Land surface temperature(LST)is the key variable in land-atmosphere interaction,having an important impact on weather and climate forecasting.However,achieving consistent analysis of LST and the atmosphere in assimila...Land surface temperature(LST)is the key variable in land-atmosphere interaction,having an important impact on weather and climate forecasting.However,achieving consistent analysis of LST and the atmosphere in assimilation is quite challenging.This is because there is limited knowledge about the cross-component background error covariance(BEC)between LST and atmospheric state variables.This study aims to clarify whether there is a relationship between the error of LST and atmospheric variables,and whether this relationship varies spatially and temporally.To this end,the BEC coupled with atmospheric variables and LST was constructed(LST-BEC),and its characteristics were analyzed based on the 2023 mei-yu season.The general characteristics of LST-BEC show that the LST is mainly correlated with the atmospheric temperature and the correlation decreases gradually with a rise in atmospheric height,and the error standard deviation of the LST is noticeably larger than that of the low-level atmospheric temperature.The spatiotemporal characteristics of LST-BEC on the heavy-rain day and light-rain day show that the error correlation and error standard deviation of LST and low-level atmospheric temperature and humidity are closely related to the weather background,and also have obvious diurnal variations.These results provide valuable information for strongly coupled land-atmosphere assimilation.展开更多
Accurate skin temperature is one of the critical factors in successfully assimilating satellite radiance data over land.However,model-simulated skin temperature may not be accurate enough.To address this issue,an exte...Accurate skin temperature is one of the critical factors in successfully assimilating satellite radiance data over land.However,model-simulated skin temperature may not be accurate enough.To address this issue,an extended skin temperature control variable(TSCV) approach is proposed in a variational assimilation framework,which also considers the background error correlation between skin temperature and atmospheric variables.A series of single observation tests and a 10-day cycling assimilation experiment were conducted to evaluate the impact of the TSCV approach on the assimilation of AMSU-A and ATMS(Advanced Technology Microwave Sounder) microwave temperature-sounding channels over land.The results of the single observation tests show that by applying the TSCV approach,not only the direct analysis of skin temperature is realized,but also the interaction between skin temperature and atmospheric variables can be achieved during the assimilation process.The results of the cycling experiment demonstrate that the TSCV approach improves the skin temperature analysis,which in turn reduces the RMSE of the surface variables and low-level air temperature forecasts.The TSCV approach also reduces the difference between the observed and simulated brightness temperatures of both microwave and infrared window channels over land,suggesting that the approach can facilitate the radiance simulation of these channels,thus contributing to the assimilation of window channels.展开更多
Hydrometeor variables （cloud water and cloud ice mixing ratios） are added into the WRF three-dimensional variational assimilation system as additional control variables to directly analyze hydrometeors by assimilati...Hydrometeor variables （cloud water and cloud ice mixing ratios） are added into the WRF three-dimensional variational assimilation system as additional control variables to directly analyze hydrometeors by assimilating cloud observations. In addition, the background error covariance matrix of hydrometeors is modeled through a control variable transform, and its characteristics discussed in detail. A suite of experiments using four microphysics schemes （LIN, SBU-YLIN, WDM6 and WSM6） are performed with and without assimilating satellite cloud liquid/ice water path. We find analysis of hydrometeors with cloud assimilation to be significantly improved, and the increment and distribution of hydrometeors are consistent with the characteristics of background error covariance. Diagnostic results suggest that the forecast with cloud assimilation represents a significant improvement, especially the ability to forecast precipitation in the first seven hours. It is also found that the largest improvement occurs in the experiment using the WDM6 scheme, since the assimilated cloud information can sustain for longer in this scheme. The least improvement, meanwhile, appears in the experiment using the SBU-YLIN scheme.展开更多
The high observation efficiency,scanning speed and observation frequency of the Fengyun-4A(FY-4A)satellite indicates the progress of Chinese geostationary meteorological satellites.The characteristics of FY-4A atmosph...The high observation efficiency,scanning speed and observation frequency of the Fengyun-4A(FY-4A)satellite indicates the progress of Chinese geostationary meteorological satellites.The characteristics of FY-4A atmospheric motion vectors(AMVs)derived from the high-level water vapor(WV-High)channel,mid-level water vapor(WV-Mid)channel,and infrared(IR)channel of FY-4A are analyzed,and their corresponding observation errors estimated.Then,the impacts of single-channel and multi-channel FY-4A AMVs on RMAPS-ST(the Rapid-refresh Multi-scale Analysis and Prediction System-Short Term)are evaluated based on one-month data assimilation cycling and forecasting experiments.Results show that the observation errors of FY-4A AMVs from the three channels have an explicit vertical structure.Results from the cycling experiments indicate that the assimilation of AMVs from WV-High produces more apparent improvement of the wind in the upper layer,while a more positive effect in the lower layer is achieved by the assimilation of AMVs from IR.Furthermore,the assimilation of AMVs from IR is more skillful for medium and moderate precipitation than from other channels owing to the good quality of data in the lower layer in the AMVs from IR.Assimilation of FY-4A AMVs from the three channels could combine the advantages of assimilation from each individual channel to improve the wind in the upper,middle and lower layers simultaneously.展开更多
Precipitation detection is an essential step in radiance assimilation because the uncertainties in precipitation would affect the radiative transfer calculation and observation errors.The traditional precipitation det...Precipitation detection is an essential step in radiance assimilation because the uncertainties in precipitation would affect the radiative transfer calculation and observation errors.The traditional precipitation detection method for microwave only detects clouds and precipitation horizontally,without considering the three-dimensional distribution of clouds.Extending precipitation detection from 2D to 3D is expected to bring more useful information to the data assimilation without using the all-sky approach.In this study,the 3D precipitation detection method is adopted to assimilate Microwave Temperature Sounder-2(MWTS-Ⅱ)onboard the Fengyun-3D,which can dynamically detect the channels above precipitating clouds by considering the near-real-time cloud parameters.Cycling data assimilation and forecasting experiments for Typhoons Lekima(2019)and Mitag(2019)are carried out.Compared with the control experiment,the quantity of assimilated data with the 3D precipitation detection increases by approximately 23%.The quality of the additional MWTS-Ⅱradiance data is close to the clear-sky data.The case studies show that the average root-mean-square errors(RMSE)of prognostic variables are reduced by 1.7%in the upper troposphere,leading to an average reduction of4.53%in typhoon track forecasts.The detailed diagnoses of Typhoon Lekima(2019)further show that the additional MWTS-Ⅱradiances brought by the 3D precipitation detection facilitate portraying a more reasonable circulation situation,thus providing more precise structures.This paper preliminarily proves that 3D precipitation detection has potential added value for increasing satellite data utilization and improving typhoon forecasts.展开更多
A unique nest-type catalyst has been designed with a nest of oxygen capture surrounding catalytic Pt centers, which shows much promoted performance, on the base of Pt/C catalyst, for oxygen reduction reaction(ORR). Th...A unique nest-type catalyst has been designed with a nest of oxygen capture surrounding catalytic Pt centers, which shows much promoted performance, on the base of Pt/C catalyst, for oxygen reduction reaction(ORR). The nest is constructed with nitrogen-doped carbon matrix(NCM), derived from the controlled carbonization of PANI precursor, to cover Pt/C catalyst. The unique structure of the catalyst(denoted as NCM■ Pt/C) has many merits. Firstly, it can capture oxygen both in air and in acidic electrolyte. Compared with naked Pt/C, it is found that, in air, the oxygen concentration within the porous nest of NCM surrounding Pt/C particles is ~13 times higher than atmospheric oxygen concentration and, in acidic electrolyte, the concentration of activated oxygen over the catalyst NCM■ Pt/C rise to~1.9 times. Secondly, the NCM nest offers a special electronic modulation on Pt centers toward modified ORR kinetics and then catalytic performances. With these merits, compared with Pt/C, the NCM■ Pt/C catalyst shows 3.2 times higher turnover frequency value and 2.9 times enhanced specific activity for ORR with half-wave potential at 0.894 V. After 50,000 sweeping cycles, the NCM■ Pt/C catalyst retains~66% mass activity and still has advantages over the fresh Pt/C catalyst. We envision that the nest-type catalyst provides a new idea for progress of practical Pt/C ORR catalyst.展开更多
Use of data assimilation to initialize hydrometeors plays a vital role in numerical weather prediction(NWP).To directly analyze hydrometeors in data assimilation systems from cloud-sensitive observations,hydrometeor c...Use of data assimilation to initialize hydrometeors plays a vital role in numerical weather prediction(NWP).To directly analyze hydrometeors in data assimilation systems from cloud-sensitive observations,hydrometeor control variables are necessary.Common data assimilation systems theoretically require that the probability density functions(PDFs)of analysis,background,and observation errors should satisfy the Gaussian unbiased assumptions.In this study,a Gaussian transform method is proposed to transform hydrometeors to more Gaussian variables,which is modified from the Softmax function and renamed as Quasi-Softmax transform.The Quasi-Softmax transform method then is compared to the original hydrometeor mixing ratios and their logarithmic transform and Softmax transform.The spatial distribution,the non-Gaussian nature of the background errors,and the characteristics of the background errors of hydrometeors in each method are studied.Compared to the logarithmic and Softmax transform,the Quasi-Softmax method keeps the vertical distribution of the original hydrometeor mixing ratios to the greatest extent.The results of the D′Agostino test show that the hydrometeors transformed by the Quasi-Softmax method are more Gaussian when compared to the other methods.The Gaussian transform has been added to the control variable transform to estimate the background error covariances.Results show that the characteristics of the hydrometeor background errors are reasonable for the Quasi-Softmax method.The transformed hydrometeors using the Quasi-Softmax transform meet the Gaussian unbiased assumptions of the data assimilation system,and are promising control variables for data assimilation systems.展开更多
基金sponsored by the National Natural Science Foundation of China[grant number U2442218]。
文摘Land surface temperature(LST)is the key variable in land-atmosphere interaction,having an important impact on weather and climate forecasting.However,achieving consistent analysis of LST and the atmosphere in assimilation is quite challenging.This is because there is limited knowledge about the cross-component background error covariance(BEC)between LST and atmospheric state variables.This study aims to clarify whether there is a relationship between the error of LST and atmospheric variables,and whether this relationship varies spatially and temporally.To this end,the BEC coupled with atmospheric variables and LST was constructed(LST-BEC),and its characteristics were analyzed based on the 2023 mei-yu season.The general characteristics of LST-BEC show that the LST is mainly correlated with the atmospheric temperature and the correlation decreases gradually with a rise in atmospheric height,and the error standard deviation of the LST is noticeably larger than that of the low-level atmospheric temperature.The spatiotemporal characteristics of LST-BEC on the heavy-rain day and light-rain day show that the error correlation and error standard deviation of LST and low-level atmospheric temperature and humidity are closely related to the weather background,and also have obvious diurnal variations.These results provide valuable information for strongly coupled land-atmosphere assimilation.
基金sponsored by the National Natural Science Foundation of China(Grant No.42075148)the High-Performance Computing Center of Nanjing University of Information Science & Technology for supporting this work。
文摘Accurate skin temperature is one of the critical factors in successfully assimilating satellite radiance data over land.However,model-simulated skin temperature may not be accurate enough.To address this issue,an extended skin temperature control variable(TSCV) approach is proposed in a variational assimilation framework,which also considers the background error correlation between skin temperature and atmospheric variables.A series of single observation tests and a 10-day cycling assimilation experiment were conducted to evaluate the impact of the TSCV approach on the assimilation of AMSU-A and ATMS(Advanced Technology Microwave Sounder) microwave temperature-sounding channels over land.The results of the single observation tests show that by applying the TSCV approach,not only the direct analysis of skin temperature is realized,but also the interaction between skin temperature and atmospheric variables can be achieved during the assimilation process.The results of the cycling experiment demonstrate that the TSCV approach improves the skin temperature analysis,which in turn reduces the RMSE of the surface variables and low-level air temperature forecasts.The TSCV approach also reduces the difference between the observed and simulated brightness temperatures of both microwave and infrared window channels over land,suggesting that the approach can facilitate the radiance simulation of these channels,thus contributing to the assimilation of window channels.
基金jointly sponsored by the 973 Program(Grant No.2013CB430102)the National Natural Science Foundation of China(Grant No.41675102)+1 种基金the Open Project Program of the Key Laboratory of Meteorological Disaster of the Ministry of Education,NUIST(KLME 1311)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Hydrometeor variables （cloud water and cloud ice mixing ratios） are added into the WRF three-dimensional variational assimilation system as additional control variables to directly analyze hydrometeors by assimilating cloud observations. In addition, the background error covariance matrix of hydrometeors is modeled through a control variable transform, and its characteristics discussed in detail. A suite of experiments using four microphysics schemes （LIN, SBU-YLIN, WDM6 and WSM6） are performed with and without assimilating satellite cloud liquid/ice water path. We find analysis of hydrometeors with cloud assimilation to be significantly improved, and the increment and distribution of hydrometeors are consistent with the characteristics of background error covariance. Diagnostic results suggest that the forecast with cloud assimilation represents a significant improvement, especially the ability to forecast precipitation in the first seven hours. It is also found that the largest improvement occurs in the experiment using the WDM6 scheme, since the assimilated cloud information can sustain for longer in this scheme. The least improvement, meanwhile, appears in the experiment using the SBU-YLIN scheme.
基金the National Key Research and Development Plan(Grant No.2018YFC1507105).
文摘The high observation efficiency,scanning speed and observation frequency of the Fengyun-4A(FY-4A)satellite indicates the progress of Chinese geostationary meteorological satellites.The characteristics of FY-4A atmospheric motion vectors(AMVs)derived from the high-level water vapor(WV-High)channel,mid-level water vapor(WV-Mid)channel,and infrared(IR)channel of FY-4A are analyzed,and their corresponding observation errors estimated.Then,the impacts of single-channel and multi-channel FY-4A AMVs on RMAPS-ST(the Rapid-refresh Multi-scale Analysis and Prediction System-Short Term)are evaluated based on one-month data assimilation cycling and forecasting experiments.Results show that the observation errors of FY-4A AMVs from the three channels have an explicit vertical structure.Results from the cycling experiments indicate that the assimilation of AMVs from WV-High produces more apparent improvement of the wind in the upper layer,while a more positive effect in the lower layer is achieved by the assimilation of AMVs from IR.Furthermore,the assimilation of AMVs from IR is more skillful for medium and moderate precipitation than from other channels owing to the good quality of data in the lower layer in the AMVs from IR.Assimilation of FY-4A AMVs from the three channels could combine the advantages of assimilation from each individual channel to improve the wind in the upper,middle and lower layers simultaneously.
基金jointly sponsored by the National Key Research and Development Program of China(Grant Nos.2018YFC1506701 and 2017YFC1502102)the National Natural Science Foundation of China(Grant No.41675102)。
文摘Precipitation detection is an essential step in radiance assimilation because the uncertainties in precipitation would affect the radiative transfer calculation and observation errors.The traditional precipitation detection method for microwave only detects clouds and precipitation horizontally,without considering the three-dimensional distribution of clouds.Extending precipitation detection from 2D to 3D is expected to bring more useful information to the data assimilation without using the all-sky approach.In this study,the 3D precipitation detection method is adopted to assimilate Microwave Temperature Sounder-2(MWTS-Ⅱ)onboard the Fengyun-3D,which can dynamically detect the channels above precipitating clouds by considering the near-real-time cloud parameters.Cycling data assimilation and forecasting experiments for Typhoons Lekima(2019)and Mitag(2019)are carried out.Compared with the control experiment,the quantity of assimilated data with the 3D precipitation detection increases by approximately 23%.The quality of the additional MWTS-Ⅱradiance data is close to the clear-sky data.The case studies show that the average root-mean-square errors(RMSE)of prognostic variables are reduced by 1.7%in the upper troposphere,leading to an average reduction of4.53%in typhoon track forecasts.The detailed diagnoses of Typhoon Lekima(2019)further show that the additional MWTS-Ⅱradiances brought by the 3D precipitation detection facilitate portraying a more reasonable circulation situation,thus providing more precise structures.This paper preliminarily proves that 3D precipitation detection has potential added value for increasing satellite data utilization and improving typhoon forecasts.
基金supported by the National Natural Science Foundation of China(91963206,21932004)the Ministry of Science and Technology of China(2017YFB0702800)the China Postdoctoral Science Foundation(2021M691512)。
文摘A unique nest-type catalyst has been designed with a nest of oxygen capture surrounding catalytic Pt centers, which shows much promoted performance, on the base of Pt/C catalyst, for oxygen reduction reaction(ORR). The nest is constructed with nitrogen-doped carbon matrix(NCM), derived from the controlled carbonization of PANI precursor, to cover Pt/C catalyst. The unique structure of the catalyst(denoted as NCM■ Pt/C) has many merits. Firstly, it can capture oxygen both in air and in acidic electrolyte. Compared with naked Pt/C, it is found that, in air, the oxygen concentration within the porous nest of NCM surrounding Pt/C particles is ~13 times higher than atmospheric oxygen concentration and, in acidic electrolyte, the concentration of activated oxygen over the catalyst NCM■ Pt/C rise to~1.9 times. Secondly, the NCM nest offers a special electronic modulation on Pt centers toward modified ORR kinetics and then catalytic performances. With these merits, compared with Pt/C, the NCM■ Pt/C catalyst shows 3.2 times higher turnover frequency value and 2.9 times enhanced specific activity for ORR with half-wave potential at 0.894 V. After 50,000 sweeping cycles, the NCM■ Pt/C catalyst retains~66% mass activity and still has advantages over the fresh Pt/C catalyst. We envision that the nest-type catalyst provides a new idea for progress of practical Pt/C ORR catalyst.
基金National Key Research and Development Program of China(Grant No.2017YFC1502102)National Natural Science Foundation of China(Grant No.42075148)+1 种基金Graduate Research and Innovation Projects of Jiangsu Province(Grant No.KYCX20_0910)the High-Performance Computing Center of Nanjing University of Information Science and Technology(NUIST).
文摘Use of data assimilation to initialize hydrometeors plays a vital role in numerical weather prediction(NWP).To directly analyze hydrometeors in data assimilation systems from cloud-sensitive observations,hydrometeor control variables are necessary.Common data assimilation systems theoretically require that the probability density functions(PDFs)of analysis,background,and observation errors should satisfy the Gaussian unbiased assumptions.In this study,a Gaussian transform method is proposed to transform hydrometeors to more Gaussian variables,which is modified from the Softmax function and renamed as Quasi-Softmax transform.The Quasi-Softmax transform method then is compared to the original hydrometeor mixing ratios and their logarithmic transform and Softmax transform.The spatial distribution,the non-Gaussian nature of the background errors,and the characteristics of the background errors of hydrometeors in each method are studied.Compared to the logarithmic and Softmax transform,the Quasi-Softmax method keeps the vertical distribution of the original hydrometeor mixing ratios to the greatest extent.The results of the D′Agostino test show that the hydrometeors transformed by the Quasi-Softmax method are more Gaussian when compared to the other methods.The Gaussian transform has been added to the control variable transform to estimate the background error covariances.Results show that the characteristics of the hydrometeor background errors are reasonable for the Quasi-Softmax method.The transformed hydrometeors using the Quasi-Softmax transform meet the Gaussian unbiased assumptions of the data assimilation system,and are promising control variables for data assimilation systems.
