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零碳生物质典型中药渣的燃烧特性研究
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作者 陈翀 冯振扬 郑晓园 《电力科技与环保》 2025年第4期625-637,共13页
【目的】中药渣作为医药产业的主要固体废物,同时也是一种生物质,其高效能源化利用对资源回收与环境保护具有重要意义,为探究不同来源中药渣(苏黄、蓝芩、胃苏、黄芪)的燃烧特性及动力学参数,分析升温速率和原料组成对燃烧性能的影响。... 【目的】中药渣作为医药产业的主要固体废物,同时也是一种生物质,其高效能源化利用对资源回收与环境保护具有重要意义,为探究不同来源中药渣(苏黄、蓝芩、胃苏、黄芪)的燃烧特性及动力学参数,分析升温速率和原料组成对燃烧性能的影响。【方法】采用热重分析法在升温速率10~40℃/min范围内研究中药渣的燃烧过程,通过切线法确定着火温度和燃尽温度,计算可燃性指数、燃尽特性指数及综合燃烧特性指数(comprehensive combustion index,CCI)。结合无模型法(Flynn-Wall-Ozawa、Kissinger-Akahira-Sunose、Starink和Friedman)估算表观活化能,利用主曲线法确定燃烧机理函数,并通过实验主曲线与理论机理函数匹配验证反应模型。【结果】结果表明,中药渣的燃烧过程主要由挥发分燃烧和固定碳燃烧组成,着火温度在249~282℃之间,表明其易点燃特性。升温速率提高显著改善燃烧性能,CCI增加,燃烧特性改善;升温速率为20℃/min时,CCI在4.53×10^(-7)~9.99×10^(-7)%2/min^(2)/℃3范围内;由于苏黄灰分含量较高,燃烧特性相对较差。动力学分析表明,4种等转化率法估算的表观活化能较为接近,但燃烧的表观活化能随转化率的变化趋势不同,它们的平均活化能在111.94~130.07 kJ/mol之间。中药渣燃烧过程阶段1和阶段2的反应机理均符合化学反应机理Fn,且阶段1的反应级数均高于阶段2;除蓝芩外,其他样品阶段1的指前因子均大于阶段2,与活化能的变化趋势一致。提高升温速率可有效增强中药渣燃烧性能,其中黄芪因高挥发分(79.68%)和低灰分综合性能最佳。【结论】燃烧动力学参数与机理的明确为中药渣能源化利用提供了关键理论支持,可为中药渣燃烧处置提供理论依据。 展开更多
关键词 动力学 等转化率法 主曲线法 活化能 反应机理
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Analysis of CFRP milling damage patterns under different laying angles with force-thermal coupling effects
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作者 WANG Yiqi MAO Yaning +3 位作者 feng zhenyang JING Xiao CHEN Liangzi HE Daliang 《纤维复合材料》 2025年第3期3-7,共5页
The wide application of carbon fiber reinforced plastic(CFRP)components in modern aerospace manufacturing field puts high demands on the manufacturing process.Especially,the temperature increase during continuous mill... The wide application of carbon fiber reinforced plastic(CFRP)components in modern aerospace manufacturing field puts high demands on the manufacturing process.Especially,the temperature increase during continuous milling process becomes a key factor affecting the performance of composites,and the high milling temperature induces a variety of processing defects.This paper obtained the temperature variation data during the end milling process of CFRP laminates through experiments.After data fitting,the data were transformed into a function of heat flux density varying with time.In the finite element analysis,a double-ellipsoid moving heat source model was introduced,and a moving heat source subrou-tine was written based on the time-varying function of heat flux density to more accurately describe the thermal effects dur-ing the milling process and simulate the changes in the temperature field during milling.The Hashin failure criterion is a-dopted as the basis of fiber and matrix failure,and the simulation results of the temperature field are input into the thermal-force coupling simulation model as the predefined field conditions for solving and analyzing by means of sequential thermal-force coupling,so as to establish a thermal-force coupling simulation and analysis model for milling processing of CFRP end faces.The model simulation results can provide a basis for exploring the damage evolution law of CFRP material under the influence of temperature. 展开更多
关键词 CFRP MILLING finite element analysis moving heat source thermo-mechanical coupling
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Mechanical behavior analysis in the needling process
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作者 WANG Yiqi feng zhenyang +3 位作者 MAO Yaning YUAN Hang SHI Zelin GAO Hang 《纤维复合材料》 2025年第3期12-16,共5页
A staged modeling approach is proposed to divide the needling process into three stages:deformation,insertion and smoothness,and construct dynamic coupling models of rigid force,cutting force and friction force respec... A staged modeling approach is proposed to divide the needling process into three stages:deformation,insertion and smoothness,and construct dynamic coupling models of rigid force,cutting force and friction force respectively.Based on the Boussinesq contact theory,the initial tip-fabric contact behavior is analyzed,combined with the elastic cutting theo-ry to quantify the fiber breakage mechanism,and the Winkler foundation model and LuGre dynamic friction model are used to characterize the friction properties of the needle shaft.It is shown that:the stiffness force in the deformation stage is af-fected by the geometrical parameters of the needle tip and the elastic modulus of the fabric;the cutting force in the insertion stage is closely related to the micro deformation of the fiber;and the dynamic friction behavior in the smooth stage can be depicted by the LuGre model with high accuracy.The complete needling force prediction model finally established provides a theoretical basis for optimizing composite needling process parameters,reducing fiber damage and equipment design. 展开更多
关键词 fiber fabric force model composite materials needling technology
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RTM工艺过程的缺陷形成分析及边缘效应研究 被引量:1
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作者 王一奇 张新齐 +2 位作者 王超群 冯振杨 桑云飞 《佳木斯大学学报(自然科学版)》 CAS 2024年第1期67-71,共5页
在树脂传递模塑(Resin transfer molding,RTM)工艺中,边缘效应很容易导致制件产生空隙、干斑等缺陷,其根本原因是在纤维增强体和模具模腔之间的间隙区域树脂的流动阻力小,使得树脂在这一区域流动速度更快。基于达西定律并结合流体体积(V... 在树脂传递模塑(Resin transfer molding,RTM)工艺中,边缘效应很容易导致制件产生空隙、干斑等缺陷,其根本原因是在纤维增强体和模具模腔之间的间隙区域树脂的流动阻力小,使得树脂在这一区域流动速度更快。基于达西定律并结合流体体积(Volume of Fluid,VOF)界面追踪方法建立了树脂在纤维增强体中的流动模型,开展RTM工艺边缘效应的数值模拟研究,模型可以准确模拟边缘效应的影响,同时研究树脂粘度及树脂注射压力等工艺参数对于流动时间的影响。研究结果可以对RTM工艺的改善优化提供帮助。 展开更多
关键词 RTM工艺 边缘效应 数值模拟 缺陷 VOF
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