For a long time,the conventional superplastic forming temperature for Ti alloys is generally too high(~900-920℃),which leads to too long production cycles,heavy surface oxidation,and property reduction.In this study,...For a long time,the conventional superplastic forming temperature for Ti alloys is generally too high(~900-920℃),which leads to too long production cycles,heavy surface oxidation,and property reduction.In this study,an ultrafine bimodal microstructure,consisting of ultrafine equiaxed microstructure(0.66μm)and 43.3%lamellar microstructure,was achieved in the Ti-6Al-4V alloy by friction stir processing(FSP).The low-temperature superplastic behavior and deformation mechanism of the FSP Ti-6Al-4V alloy were investigated at temperatures of 550-675℃and strain rates ranging from 1×10^(−4)to 3×10^(−3)s^(−1).The FSP alloy exhibited superplastic elongations of>200%at the temperature range from 550 to 650℃,and an optimal superplastic elongation of 611%was achieved at 625℃and 1×10^(−4)s^(−1).This is the first time to report the low-temperature superplasticity of the bimodal microstructure in Ti alloys.Grain boundary sliding was identified as the dominant deformation mechanism,which was effectively accommodated by the comprehensive effect of dislocation-inducedβphase precipitation and dynamic spheroidization of the lamellar structure.This study provides a novel insight into the low-temperature superplastic deformation behavior of the bimodal microstructure.展开更多
Large-scale components of steel and aluminum alloys(Fe-Al)with high bonding strength are highly needed from space exploration to the fabrication of transportation systems.The formation of detrimental intermetallic com...Large-scale components of steel and aluminum alloys(Fe-Al)with high bonding strength are highly needed from space exploration to the fabrication of transportation systems.The formation of detrimental intermetallic compounds at the Al-Fe interface has limited the application range of the Fe-Al components.The modified friction stir additive manufacturing was developed for fabricating large-scale Fe-Al compo-nents with homogenously distributed interfacial amorphous layers rather than detrimental intermetallic compounds.The interfacial amorphous layers comprised an Mg-O rich amorphous layer<20 nm in thick-ness and an Al-Fe-Si amorphous layer<120 nm in thickness.The interfacial amorphous layers exhibited high thermal stability and did not change even after the post-processing heat treatment of heating at 500℃ for 20 min and aging at 170℃ for 7 h.The tensile strengths of the Fe-Al tensile specimens were increased from 160 to 250 MPa after the application of the post-processing heat treatment.The fracture occurred in the aluminum alloys instead of at the dissimilar metal interface,demonstrating that high bonding strength at the Al-Fe interface was enabled by the formation of homogenously distributed interfacial amorphous layers.展开更多
A major dilemma faced in the nuclear industry is repair of stainless steel reactor components that have been exposed to neutron irradiation. When conventional fusion welding is used for repair, intergranular cracks de...A major dilemma faced in the nuclear industry is repair of stainless steel reactor components that have been exposed to neutron irradiation. When conventional fusion welding is used for repair, intergranular cracks develop in the heat-affected zone(HAZ). Friction stir processing(FSP), which operates at much lower peak temperatures than fusion welding, was studied as a crack repair method for irradiated 304 L stainless steel. A numerical simulation of the FSP process in 304 L was developed to predict temperatures and recrystallized grain size in the stir zone. The model employed an Eulerian finite element approach,where flow stresses for a large range of strain rates and temperatures inherent in FSP were used as input. Temperature predictions in three locations near the stir zone were accurate to within 4%, while prediction of welding power was accurate to within 5% of experimental measurements. The predicted recrystallized grain sizes ranged from 7.6 to 10.6 μm, while the experimentally measured grains sizes in the same locations ranged from 6.0 to 7.6 μm. The maximum error in predicted recrystallized grain size was about 39%, but the associated stir zone hardness from the predicted grain sizes was only different from the experiment by about 10%.展开更多
Friction stir processing （FSP） was investigated as a method of repairing cracks in 12 mm thick 304L stainless steel plate. Healing feasibility was demonstrated by processing a tapered crack using a PCBN/W- Re tool w...Friction stir processing （FSP） was investigated as a method of repairing cracks in 12 mm thick 304L stainless steel plate. Healing feasibility was demonstrated by processing a tapered crack using a PCBN/W- Re tool with a 25 mm diameter shoulder and a pin length of 6.4 mm. The experiment showed that it was possible to heal a crack that begins narrow and then progressively grows up to a width of 2 mm. Bead on plate experiments were used to find the best parameters for creating a consolidated stir zone with the least amount of hardness difference compared to the base metal. Grain refinement in some specimens resulted in much higher stir zone hardness, compared to base metal, A plot of grain size versus microhardness showed a very strong inverse correlation between grain size and hardness, as expected from the Hall- Perch relationship. Corrosion testing was carried out in order to evaluate the effect of FSP on potential sensitization of the stir zone. After 1000 h of intermittent immersion in 3.5% saline solution at room temperature it was found that no corrosion products formed on the base material controls or on any of the friction stir processed specimens.展开更多
基金supported by the funding from the Shi Changxu Innovation Center for Advanced Materials(No.SCXKFJJ202210)the National Natural Science Foundation of China(No.52271043)+2 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2021193)the Liaoning Province Excellent Youth Foundation(No.2024JH3/10200021)the Liaoning Revitalization Talents Program(No.XLYC2403094).
文摘For a long time,the conventional superplastic forming temperature for Ti alloys is generally too high(~900-920℃),which leads to too long production cycles,heavy surface oxidation,and property reduction.In this study,an ultrafine bimodal microstructure,consisting of ultrafine equiaxed microstructure(0.66μm)and 43.3%lamellar microstructure,was achieved in the Ti-6Al-4V alloy by friction stir processing(FSP).The low-temperature superplastic behavior and deformation mechanism of the FSP Ti-6Al-4V alloy were investigated at temperatures of 550-675℃and strain rates ranging from 1×10^(−4)to 3×10^(−3)s^(−1).The FSP alloy exhibited superplastic elongations of>200%at the temperature range from 550 to 650℃,and an optimal superplastic elongation of 611%was achieved at 625℃and 1×10^(−4)s^(−1).This is the first time to report the low-temperature superplasticity of the bimodal microstructure in Ti alloys.Grain boundary sliding was identified as the dominant deformation mechanism,which was effectively accommodated by the comprehensive effect of dislocation-inducedβphase precipitation and dynamic spheroidization of the lamellar structure.This study provides a novel insight into the low-temperature superplastic deformation behavior of the bimodal microstructure.
基金supported by the National Natu-ral Science Foundation of China(Nos.52375396,52034005,and 51975553)the Liaoning Provincial Department of Science and Technology(No.2023JH2/101300149)+4 种基金the Shenyang Science and Technology Bureau(No.22-315-6-03)and Institute of Metal Re-search,Chinese Academy of Sciences(No.2023-ZD02-01)the Liaoning Province Excellent Youth Foundation(No.2021-YQ-01)the Program of the Youth Innovation Promotion Association of the Chi-nese Academy of Sciences(No.Y2021061)the Bintech-IMR R&D Program(No.GYY-JSBU-2022-002).
文摘Large-scale components of steel and aluminum alloys(Fe-Al)with high bonding strength are highly needed from space exploration to the fabrication of transportation systems.The formation of detrimental intermetallic compounds at the Al-Fe interface has limited the application range of the Fe-Al components.The modified friction stir additive manufacturing was developed for fabricating large-scale Fe-Al compo-nents with homogenously distributed interfacial amorphous layers rather than detrimental intermetallic compounds.The interfacial amorphous layers comprised an Mg-O rich amorphous layer<20 nm in thick-ness and an Al-Fe-Si amorphous layer<120 nm in thickness.The interfacial amorphous layers exhibited high thermal stability and did not change even after the post-processing heat treatment of heating at 500℃ for 20 min and aging at 170℃ for 7 h.The tensile strengths of the Fe-Al tensile specimens were increased from 160 to 250 MPa after the application of the post-processing heat treatment.The fracture occurred in the aluminum alloys instead of at the dissimilar metal interface,demonstrating that high bonding strength at the Al-Fe interface was enabled by the formation of homogenously distributed interfacial amorphous layers.
基金supported by the National Science Foundation grant CMMI-1405508
文摘A major dilemma faced in the nuclear industry is repair of stainless steel reactor components that have been exposed to neutron irradiation. When conventional fusion welding is used for repair, intergranular cracks develop in the heat-affected zone(HAZ). Friction stir processing(FSP), which operates at much lower peak temperatures than fusion welding, was studied as a crack repair method for irradiated 304 L stainless steel. A numerical simulation of the FSP process in 304 L was developed to predict temperatures and recrystallized grain size in the stir zone. The model employed an Eulerian finite element approach,where flow stresses for a large range of strain rates and temperatures inherent in FSP were used as input. Temperature predictions in three locations near the stir zone were accurate to within 4%, while prediction of welding power was accurate to within 5% of experimental measurements. The predicted recrystallized grain sizes ranged from 7.6 to 10.6 μm, while the experimentally measured grains sizes in the same locations ranged from 6.0 to 7.6 μm. The maximum error in predicted recrystallized grain size was about 39%, but the associated stir zone hardness from the predicted grain sizes was only different from the experiment by about 10%.
基金financial support of the project by National Science Foundation award CMII-1405508
文摘Friction stir processing （FSP） was investigated as a method of repairing cracks in 12 mm thick 304L stainless steel plate. Healing feasibility was demonstrated by processing a tapered crack using a PCBN/W- Re tool with a 25 mm diameter shoulder and a pin length of 6.4 mm. The experiment showed that it was possible to heal a crack that begins narrow and then progressively grows up to a width of 2 mm. Bead on plate experiments were used to find the best parameters for creating a consolidated stir zone with the least amount of hardness difference compared to the base metal. Grain refinement in some specimens resulted in much higher stir zone hardness, compared to base metal, A plot of grain size versus microhardness showed a very strong inverse correlation between grain size and hardness, as expected from the Hall- Perch relationship. Corrosion testing was carried out in order to evaluate the effect of FSP on potential sensitization of the stir zone. After 1000 h of intermittent immersion in 3.5% saline solution at room temperature it was found that no corrosion products formed on the base material controls or on any of the friction stir processed specimens.
