铂族元素(Platinum group elements,PGEs)作为地壳最稀缺的一类金属元素,是重要的战略性矿产资源。非洲铂族金属矿产资源丰富且高度集中,占世界资源量>80%,主要集中在南非和津巴布韦。本文在前人研究基础上,对非洲PGEs矿床主要成矿...铂族元素(Platinum group elements,PGEs)作为地壳最稀缺的一类金属元素,是重要的战略性矿产资源。非洲铂族金属矿产资源丰富且高度集中,占世界资源量>80%,主要集中在南非和津巴布韦。本文在前人研究基础上,对非洲PGEs矿床主要成矿类型、时空分布特点和开发利用现状进行了总结,研究认为:(1)非洲大型-超大型PGEs矿床成因类型主要为岩浆型,在时空上与世界级铁质-镁铁质大火成岩省(南非布什维尔德和津巴布韦大岩墙)密切相关,可细化分为脉状铜镍硫化物型、整合接触型铜镍硫化物型、脉状铬铁矿型和钒钛磁铁矿型。依据区域构造演化及其所产出的矿化特征,认为以铁质-镁铁质岩有关的岩浆型矿床仍具有较大的找矿潜力。(2)非洲铂族金属矿产勘查开发程度相对较高,近十年是全球勘查资金投入最多的地区,同时也是世界第一大铂生产地和第二大钯生产地。从事勘查开发的主要为世界顶级PGEs矿业寡头。(3)非洲是全球一次性铂族金属矿产品主要供应国,主要出口至美国、日本、中国、德国和英国。加强与南非、津巴布韦等国家之间的合作,保障PGEs资源供应的安全对我国尤为重要。展开更多
To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiat...To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiation X-ray fluorescence(SRXRF)analyses of fluid inclusions were conducted.The ore-forming fluid is characterized as an H_(2)O-CO_(2)-NaCl system with medium-high temperatures and low salinity.Four mineralization stages are identified,namely,feldsparquartz(stage 1);pyrite-white quartz(stage 2);sulfide-smoky grey quartz(stage 3);and carbonate-quartz(stage 4).Three types of inclusions were distinguished,based on fluid composition,phase assemblages and mode of homogenization.Type A:H_(2)O-rich fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+vapour H_(2)O(VH_(2)O))at room temperature and homogenize to the liquid phase.Type B:H_(2)O-CO_(2)fluid inclusions contain 2–3 phases(liquid H_(2)O(LH_(2)O)+vapour CO_(2)(VCO_(2));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2)));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))+vapour CO_(2)(VCO_(2)))at room temperature and homogenized to the liquid H_(2)O phase.Type C:H_(2)O-CO_(2)fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))at room temperature and homogenize to a critical state.CO_(2)is clearly more enriched in the fluid inclusions of stages 2 and 3 than in stage 1.Stage 1 is dominated by type A(H_(2)O-rich)inclusions with homogenization temperatures(Th)of 220–359℃and salinities of 1.1–3.1 wt%NaCl equivalent.Type B(CO_(2)-rich)inclusions gradually increase in stages 2 and 3.The Th range of type B inclusions in stage 2 is 241–397℃with salinities of 2.2–6.9 wt%NaCl equivalent;the Th range of type A inclusions is 217–373℃with salinities of 1.2–8.1 wt%NaCl equivalent.The Th range of type B inclusions in stage 3 is 215–361℃with salinities of 2.9–6.1 wt%NaCl equivalent;the range of type A inclusions is 158–351℃with a salinity of 0.7–5.5 wt%NaCl equivalent.Stage 4 is characterized by type A with Th of 151–250℃and salinities of 0.9–8.3 wt%NaCl equivalent.The mapping results show that elements As,Te and Sb are more concentrated in vapour CO_(2)than in liquid H_(2)O at room temperature,which suggests that vapour components are more able to transport elements when phase separation occurs.The SRXRF quantitative results show that Au,Cl,S and some other metals are obviously more enriched in the fluid inclusions of stages 2 and 3 than those in stage 1.Additionally,the contents of S in stages 1–3 are much lower than those of Cl,which suggests that gold might migrate mainly in the form of a gold-chloride complex.Au is more enriched in type B fluid inclusions than in type A fluid inclusions,which suggests that the enrichment and migration of gold are closely related to CO_(2)and CO_(2)plays a critical role in the migration and enrichment of gold.The trace elements in the fluid have a similar change trend to those in the Yanshanian syenogranite distributed in the southeastern part of the mining area,which may provide some evidence for an intrusion-related genesis for the Dongping gold deposit.展开更多
文摘铂族元素(Platinum group elements,PGEs)作为地壳最稀缺的一类金属元素,是重要的战略性矿产资源。非洲铂族金属矿产资源丰富且高度集中,占世界资源量>80%,主要集中在南非和津巴布韦。本文在前人研究基础上,对非洲PGEs矿床主要成矿类型、时空分布特点和开发利用现状进行了总结,研究认为:(1)非洲大型-超大型PGEs矿床成因类型主要为岩浆型,在时空上与世界级铁质-镁铁质大火成岩省(南非布什维尔德和津巴布韦大岩墙)密切相关,可细化分为脉状铜镍硫化物型、整合接触型铜镍硫化物型、脉状铬铁矿型和钒钛磁铁矿型。依据区域构造演化及其所产出的矿化特征,认为以铁质-镁铁质岩有关的岩浆型矿床仍具有较大的找矿潜力。(2)非洲铂族金属矿产勘查开发程度相对较高,近十年是全球勘查资金投入最多的地区,同时也是世界第一大铂生产地和第二大钯生产地。从事勘查开发的主要为世界顶级PGEs矿业寡头。(3)非洲是全球一次性铂族金属矿产品主要供应国,主要出口至美国、日本、中国、德国和英国。加强与南非、津巴布韦等国家之间的合作,保障PGEs资源供应的安全对我国尤为重要。
基金funded by a Natural Science Foundation of Hebei Province(Grant No.D2020403019)the Natural Science Foundation of Hebei Province(Grant Nos.D2020403101 and D2019403041)+2 种基金the Science and Technology Project of Hebei Education Department(Grant No.ZD2020134)the National Natural Science Foundation of China(Grant Nos.41702094 and 41672070)the Science and Technology Innovation Team Project of Hebei GEO University(Grant No.KJCXTD-2021-02)。
文摘To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiation X-ray fluorescence(SRXRF)analyses of fluid inclusions were conducted.The ore-forming fluid is characterized as an H_(2)O-CO_(2)-NaCl system with medium-high temperatures and low salinity.Four mineralization stages are identified,namely,feldsparquartz(stage 1);pyrite-white quartz(stage 2);sulfide-smoky grey quartz(stage 3);and carbonate-quartz(stage 4).Three types of inclusions were distinguished,based on fluid composition,phase assemblages and mode of homogenization.Type A:H_(2)O-rich fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+vapour H_(2)O(VH_(2)O))at room temperature and homogenize to the liquid phase.Type B:H_(2)O-CO_(2)fluid inclusions contain 2–3 phases(liquid H_(2)O(LH_(2)O)+vapour CO_(2)(VCO_(2));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2)));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))+vapour CO_(2)(VCO_(2)))at room temperature and homogenized to the liquid H_(2)O phase.Type C:H_(2)O-CO_(2)fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))at room temperature and homogenize to a critical state.CO_(2)is clearly more enriched in the fluid inclusions of stages 2 and 3 than in stage 1.Stage 1 is dominated by type A(H_(2)O-rich)inclusions with homogenization temperatures(Th)of 220–359℃and salinities of 1.1–3.1 wt%NaCl equivalent.Type B(CO_(2)-rich)inclusions gradually increase in stages 2 and 3.The Th range of type B inclusions in stage 2 is 241–397℃with salinities of 2.2–6.9 wt%NaCl equivalent;the Th range of type A inclusions is 217–373℃with salinities of 1.2–8.1 wt%NaCl equivalent.The Th range of type B inclusions in stage 3 is 215–361℃with salinities of 2.9–6.1 wt%NaCl equivalent;the range of type A inclusions is 158–351℃with a salinity of 0.7–5.5 wt%NaCl equivalent.Stage 4 is characterized by type A with Th of 151–250℃and salinities of 0.9–8.3 wt%NaCl equivalent.The mapping results show that elements As,Te and Sb are more concentrated in vapour CO_(2)than in liquid H_(2)O at room temperature,which suggests that vapour components are more able to transport elements when phase separation occurs.The SRXRF quantitative results show that Au,Cl,S and some other metals are obviously more enriched in the fluid inclusions of stages 2 and 3 than those in stage 1.Additionally,the contents of S in stages 1–3 are much lower than those of Cl,which suggests that gold might migrate mainly in the form of a gold-chloride complex.Au is more enriched in type B fluid inclusions than in type A fluid inclusions,which suggests that the enrichment and migration of gold are closely related to CO_(2)and CO_(2)plays a critical role in the migration and enrichment of gold.The trace elements in the fluid have a similar change trend to those in the Yanshanian syenogranite distributed in the southeastern part of the mining area,which may provide some evidence for an intrusion-related genesis for the Dongping gold deposit.
