Track irregularity from rail alternate side wear is manifested as uneven rail wear waveforms alternating in the left and right rails with equal intervals,which will cause carbody sway behaviour of railway vehicles and...Track irregularity from rail alternate side wear is manifested as uneven rail wear waveforms alternating in the left and right rails with equal intervals,which will cause carbody sway behaviour of railway vehicles and greatly influences the passenger comfort.In this work,the carbody sway behaviour and mechanism due to track irregularity from rail alternate side wear and possible solutions to this issue were studied by the field testing and numerical calculation approaches.First,the carbody sway of an urban rail transit train is introduced with full-scale field tests,through which the rail alternate side wear is characterized and the formatted track irregularity are presented.Then,multibody vehicle dynamic models are developed to reproduce the carbody sway behaviour induced by the track irregularity from the rail alternate side wear.The creep forces acting on the wheel and rail are preliminarily discussed to study the influence of the carbody sway on the wear of the wheel flange and the rail corner.Finally,some potential solutions,e.g.improving the damping ratio of carbody rigid mode and rail grinding,are proposed to relieve this issue.It is concluded that an increased damping ratio of the carbody mode can alleviate the carbody sway and wheel–rail interactions,while properly maintaining track conditions can improve the vehicle performance.展开更多
The evolution of cracks in shale directly affects the efficient production of shale gas.However,there is a lack of research on the characteristics of crack initiation in deep dense shale under different stress conditi...The evolution of cracks in shale directly affects the efficient production of shale gas.However,there is a lack of research on the characteristics of crack initiation in deep dense shale under different stress conditions.In this work,considering the different combinations of confining pressure and bedding plane inclination angle(α),biaxial mechanical loading experiments were conducted on shale containing circular holes.The research results indicate that the confining pressure and inclination angle of the bedding planes significantly influence the failure patterns of shale containing circular holes.The instability of shale containing circular holes can be classified into five types:tensile failure along the bedding planes,tensile failure through the bedding planes,shear slip along the bedding planes,shear failure through the bedding planes,and block instability failure.Furthermore,the evolution of strain and stress fields around the circular holes was found to be the fundamental cause of variations in the initiation characteristics and locations of shale cracks.The crack initiation criterion for shale containing circular hole was established,providing a new method for evaluating the trajectory of shale hole wall fractures.This study holds significant importance for evaluating the evolution and stability of fracture networks within shale reservoirs.展开更多
Electrospun nanofibrous separators,despite lacking superior mechanical strength,have gained widespread attention with high porosity and facile processing.Herein,utilizing the fact that thermal imidization temperature ...Electrospun nanofibrous separators,despite lacking superior mechanical strength,have gained widespread attention with high porosity and facile processing.Herein,utilizing the fact that thermal imidization temperature of poly(amic acid)(PAA)into polyimide(PI)coincides with the pre-oxidation temperature of polyacrylonitrile(PAN)into carbon fiber,we proposed a new cross-electrospinning strategy to obtain a composite nanofibrous separator(PI/oPAN)randomly interwoven by PI and pre-oxidized PAN(oPAN)nanofibers,via synchronously electrospinning the PAA and PAN onto the same collector and then heat-treating for 2 h at 300℃.The resultant PI/oPAN separator was able to preserve high porosity(71.7%),electrolyte wettability and thermal stability of PI nanofibrous membrane,and surprisingly exhibited high mechanical strength,being 3 times of PI,which mainly because of the numerous adhesion points generated by the melting of PAN in the pre-oxidation process.Meanwhile,the polar groups of oPAN and 3D fibrous network enhanced the PI/oPAN separator's ionic conductivity and Li+transference number,rendering the corresponding cell with more stable cycling performance than cells assembled with pure PI,PAN or commercial PP separator.Therefore,this work might provide a new avenue for the ongoing design and further development of LIB separators capable of high safety and high performance.展开更多
Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability....Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability.In this study,a novel perovskite-based composite with positive sensitivity to temperature was designed and obtained based on its inverse temperature crystallization,demonstrating good flexibility and solution processability.The supercritical drying method was used to address the limitations of annealing drying in preparing high-performance perovskite.Optimizing the precursor composition proved to be an effective approach for achieving high fluorescence and structural integrity in the perovskite material.This perovskite-based composite exhibited a positive temperature sensitivity of 28.563%℃^(-1)for intensity change and excellent temperature cycling reversibility in the range of 25-40℃in an ambient environment.This made it suitable for use as a smart window with rapid response.Furthermore,the perovskite composite was found to offer temperature-sensing photoluminescence and flexible processability due to its components of perovskite-based compounds and polyethylene oxide.The organic precursor solvent could be a promising candidate for use as ink to print or write on various substrates for optoelectronic devices responding to temperature.展开更多
An effective design strategy for preparing highly transparent polyimide film with low dielectric constant is presented.The key to the strategy is to simultaneously introduce meta-substituted structure and trifluoromet...An effective design strategy for preparing highly transparent polyimide film with low dielectric constant is presented.The key to the strategy is to simultaneously introduce meta-substituted structure and trifluoromethyl in polymer chains.By using this design strategy,a highly transparent polyimide film with low-k was synthesized from 3,5-diaminobenzotrifluoride(m-TFPDA)and 4,4'-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)through a two-step method.The obtained m-TFPDA/6FDA(CPI)film(~30 pm)possesses high optical transparency(λ_(cutoff)=334 nm,T_(450nm)=85.26%,Haze=0.31)and is close to colorless(L^(*)=96.03,a^(*)=-0.34,b^(*)=2.12,yellow index=3.96).The intrinsic k and dielectric loss value of the film are 2.27 and 0.0013 at 10 kHz,respectively.More importantly,such low dielectric performance could remain stable up to 280℃,and the film shows a low moisture rate(~0.51%),which helps to maintain the low-k property stability in different humid environments.Meanwhile,the film also shows good thermal stability and mechanical properties,with a glass transition temperature(T_(g))of 296℃and the 5 wt%decomposition temperature(T_(d,s%))of 522℃under N_(2).The tensile strength and tensile modulus of the film are 85.1 MPa and 1.96 GPa,respectively.In addition,the film is soluble in common solvents,which allows simple solution processing and low-cost,continuous roll-to-roll processes.This design strategy is beneficial to improving the transparency,lightening yellow color,lowering the dielectric constant and meanwhile maintaining the comprehensive properties of polyimide films,which is mainly due to the introduced meta-substituted and trifluoromethyl structures effectively inhibiting the transfer of charge transfer complex(CTC)effects and increasing the free volume of film.This design strategy could also be extended to other high-performance polymer systems.展开更多
The strategy of N-doping in carbon materials could provide additional Li-ion storage sites to improve their electrochemical properties. Heteroatom-containing polymers could serve as good precursors to fabricate doped ...The strategy of N-doping in carbon materials could provide additional Li-ion storage sites to improve their electrochemical properties. Heteroatom-containing polymers could serve as good precursors to fabricate doped carbons due to the capability to in situ dope heteroatoms into the structures, In this work, electrospun heterocyclic polyimide （PI） nanofiber membranes containing biphenyl and pyrimidine rings were carbonized to fabricate freestanding and flexible heteroatoms-containing carbon membranes. When the polymer membranes were subjected to various calcination temperatures （from 550℃ to 950 ℃） and durations （0.5-10 h）, the structural evolutions strongly affect their electrochemical properties as anodes for lithium ion batteries. It demonstrated that the reversible specific capacity of obtained sample treated at 650 ℃ for 3 h could achieve 695 mAh/g at 0.1 A/g and retain 245 mAh/g at 1.5 A/g after 300 cycles. Furthermore, the electrospun membrane maintains a good electrochemical performance at bending state as a flexible electrode.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.52002344,U2034210,and 61960206010)the Development Project of State Key Laboratory of Rail Transit Vehicle System(Grant No.2022TPL_T09)。
文摘Track irregularity from rail alternate side wear is manifested as uneven rail wear waveforms alternating in the left and right rails with equal intervals,which will cause carbody sway behaviour of railway vehicles and greatly influences the passenger comfort.In this work,the carbody sway behaviour and mechanism due to track irregularity from rail alternate side wear and possible solutions to this issue were studied by the field testing and numerical calculation approaches.First,the carbody sway of an urban rail transit train is introduced with full-scale field tests,through which the rail alternate side wear is characterized and the formatted track irregularity are presented.Then,multibody vehicle dynamic models are developed to reproduce the carbody sway behaviour induced by the track irregularity from the rail alternate side wear.The creep forces acting on the wheel and rail are preliminarily discussed to study the influence of the carbody sway on the wear of the wheel flange and the rail corner.Finally,some potential solutions,e.g.improving the damping ratio of carbody rigid mode and rail grinding,are proposed to relieve this issue.It is concluded that an increased damping ratio of the carbody mode can alleviate the carbody sway and wheel–rail interactions,while properly maintaining track conditions can improve the vehicle performance.
基金Projects(52104143,52109135,52374099)supported by the National Natural Science Foundation of ChinaProject(2025YFHZ0323)supported by the Natural Science Foundation of Sichuan Province,China。
文摘The evolution of cracks in shale directly affects the efficient production of shale gas.However,there is a lack of research on the characteristics of crack initiation in deep dense shale under different stress conditions.In this work,considering the different combinations of confining pressure and bedding plane inclination angle(α),biaxial mechanical loading experiments were conducted on shale containing circular holes.The research results indicate that the confining pressure and inclination angle of the bedding planes significantly influence the failure patterns of shale containing circular holes.The instability of shale containing circular holes can be classified into five types:tensile failure along the bedding planes,tensile failure through the bedding planes,shear slip along the bedding planes,shear failure through the bedding planes,and block instability failure.Furthermore,the evolution of strain and stress fields around the circular holes was found to be the fundamental cause of variations in the initiation characteristics and locations of shale cracks.The crack initiation criterion for shale containing circular hole was established,providing a new method for evaluating the trajectory of shale hole wall fractures.This study holds significant importance for evaluating the evolution and stability of fracture networks within shale reservoirs.
基金financially supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.22KJA480004)the Key Laboratory of Flame Retardancy Finishing of Textile Materials,CNTAC(No.Q811580421)。
文摘Electrospun nanofibrous separators,despite lacking superior mechanical strength,have gained widespread attention with high porosity and facile processing.Herein,utilizing the fact that thermal imidization temperature of poly(amic acid)(PAA)into polyimide(PI)coincides with the pre-oxidation temperature of polyacrylonitrile(PAN)into carbon fiber,we proposed a new cross-electrospinning strategy to obtain a composite nanofibrous separator(PI/oPAN)randomly interwoven by PI and pre-oxidized PAN(oPAN)nanofibers,via synchronously electrospinning the PAA and PAN onto the same collector and then heat-treating for 2 h at 300℃.The resultant PI/oPAN separator was able to preserve high porosity(71.7%),electrolyte wettability and thermal stability of PI nanofibrous membrane,and surprisingly exhibited high mechanical strength,being 3 times of PI,which mainly because of the numerous adhesion points generated by the melting of PAN in the pre-oxidation process.Meanwhile,the polar groups of oPAN and 3D fibrous network enhanced the PI/oPAN separator's ionic conductivity and Li+transference number,rendering the corresponding cell with more stable cycling performance than cells assembled with pure PI,PAN or commercial PP separator.Therefore,this work might provide a new avenue for the ongoing design and further development of LIB separators capable of high safety and high performance.
基金the financial support from the National Natural Science Foundation of China(No.61904005,52103010 and 52003200)Guangdong Provincial Department of Education Featured Innovation Project(No.2021KTSCX138)+4 种基金Jiangmen Key Project of Research for Basic and Basic Application(No.2021030102800007443 and 2021030102790006114)the Science Foundation for Young Research Group of Wuyi University(No.2020AL021,2019AL019,and 2020AL016)Wuyi University-Hong Kong/Macao Joint Research Funds(No.2021WGALH05)Youth Innovation Talent Project for the Universities of Guangdong(No.2020KQNCX089)Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110897)
文摘Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability.In this study,a novel perovskite-based composite with positive sensitivity to temperature was designed and obtained based on its inverse temperature crystallization,demonstrating good flexibility and solution processability.The supercritical drying method was used to address the limitations of annealing drying in preparing high-performance perovskite.Optimizing the precursor composition proved to be an effective approach for achieving high fluorescence and structural integrity in the perovskite material.This perovskite-based composite exhibited a positive temperature sensitivity of 28.563%℃^(-1)for intensity change and excellent temperature cycling reversibility in the range of 25-40℃in an ambient environment.This made it suitable for use as a smart window with rapid response.Furthermore,the perovskite composite was found to offer temperature-sensing photoluminescence and flexible processability due to its components of perovskite-based compounds and polyethylene oxide.The organic precursor solvent could be a promising candidate for use as ink to print or write on various substrates for optoelectronic devices responding to temperature.
基金supported by the Scientific Research Inn ovation Plan of Sha nghai Education Commission(No.2019-01-07-00-03-E0001)the National Natural Science Foundation of China(Nos.21774019,21975040,51903038)+2 种基金the Program of Shanghai Academic Research Leader(No.18XD1400100)the Natural Science Foundation of Shanghai(No.18ZR1400600)the DHU Distinguished Young Professor Program.
文摘An effective design strategy for preparing highly transparent polyimide film with low dielectric constant is presented.The key to the strategy is to simultaneously introduce meta-substituted structure and trifluoromethyl in polymer chains.By using this design strategy,a highly transparent polyimide film with low-k was synthesized from 3,5-diaminobenzotrifluoride(m-TFPDA)and 4,4'-(hexafluoroisopropylidene)diphthalic anhydride(6FDA)through a two-step method.The obtained m-TFPDA/6FDA(CPI)film(~30 pm)possesses high optical transparency(λ_(cutoff)=334 nm,T_(450nm)=85.26%,Haze=0.31)and is close to colorless(L^(*)=96.03,a^(*)=-0.34,b^(*)=2.12,yellow index=3.96).The intrinsic k and dielectric loss value of the film are 2.27 and 0.0013 at 10 kHz,respectively.More importantly,such low dielectric performance could remain stable up to 280℃,and the film shows a low moisture rate(~0.51%),which helps to maintain the low-k property stability in different humid environments.Meanwhile,the film also shows good thermal stability and mechanical properties,with a glass transition temperature(T_(g))of 296℃and the 5 wt%decomposition temperature(T_(d,s%))of 522℃under N_(2).The tensile strength and tensile modulus of the film are 85.1 MPa and 1.96 GPa,respectively.In addition,the film is soluble in common solvents,which allows simple solution processing and low-cost,continuous roll-to-roll processes.This design strategy is beneficial to improving the transparency,lightening yellow color,lowering the dielectric constant and meanwhile maintaining the comprehensive properties of polyimide films,which is mainly due to the introduced meta-substituted and trifluoromethyl structures effectively inhibiting the transfer of charge transfer complex(CTC)effects and increasing the free volume of film.This design strategy could also be extended to other high-performance polymer systems.
基金financially supported by the DHU Distinguished Young Professor Programthe National Natural Science Foundation of China (No. 51403036)
文摘The strategy of N-doping in carbon materials could provide additional Li-ion storage sites to improve their electrochemical properties. Heteroatom-containing polymers could serve as good precursors to fabricate doped carbons due to the capability to in situ dope heteroatoms into the structures, In this work, electrospun heterocyclic polyimide （PI） nanofiber membranes containing biphenyl and pyrimidine rings were carbonized to fabricate freestanding and flexible heteroatoms-containing carbon membranes. When the polymer membranes were subjected to various calcination temperatures （from 550℃ to 950 ℃） and durations （0.5-10 h）, the structural evolutions strongly affect their electrochemical properties as anodes for lithium ion batteries. It demonstrated that the reversible specific capacity of obtained sample treated at 650 ℃ for 3 h could achieve 695 mAh/g at 0.1 A/g and retain 245 mAh/g at 1.5 A/g after 300 cycles. Furthermore, the electrospun membrane maintains a good electrochemical performance at bending state as a flexible electrode.
