snowpit during the melting process.In contrast,refractory black carbon(rBC)concentration measured by Single Particle Soot Photometer of snowpit samples(4.27±3.15μg/L)was much higher than that of precipitation samples(0.97±0.49μg/L).Similarly,DOC with high mass absorption cross-section measured at 365 nm value was also likely to enrich in snowpit during the melting process.In addition,it was found that both r BC and DOC with high light-absorbing ability began to leach from the snowpit when melting process became stronger.Therefore,rBC and DOC with high light-absorbing ability exhibited similar behavior during the melting process.Based on relationship among DOC,rBC and K^+ in precipitation,the main source of carbonaceous matter in GLJM glacier was biomass burning during the study period.
基金supported by the National Natural Science Foundation of China (Nos.41675130, 41271015, 41225002)the Academy of Finland (decision number: 268170)the State Key Laboratory of Cryospheric Science (SKLCS-ZZ-2008-01 and SKLCS-OP-2014-05)
文摘Rivers are critical links in the carbon and nitrogen cycle in aquatic,terrestrial,and atmospheric environments.Here riverine carbon and nitrogen exports in nine large rivers on the Tibetan Plateau—the＂Water Tower of Asia＂—were investigated in the monsoon season from 2013 to 2015.Compared with the world average,concentrations of dissolved inorganic carbon（DIC,30.7 mg/L）were high in river basins of the plateau due to extensive topographic relief and intensive water erosion.Low concentrations of dissolved organic carbon（DOC,1.16 mg/L）were likely due to the low temperature and unproductive land vegetation environments.Average concentrations of riverine DIN（0.32 mg/L）and DON（0.35 mg/L）on the Tibetan Plateau were close to the world average.However,despite its predominantly pristine environment,discharge from agricultural activities and urban areas of the plateau has raised riverine N export.In addition,DOC/DON ratio（C/N,~6.5）in rivers of the Tibetan Plateau was much lower than the global average,indicating that dissolved organic carbon in the rivers of this region might be more bioavailable.Therefore,along with global warming and anthropogenic activities,increasing export of bioavailable riverine carbon and nitrogen from rivers of the Tibetan Plateau can be expected in the future,which will possibly influence the regional carbon and nitrogen cycle.
基金supported by the National Natural Science Foundation of China(42201158,42177366)the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(2019QZKK0605)+1 种基金Natural Science Foundation of Gansu Province,China(23JRRA656)the State Key Laboratory of Cryospheric Science(SKLCS-ZZ-2022).
文摘As an important component of carbonaceous matters,dissolved organic carbon(DOC)can absorb and scatter the solar radiation at ultraviolet and blue wavelengths.The wet deposition process has great impact on the con-centration and light absorption ability of precipitation DOC,affecting the climatic effect caused by DOC in the atmosphere.In this study,light absorption and fluorescence characteristics of precipitation DOC was investigated in the central Tibetan Plateau(TP).The results showed that the mean DOC concentration and mass absorption cross-section measured at 365 nm(MAC_(365))in Tanggula(TGL)station were 0.59±0.42 mg/L and 0.37±0.19 m^(2)/g,respectively,while both values showed much higher volatilities than those of aerosols.DOC concentrations had significant negative correlation with the precipitation amount,while MAC_(365)values increase with the precipitation amount in TGL station.Therefore,DOC with high light-absorbing ability was preferred to be retained in the atmosphere during wet deposition.In this study,precipitation DOC contained three fluorescent components(one humic-like component and two tyrosine-like components)mainly from local biomass burning sources.DOC concentration showed a negative relationship with MAC_(365)value in TGL station.The wet deposition of DOC with low light-absorbing ability can reduce the strong negative radiative forcing caused by secondary organic aerosol due to high proportion of DOC in secondary organic carbon.Similar phenomenon was also found in Nam Co,Lulang and Everest stations of previous study,which may have a potential impact on radiative forcing in the atmosphere of TP.
基金This research is supported by the Fundamental Research Funds for the Central Universities(No.15CX05036A,18CX05009A)the National Key Basic Research Program 973 project(No.2015CB251201)+2 种基金It is also partially financed by the National Major S&T Project(No.2016ZX05056004-003)the General Project of Shandong Natural Science Foundation(ZR2020ME090)the National Natural Science Foundation of China(No.51974347)。
文摘Seepage-type gas hydrate accumulation in subsea shallow formations involves complicated thermohydro-solid coupling processes and matching problem between various accumulation elements.Theformation physical properties control local natural gas migration pathway and thus the final reservoircharacteristics of hydrates.In this paper,a novel mixed-flux model for gas hydrate accumulation isestablished and then used to simulate the process of methane gas migration into the shallow stratum toform a hydrate reservoir.The effects of reservoir heterogeneity and gas source conditions on the distribution of pore fluid and hydrate accumulation are examined.The simulation results show thatreservoir heterogeneity is conducive to the retention and lateral migration of CH4 in a hydrate stabilityzone.CH4 can contact more pore water to form a large hydrate reserve,but the formed hydrate is oftendispersed.Low-permeability layers enhance the trapping of CH4 and form a uniform and large hydratesaturation.Besides,gas source conditions have an important impact on the hydrate accumulation inreservoirs.Large gas flux,small pore water flux,continuous gas supply,high content of heavy components in natural gas,and numerous gas source points contribute to large amounts of hydrates generationin a certain time period.The presented work will deepen our understanding of the controls of natural gashydrate systems in subea shallow formations.
