Hydrogel zinc ion batteries(HZIBs)represent a cutting-edge advancement in energy storage systems,leveraging the exceptional properties of hydrogels,including superior mechanical flexibility and robust structural stabi...Hydrogel zinc ion batteries(HZIBs)represent a cutting-edge advancement in energy storage systems,leveraging the exceptional properties of hydrogels,including superior mechanical flexibility and robust structural stability.Despite their promising attributes,HZIBs face persistent challenges that hinder their practical deployment,notably performance degradation during long-term cycling.In this review,we provide a comprehensive explanation of the fundamental structure and working principles of HZIBs,analyzing the roles of each component.We then systematically explore these degradation mechanisms and comprehensively summarize the key influencing factors,including zinc dendrite formation,hydrogel matrix degradation,electrolyte depletion,and interfacial instability.The role of environmental and operational factors,such as temperature fluctuations and humidity variations,in exacerbating these degradation processes is also highlighted.Recent material engineering strategies to mitigate these issues are summarized:1)the development of structurally reinforced hydrogel electrolytes;2)the use of functional additives for ion transport regulation;and 3)interfacial engineering for uniform zinc deposition.Moreover,emerging fabrication techniques,such as nanoscale structural design and additive manufacturing,are discussed for their potential to optimize the mechanical robustness and electrochemical performance of HZIBs.This review integrates fundamental insights with advanced engineering approaches to provide practical guidance for the scalable development of high performance HZIBs for flexible and wearable applications.展开更多
With the increasing demands for electrical energy storage technologies,rechargeable zinc ion batteries(ZIBs)have been rapidly developed in recent years owing to their high safety,low cost and high energy storage capab...With the increasing demands for electrical energy storage technologies,rechargeable zinc ion batteries(ZIBs)have been rapidly developed in recent years owing to their high safety,low cost and high energy storage capability.The cathode is an essential part of ZIBs,which hosts zinc ions and determines the capacity,rate and cycling performance of the battery.The mainstream cathodes for ZIBs are oxidebased materials with tunnel,layer or 3 D crystal structures.In this review,we mainly focus on the latest advanced oxide-based cathode materials in ZIBs,including manganese oxides,vanadium oxides,spinel compounds,and other metal oxide based cathodes.In addition,the mechanisms of zinc storage and recent development in cathode design have been discussed in detail.Finally,current challenges and perspectives for the future research directions of oxide-based cathodes in ZIBs are presented.展开更多
Silver-zinc(Ag-Zn)batteries are a promising battery system for flexible electronics owing to their high safety,high energy density,and stable output voltage.However,poor cycling performance,low areal capacity,and infe...Silver-zinc(Ag-Zn)batteries are a promising battery system for flexible electronics owing to their high safety,high energy density,and stable output voltage.However,poor cycling performance,low areal capacity,and inferior flexibility limit the practical application of Ag-Zn batteries.Herein,we develop a flexible quasi-solid-state Ag-Zn battery system with superior performance by using mild electrolyte and binder-free electrodes.Copper foam current collector is introduced to impede the growth of Zn dendrite,and the structure of Ag cathode is engineered by electrodeposition and chloridization process to improve the areal capacity.This novel battery demonstrates a remarkable cycle retention of 90%for 200 cycles at 3 mA cm^(-2).More importantly,this binder-free battery can afford a high capacity of 3.5 mAh cm^(-2)at 3 mA cm^(-2),an outstanding power density of 2.42 mW cm^(-2),and a maximum energy density of 3.4 mWh cm^(-2).An energy management circuit is adopted to boost the output voltage of a single battery,which can power electronic ink display and Bluetooth temperature and humidity sensor.The developed battery can even operate under the extreme conditions,such as being bent and sealed in solid ice.This work offers a path for designing electrodes and electrolyte toward high-performance flexible Ag-Zn batteries.展开更多
基金support from the Australian Research Council projects(IC230100042).
文摘Hydrogel zinc ion batteries(HZIBs)represent a cutting-edge advancement in energy storage systems,leveraging the exceptional properties of hydrogels,including superior mechanical flexibility and robust structural stability.Despite their promising attributes,HZIBs face persistent challenges that hinder their practical deployment,notably performance degradation during long-term cycling.In this review,we provide a comprehensive explanation of the fundamental structure and working principles of HZIBs,analyzing the roles of each component.We then systematically explore these degradation mechanisms and comprehensively summarize the key influencing factors,including zinc dendrite formation,hydrogel matrix degradation,electrolyte depletion,and interfacial instability.The role of environmental and operational factors,such as temperature fluctuations and humidity variations,in exacerbating these degradation processes is also highlighted.Recent material engineering strategies to mitigate these issues are summarized:1)the development of structurally reinforced hydrogel electrolytes;2)the use of functional additives for ion transport regulation;and 3)interfacial engineering for uniform zinc deposition.Moreover,emerging fabrication techniques,such as nanoscale structural design and additive manufacturing,are discussed for their potential to optimize the mechanical robustness and electrochemical performance of HZIBs.This review integrates fundamental insights with advanced engineering approaches to provide practical guidance for the scalable development of high performance HZIBs for flexible and wearable applications.
基金funded by the Australian Research Council Project(grant no.LP190100113)the award of a Future Fellow from Australian Research Council(FT170100224)。
文摘With the increasing demands for electrical energy storage technologies,rechargeable zinc ion batteries(ZIBs)have been rapidly developed in recent years owing to their high safety,low cost and high energy storage capability.The cathode is an essential part of ZIBs,which hosts zinc ions and determines the capacity,rate and cycling performance of the battery.The mainstream cathodes for ZIBs are oxidebased materials with tunnel,layer or 3 D crystal structures.In this review,we mainly focus on the latest advanced oxide-based cathode materials in ZIBs,including manganese oxides,vanadium oxides,spinel compounds,and other metal oxide based cathodes.In addition,the mechanisms of zinc storage and recent development in cathode design have been discussed in detail.Finally,current challenges and perspectives for the future research directions of oxide-based cathodes in ZIBs are presented.
基金financial support from the Australian Research Council(LP1900113)
文摘Silver-zinc(Ag-Zn)batteries are a promising battery system for flexible electronics owing to their high safety,high energy density,and stable output voltage.However,poor cycling performance,low areal capacity,and inferior flexibility limit the practical application of Ag-Zn batteries.Herein,we develop a flexible quasi-solid-state Ag-Zn battery system with superior performance by using mild electrolyte and binder-free electrodes.Copper foam current collector is introduced to impede the growth of Zn dendrite,and the structure of Ag cathode is engineered by electrodeposition and chloridization process to improve the areal capacity.This novel battery demonstrates a remarkable cycle retention of 90%for 200 cycles at 3 mA cm^(-2).More importantly,this binder-free battery can afford a high capacity of 3.5 mAh cm^(-2)at 3 mA cm^(-2),an outstanding power density of 2.42 mW cm^(-2),and a maximum energy density of 3.4 mWh cm^(-2).An energy management circuit is adopted to boost the output voltage of a single battery,which can power electronic ink display and Bluetooth temperature and humidity sensor.The developed battery can even operate under the extreme conditions,such as being bent and sealed in solid ice.This work offers a path for designing electrodes and electrolyte toward high-performance flexible Ag-Zn batteries.
