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青海小柴旦盐湖沉积物的地球化学初步研究 被引量:1
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作者 贾蓉芬 傅家谟 +3 位作者 徐芬芳 范善发 孙大鹏 G.埃格林顿 《海洋与湖沼》 1986年第2期117-125,173-174,共11页
本文采用地球化学与有机地球化学方法详细研究了小柴旦盐湖沉积物。结果表明,该沉积物的矿物组成与化学组成非常类似于中国东部第三纪盐湖沉积物(如江汉和东濮油田的生油岩),而区别于淡水湖相沉积物(如茂名和抚顺油页岩)。分析鉴定了盐... 本文采用地球化学与有机地球化学方法详细研究了小柴旦盐湖沉积物。结果表明,该沉积物的矿物组成与化学组成非常类似于中国东部第三纪盐湖沉积物(如江汉和东濮油田的生油岩),而区别于淡水湖相沉积物(如茂名和抚顺油页岩)。分析鉴定了盐湖沉积物的氨基酸、脂肪酸和烷烃组成。脂肪酸与烷烃的分布特征表明,生物输入以陆源植物为主,与其孢子、花粉组成的鉴定结果相符。 展开更多
关键词 小柴旦盐湖 矿物组成 化学组成 地球化学
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Chemical characteristics of PM_(2.5) during a typical haze episode in Guangzhou 被引量:74
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作者 TAN Jihua DUAN Jingchun +4 位作者 HE Kebin MA Yongliang DUAN Fengkui CHEN Yuan fu jiamo 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2009年第6期774-781,共8页
The chemical characteristics(water-soluble ions and carbonaceous species) of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between... The chemical characteristics(water-soluble ions and carbonaceous species) of PM2.5 in Guangzhou were measured during a typical haze episode.Most of the chemical species in PM2.5 showed significant difference between normal and haze days.The highest contributors to PM2.5 were organic carbon(OC),nitrate,and sulfate in haze days and were OC,sulfate,and elemental carbon(EC) in normal days.The concentrations of secondary species such as,NO3^-,SO4^2-,and NH4^+ in haze days were 6.5,3.9,and 5.3 times higher than those in normal days,respectively,while primary species(EC,Ca^2+,K^+) show similar increase from normal to haze days by a factor about 2.2-2.4.OC/EC ratio ranged from 2.8 to 6.2 with an average of 4.7 and the estimation on a minimum OC/EC ratio showed that SOC(secondary organic carbon) accounted more than 36.6% for the total organic carbon in haze days.The significantly increase in the secondary species(SOC,NO3^-,SO4^2-,and NH4^+),especially in NO3^-,caused the worst air quality in this region.Simultaneously,the result illustrated that the serious air pollution in haze episodes was strongly correlated with the meteorological conditions.During the sampling periods,air pollution and visibility had a good relationship with the air mass transport distance;the shorter air masses transport distance,the worse air quality and visibility in Guangzhou,indicating the strong domination of local sources contributing to haze formation.High concentration of the secondary aerosol in haze episodes was likely due to the higher oxidation rates of sulfur and nitrogen species. 展开更多
关键词 PM2.5 haze episode water-soluble inorganic ions organic carbon elemental carbon GUANGZHOU
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Organic/ Inorganic Occurrence of Metallic Elements of the Black Shale-Hosted Baiguoyuan Silver-Vanadium Deposit in Xingshan, Hubei 被引量:4
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作者 ZHUANG Hanping LU Jialan +4 位作者 fu jiamo LIU Jinzhong REN Chigang ZOU Degang TIAN Weizhi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1998年第3期299-307,共9页
: By means of kerogen purification, the proton induced X-ray emission (PIXE) and instrumental neutron activation analysis (INAA), the authors have studied the organic/inorganic occurrence modes of the metallic element... : By means of kerogen purification, the proton induced X-ray emission (PIXE) and instrumental neutron activation analysis (INAA), the authors have studied the organic/inorganic occurrence modes of the metallic elements of the Baiguoyuan silver-vanadium deposit hosted in black shale in Hubei Province, China. The result shows that Au, Hg and Ta have a strong tendency to occur organically, with more than 70% of these elements being associated organically. Se, Ga, Ag and Hf are partly associated with organic matter, with more than 20% of them occurring organically. Compared with the above elements, Zn, Cu, As and Sb are weakly associated organically, and tend to be enriched in kerogen. However, Mn, Th, U, V, Co, Cr, AI, Fe and Sc usually occur inorganically. Of the rare earth elements (REE), La, Ce, Tb, Dy, Yb and Lu have stronger ability to be associated with organic matter than Sm and Eu. 展开更多
关键词 Baiguoyuan black shale-hosted silver-vanadium deposit organic matter metallic elements occurrence modes
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Immature crude oils in the salt lake depositional environment are related to organic matter precipitated at stage of carbonate in salt lake sedimentation sequences 被引量:6
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作者 PENG Ping’an SHENG Guoying +1 位作者 fu jiamo JIANG Jiagang 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期1-6,共6页
The present paper studies the mineralogy and geochemistry of a geological section in Jianghan basin. Widely distributed immature oils in this basin have been shown to relate to the carbonate depositional stage of salt... The present paper studies the mineralogy and geochemistry of a geological section in Jianghan basin. Widely distributed immature oils in this basin have been shown to relate to the carbonate depositional stage of salt lake sedimentation cycle. It is concluded that only when the content of organic carbon in the rocks is taken into account, is it meaningful to calculate the immature oil in the source rocks. 展开更多
关键词 DEPOSITIONAL environment of salt lake IMMATURE CRUDE oils biological markers compound specific carbon isotope composition.
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Sequential extraction and compositional analysis of oil-bearing fluid inclusions in reservoir rocks from Kuche Depression, Tarim Basin 被引量:6
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作者 PAN Changchun fu jiamo SHENG Guoying 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期60-66,共7页
The free oils, adsorbed oils and oil-bearing fluid inclusions have been extracted separately and analyzed by GC and GC-MS in reservoir rock samples collected from the Kuche Depression. The results demonstrate that the... The free oils, adsorbed oils and oil-bearing fluid inclusions have been extracted separately and analyzed by GC and GC-MS in reservoir rock samples collected from the Kuche Depression. The results demonstrate that the molecular compositions of oil-bearing fluid inclusions are significantly different from those of the free oils (the current oils). Compared with the current oil, the oil-bearing fluid inclusions are characterized by relatively high values of parameters Pr/nC17 and Ph/nC18, low values of Pr/Ph, hopanes/steranes, C30-diahopane/C30-hopane and Ts/Tm, low content of C29Ts terpane and high maturities as indicated by C29 steranes 20S/(20R+20S). In addition, the oil-bearing fluid inclusions correlate very well with the oils in northern and central Tarim Basin, which were derived from Cambrian-Ordovician marine source rocks. The adsorbed oils appear to be an intermediate type between free oils and oil-bearing fluid inclusions. The above analytical data indicate that there are at least two 展开更多
关键词 oil-bearing fluid INCLUSIONS adsorbed OILS sequential extraction Kuche DEPRESSION TARIM Basin.
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A new method to reconstruct hydrocarbon-generating histories of source rocks in a petroleum-bearing basin——the method of geological and geochemical sections 被引量:6
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作者 XIAO Xianming LIU Zufa +2 位作者 LIU Dehan SHEN Jiagui fu jiamo 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期35-40,共6页
Via investigating typical Palaeozoic and Mesozoic petroleum-bearing basins in China by using thermal maturation theories of organic matter to improve the conventional Karweil’s method, a new method to reconstruct hyd... Via investigating typical Palaeozoic and Mesozoic petroleum-bearing basins in China by using thermal maturation theories of organic matter to improve the conventional Karweil’s method, a new method to reconstruct hydrocarbon-generating histories of source rocks has been suggested. This method, combining geological background with geochemical information makes the calculated VRo closer to the measured one. Moreover, it enables us to make clear the hydrocarbon generation trend of source rocks during geological history. The method has the merits of simple calculation and objective presentation, especially suitable to basins whose sedimentation and tectonic movements are complicated. 展开更多
关键词 petroleum-bearing BASIN hydrocarbon-generating HISTORIES organic maturation.
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Water quality criteria for 4-nonylphenol in protection of aquatic life 被引量:4
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作者 LEI BingLi LIU Qian +5 位作者 SUN YanFeng WANG YiPei YU ZhiQiang ZENG XiangYing fu jiamo SHENG GuoYing 《Science China Earth Sciences》 SCIE EI CAS 2012年第6期892-899,共8页
Here reproduction and death toxicity data were selected for 4-nonylphenol based on endocrine disrupting properties of the re- productive system. Assessment factor (AF) and species sensitivity distribution (SSD) cu... Here reproduction and death toxicity data were selected for 4-nonylphenol based on endocrine disrupting properties of the re- productive system. Assessment factor (AF) and species sensitivity distribution (SSD) curve were employed to derive criteria maximum concentration (CMC) and criteria continuous concentration (CCC) of three different 4-nonylphenols for protection of aquatic life. The results showed that the CMC and CCC based on SSD method and death toxicity data for three different 4-nonylphenols (CAS No: 104405, 25154523, 84852163) were 26.7, 13.6, 3.84μg L-1 and 8.86, 2.21, 0.97 μg L-1, respectively. Based on SSD and reproductive toxicity data, the CCC values of different 4-nonylphenols (CAS No: 104405, 25154523) were 1.59 and 1.34μg L-l, respectively. The CCC values obtained by the AF for three different 4-nonylphenol (CAS No: 104405, 25154523, 84852163) were 0.165, 1.03, 0.74 μg L -1 and 0.5, 0.5, 0.1μg L-1, respectively, based on death toxicity data and re- productive toxicity data. The CCC values obtained by AF were all lower than the corresponding criteria values obtained by SSD, and the CCC values based on reproductive toxicity data were less than those based on the death toxicity data. This study provides a useful method for deriving water quality criteria for endocrine disruptors. 展开更多
关键词 4-NONYLPHENOL toxicity endpoint assessment method aquatic quality criteria
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Geochemical identification of coal-sourced oils and inter-bedded shale-sourced oils as revealed by compound specific carbon isotopic analysis 被引量:2
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作者 SUN Yongge WANG Zhiyong +5 位作者 SHENG Guoying ZHANG Shihuan PENG Ping’an fu jiamo WANG Wuhe YUAN Mingshen 《Chinese Science Bulletin》 SCIE EI CAS 2001年第20期1737-1740,共4页
To date, questions remain as to how to differentiate between coal- and interbedded shale-sourced oils in coal measures. Based on the hypothesis that δ13C value of sedimentary organic matter is controlled by the depos... To date, questions remain as to how to differentiate between coal- and interbedded shale-sourced oils in coal measures. Based on the hypothesis that δ13C value of sedimentary organic matter is controlled by the depositional environment and productivities of biota grown in such depositional setting, this note examines compound specific carbon isotopic profiles from coal and interbedded shale extracts using the gas chromatography-isotope ratio mass spec-trometry technique (GC/IRMS). The results show that compound specific carbon isotope values from coal extracts are enriched in 13C relative to that of interbedded shale extracts, and provide useful information in characterizing coal- and interbedded shale-sourced oils in coal measures. An example for its successful application from the Turpan Basin, Northwestern China is presented. 展开更多
关键词 COMPOUND SPECIFIC CARBON isotope productivities of BIOTA coal-derived oil Turpan Basin.
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Measurement of aerosol effective density by single particle mass spectrometry 被引量:2
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作者 ZHANG GuoHua BI XinHui +5 位作者 HAN BingXue QIU Ning DAI ShouHui WANG XinMing SHENG GuoYing fu jiamo 《Science China Earth Sciences》 SCIE EI CAS CSCD 2016年第2期320-327,共8页
Single particle mass spectrometry has been widely used to determine the size and chemical compositions of at- mospheric aerosols; however, it is still rarely used for the microphysical properties measurement. In this ... Single particle mass spectrometry has been widely used to determine the size and chemical compositions of at- mospheric aerosols; however, it is still rarely used for the microphysical properties measurement. In this study, two methods were developed for determining aerosol effective density by a single particle aerosol mass spectrometer (SPAMS). Method I retrieved effective density through comparison between measured light scattering intensities and Mie theoretical modelled par- tial scattering cross section. Method Ⅱ coupled a differential mobility analyzer (DMA) with SPAMS to simultaneously deter- mine the electric mobility and vacuum aerodynamic diameter, and thus the effective density. Polystyrene latex spheres, ammo- nium sulfate and sodium nitrate were tested by these methods to help validate their effectiveness for determining the aerosol effective density. This study effectively extends SPAMS measurements to include particle size, chemical composition, light scattering, and effective density, and thus helps us better understand the environment and climate effects of aerosols. 展开更多
关键词 Effective density Single particle SPAMS Mie theory DMA
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Sorption and desorption of 1,4-dichlorobenzene on peat 被引量:1
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作者 RAN Yong LIN Zheng +3 位作者 WANG Xili MIN Yushun SHENG Guoying fu jiamo 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期47-52,共6页
Sorption and desorption of 1,4-dichlorobenzene (DCB) on peat (】92% organic matter) display large-scale hysteresis and nonlinearity. The magnitude of desorption hysteresis decreases in the order: untreated Pahokee pea... Sorption and desorption of 1,4-dichlorobenzene (DCB) on peat (】92% organic matter) display large-scale hysteresis and nonlinearity. The magnitude of desorption hysteresis decreases in the order: untreated Pahokee peat (P)】 acid treated peat (FP)】 humin (TP). The desorption percentages are lower than 28% of the sorbed 1, 4-DCB after desorbing for 6 days. The sorption and desorption isotherms are well fitted to Freundlich equation, whose parameter 1/n ranges from 0.055 to 0.527. Moreover, the parameter 1/n of the desorption isotherm is significantly lower than that of the sorption isotherm, but the parameter logK increases on contrary to 1/n. The desorption isotherms are very well fitted to Langmuir equation, whose Qm decreases in the order: TP】FP】 P. The apparent partition coefficients (Kp) increase with increasing sorption time or decreasing aqueous equilibrium concentration of DCB. And Kp of P is significantly higher than that of FP or TP. 展开更多
关键词 1 4-dichlorobenze SORPTION DESORPTION natural organic MATTER ISOTHERMAL equation.
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Tricyclic aromatic diterpanes found in the Tertiary sediments and their geochemical significance
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作者 SHENG Guoying fu jiamo +1 位作者 SONG Yitao PENG Ping’an 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期11-15,共5页
One monoaromatic tricyclic diterpane and two aromatic tricyclic diterpanes were found in three low-maturity source rocks and five crude oils of the Tertiary Shahejie Formation in Shengli Oil Field. The compounds found... One monoaromatic tricyclic diterpane and two aromatic tricyclic diterpanes were found in three low-maturity source rocks and five crude oils of the Tertiary Shahejie Formation in Shengli Oil Field. The compounds found include C19H28 (m/z 145, M+ 256) ring-C monoaromatic tricyclic terpane, C17H20 (m/z 209, M+ 224) and C18H22 (m/z 223,M+ 238) rings-B,C diaromatic diterpanes. The results show that these compounds are biomarkers of immature organic matter with a stability sequence of C18H22 】 C17H20 】 C19H28. The cleavage of ring-D of pentacyclic triterpanoids, such as oleanene, hopene, fernene, ursene, in the early stage of diagenesis may be one of the origin pathways of rings-B, C diaromatic tricyclic diterpanes. 展开更多
关键词 monoaromatic TRICYCLIC TERPANE diaromatic TRICYCLIC diterpanes TERTIARY Shahejie Formation IMMATURE source rocks CRUDE oil.
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Geochemical study and significance of sequential extraction in reservoir rocks of Turpan-Hamin Basin
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作者 YU Linping PAN Changchun fu jiamo 《Chinese Science Bulletin》 SCIE EI CAS 2004年第S1期32-38,共7页
Seven samples collected from the Turpan-Hamin Basin were treated by sequential extraction method. Analytical results indicate that the free oils, inclusion oils (oil-bearing fluid inclusions) and clay-adsorbed oils va... Seven samples collected from the Turpan-Hamin Basin were treated by sequential extraction method. Analytical results indicate that the free oils, inclusion oils (oil-bearing fluid inclusions) and clay-adsorbed oils vary significantly. The geochemical characteristics of inclusion and clay-adsorbed oils correlate well with the lacustrine mudstones. The characteristics are as follows: (i) with higher Ph/nC18 ratio and lower Pr/Ph ratio; (ii) with higher values of C26 tricyclic/C24 tetracyclic terpane, C23 tricyclic ter-pane/(C23 tricyclic terpane+C3017α(H) hopane), C21/(C21+C29) sterane, Ts/Tm and C29Ts/C29l7α(H) norhopane and lower value of C19/C21 tricyclic terpane; (iii) with relatively high content of C27 and C28 sterane and lower abundance of C29 sterane and diasterane. They indicate that the early charged oils are derived from the pre-Jurassic lacustrine mudstones and the later charged oils are from the Jurassic coal-bearing strata or coals. 展开更多
关键词 Turpan-Hamin BASIN sequential extraction free OILS oil-bearing fluid inclusions clay-adsorbed oils.
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Molecular source of biomarkers by genetic engineering techniques
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作者 DAI Junbiao WU Qingyu +3 位作者 WANG Ruiyong PENG Weimin SHEN Guoyin fu jiamo 《Chinese Science Bulletin》 SCIE EI CAS 2000年第11期1025-1030,共6页
The mutant lacking ORF469 fragment in Synechocystis sp. PCC 6803 (cyanobacterium) was created by means of DNA recombination. In its genome, ORF469, the key DNA fragment controlling the light-independent pathway of chl... The mutant lacking ORF469 fragment in Synechocystis sp. PCC 6803 (cyanobacterium) was created by means of DNA recombination. In its genome, ORF469, the key DNA fragment controlling the light-independent pathway of chlorophyll biosynthesis was deleted and replaced by erythromycin resistance cassette. The operation resulted in the fact that the content of chlorophyll in mutant cells was fully controlled by illumination and two kinds of cells were harvested, one is high chlorophyll with concentration of 9.427 μg · mg-1 and the other is low chlorophyll with concentration of 0.695 μg ·mg-1. They were subjected to thermal simulation respectively at 300℃ for 100 h. The alkanes biomarkers from pyrolysates were analyzed by GC-MS and main difference between high and low chlorophyll cells was found at their contents of isoprenoid hydrocarbons. Pr/nC17 and Ph/nC18 from pyrolysate of low chlorophyll cells were 0.192 and 0.216 respectively, which were about 1/3 and 1/7 of that from high chlorophyll cells. The 展开更多
关键词 SYNECHOCYSTIS sp. PCC 6803 DNA recombination biomarkers thermal DEGRADATION ISOPRENOID hydrocarbons.
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Factors influencing the purification efficiency of photosynthetic bacteria
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作者 CHEN Fanzhong DING Aizhong +1 位作者 fu jiamo SHENG Guoying 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期105-109,共5页
One strain of photosynthetic bacteria (PSB) was isolated from substrate sludge of fresh-water fishpond. Influence of the use level of PSB culture solution, illumination condition, temperature, salinity, the use level ... One strain of photosynthetic bacteria (PSB) was isolated from substrate sludge of fresh-water fishpond. Influence of the use level of PSB culture solution, illumination condition, temperature, salinity, the use level of copper sulfate and dipterex on the purification efficiency was investigated. The results showed that the optimum use level of PSB culture solution was 10 mg/L, and the purification efficiency at illumination was higher than that at black, and if the temperature was lower than 15@, or the use level of sodium chloride, copper sulfate and dipterex were higher than 10 000 mg/L, 0.4 mg/L and 2.0 mg/L, respectively, the purification efficiency dropped distinctly. 展开更多
关键词 PHOTOSYNTHETIC BACTERIA (PSB) WATER PURIFICATION influencing factor.
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High-resolution sedimentary record of hydrocarbon contaminants in a core from the major reaches of the Pearl River, China
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作者 MAI Bixian SHENG Guoying +3 位作者 LIN Zheng ZHANG Gan MIN Yushun fu jiamo 《Chinese Science Bulletin》 SCIE EI CAS 2000年第S1期97-104,共8页
The concentrations and compositions of hydrocarbon contaminants, and molecular marker indices in modern sediments from a core in the major reaches of the Pearl River were investigated. The sedimentary record of hydroc... The concentrations and compositions of hydrocarbon contaminants, and molecular marker indices in modern sediments from a core in the major reaches of the Pearl River were investigated. The sedimentary record of hydrocarbons in the core, in combination with 210Pb-dating, was used to reconstruct the pollution history of hydrocarbon pollutants in the Pearl River in the past 100 years. 展开更多
关键词 organic CONTAMINANTS SEDIMENTARY RECORD SEDIMENTARY core.
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