This study aims to investigate the primary carbides precipitation in H13 steel solidified at relatively high cooling rates,ranging from 300 to 6,000℃·min^-1,based on in situ observations with a high temperature ...This study aims to investigate the primary carbides precipitation in H13 steel solidified at relatively high cooling rates,ranging from 300 to 6,000℃·min^-1,based on in situ observations with a high temperature confocal laser scanning microscope.In the cooling rate range investigated,the solidification microstructure becomes more refined as cooling rate increases and the relationship between the secondary dendrite arm spacing(SDAS),λ2,and cooling rate,.T,can be expressed asλ2=128.45.T-0.124.Regardless of cooling rates,two kinds of primary carbides,i.e.,the Mo-Cr-rich and V-rich carbides,are precipitated along the interdendritic region and most of them are the Mo-Cr-rich carbides.The morphology of Mo-Cr-rich carbide is not obviously influenced by the cooling rate,but that of V-rich carbide is obviously affected.The increasing cooling rate markedly refines the primary carbides and reduces their volume fractions,but their precipitations cannot be inhibited even when the cooling rate is increased to 6,000℃·min^-1.Besides,the segregation ratios(SRs)of the carbides forming elements are not obviously affected by the cooling rate.However,compared with the conventionally cast ingot,the SDAS and primary carbides in the steel solidified at the investigated cooling rates are much finer,morphologies of the carbides have changed significantly,and SRs of the carbides forming elements are markedly greater.The variation of primary carbide characteristics with cooling rate is mainly due to the change in SDAS.展开更多
The determination of the local cooling rate has a great significance in optimizing the parameters of electroslag remelting(ESR)and improving the quality of the ingots.An innovative method was proposed for calibrating ...The determination of the local cooling rate has a great significance in optimizing the parameters of electroslag remelting(ESR)and improving the quality of the ingots.An innovative method was proposed for calibrating the local cooling rate of M42 high-speed steel(HSS)in the ESR process.After resolidification at different cooling rates under high-temperature laser confocal microscopy,the carbide network spacing of the specimen was observed using a scanning electron microscope.A functional relationship between the cooling rate and average carbide network spacing was established.The average local cooling rate of the solidification process of the M42 HSS ingot was calibrated.The results show that the higher the cool-ing rate,the smaller the network spacing of the carbides.For the steel ingot with a diameter of 360 mm,the average local cooling rate was 0.562℃/s at the surface,0.057℃/s at the position of 0.25D(where D is the diameter of the ingot),and 0.046℃/s at the center of the ingot.展开更多
Steel teeming time is a very important parameter in the new slide gate system with electromagnetic induction （called electromagnetic steel teeming system）, and how to shorten this time is a key to realize applicatio...Steel teeming time is a very important parameter in the new slide gate system with electromagnetic induction （called electromagnetic steel teeming system）, and how to shorten this time is a key to realize application of the new system in continuous casting. The effects of power parameters, coil position, nozzle material and other factors on the steel teeming time were investigated by a self-designed electromagnetic steel teeming system in detail. The experimental results show that the relationship between power and steel teeming time is nonlinear. The coil position has great in- fluence on steel teeming time. And the upper nozzle with high permeability can reduce the teeming time. In addition, the steel teeming time becomes minimum when the size of the spherical cast iron particles is 2.0 ram. This research can provide technical references for the industrial application of the new electromagnetic steel teeming system.展开更多
Efficient extraction of electrode components from recycled lithium-ion batteries(LIBs)and their highvalue applications are critical for the sustainable and ecofriendly utilization of resources.This work demonstrates a...Efficient extraction of electrode components from recycled lithium-ion batteries(LIBs)and their highvalue applications are critical for the sustainable and ecofriendly utilization of resources.This work demonstrates a novel approach to stripping graphite anodes embedded with Li^(+)from spent LIBs directly in anhydrous ethanol which can be utilized as high efficiency cathodes for aluminum-ion batteries(AIBs).Recycled graphite(RG)with foam morphology and crystal structure defects was obtained under the action of ultrasonic peeling and gas generation reaction between residual lithium-graphite interlayer compound and ethanol.The inherent open structure of RG facilitates the intercalation/deintercalation of chloralum anions(AlCl_(4)^(-))and enhances its AIB cathode performance.The electrochemical measurements revea that the RG cathode has a specific capacity of 123 m Ah·g^(-1)at a current of 5 A·g^(-1),which is 1.55 times higher than tha of unprocessed natural graphite and 1.25 times higher than that of commercial artificial graphite.Additionally,the RG cathode demonstrated remarkable stability,retaining its high particular capacity of 138.15 mAh·g^(-1)even through2000 times at 10 A·g^(-1)in a low-cost electrolyte consisting of an ionic liquid/urea/AlCl_(3)mixture.This work offers a novel approach to reusing of graphite anode waste materials from LIBs.展开更多
The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;h...The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;however,it is difficult to be studied in situ.Here,a new method of measuring the oxygen transfer rate at the gas-slag and slag-metal interfaces was reported based on electrochemical analyses.The interfacial oxygen transfer rate in the smelting process of Inconel 718 superalloy was investigated at 1723,1773,1823,and 1873 K.The experimental results show that the electrochemical method can measure the real-time oxygen content;hence,this method is promising in controlling the oxygen content in alloys.As the temperature increased,both the equilibrium oxygen content and the rate of oxygen absorption increased significantly,and the increase was the most obvious when the temperature was 1873 K.The possible reason is that the increase in temperature weakens the mass transfer resistance of the electric double layer at the interface,thus accelerating the oxygen transfer rate.展开更多
Zn_(2)SnO_(4)plates,particles and spheres are suc-cessfully prepared via a facile synthesis way by carefully adjusting the solvothermal conditions,which are further applied as photoanodes in dye-sensitized solar cells...Zn_(2)SnO_(4)plates,particles and spheres are suc-cessfully prepared via a facile synthesis way by carefully adjusting the solvothermal conditions,which are further applied as photoanodes in dye-sensitized solar cells(DSSCs)to explore the relationships between the pho-toanode nanostructure and the photovoltaic performances.As a result,the DSSCs based on Zn_(2)SnO_(4)spheres pho-toanode showcased the best power conversion efficiency(PCE,4.85%),compared to Zn_(2)SnO_(4)plates(3.80%)and particles(4.13%).It is found that Zn_(2)SnO_(4)spheres exhibit the highest light-scattering abilities,as evidenced by ultraviolet–visible(UV–Vis)diffuse reflectance spectra.Additionally,investigations on dynamic electron transport and recombination properties via intensity-modulated photovoltage/photocurrent spectroscopy(IMVS/IMPS),and electrochemical impedance spectroscopy(EIS)mea-surements demonstrate that the Zn_(2)SnO_(4)spheres-based DSSCs possess the fastest electron transport rate,the longest electron lifetime,the highest electron collection efficiency(ηc c),and the largest charge recombination resistance,compared with the Zn_(2)SnO_(4)plates and particles,all of which are highly beneficial for the powder conversion efficiency enhancements.展开更多
By using a simplified Coulomb explosion model, the laser-driven Coulomb explosion processes of three deuterated alkane clusters, i.e., deuterated methane（CD4）N, ethane（C2D6）N and propane（C3D8）N clusters are simu...By using a simplified Coulomb explosion model, the laser-driven Coulomb explosion processes of three deuterated alkane clusters, i.e., deuterated methane（CD4）N, ethane（C2D6）N and propane（C3D8）N clusters are simulated numerically.The overrun phenomenon that the deuterons overtake the carbon ions inside the expanding clusters, as well as the dependence of the energetic deuterons and fusion neutron yield on cluster size, is discussed in detail. Researches show that the average kinetic energy of deuterons and neutron yield generated in the Coulomb explosion of（C2D6）N cluster are higher than those of（CD4）N cluster with the same size, in qualitative agreement with the reported conclusions from the experiments of（C2 H6）N and（CH4）N clusters. It is indicated that（C2D6）N clusters are superior to（CD4）N clusters as a target for the laser-induced nuclear fusion reaction to achieve a higher neutron yield. In addition, by comparing the relevant data of（C3D8）N cluster with those of（C2D6）N cluster with the same size, it is theoretically concluded that（C3D8）N clusters with a larger competitive parameter might be a potential candidate for improving neutron generation. This will provide a theoretical basis for target selection in developing experimental schemes on laser-driven nuclear fusion in the future.展开更多
Different C_(60) crystals were synthesized by precipitation from a mixture of the good solvent m-xylene and the poor solvent isopropyl alcohol.The samples were characterized by scanning electron microscopy(SEM),Raman ...Different C_(60) crystals were synthesized by precipitation from a mixture of the good solvent m-xylene and the poor solvent isopropyl alcohol.The samples were characterized by scanning electron microscopy(SEM),Raman spectroscopy,thermogravimetric analysis,and high resolution transmission electron microscope(HRTEM).We found that the morphologies and sizes of the samples could be controlled by adjusting the volume ratio between the good and poor solvents.Especially,an unexpected short flower column-like crystal was synthesized at low ratios(from 1:6 to 1:12).Room temperature photoluminescence(PL)and HRTEM studies of the C_(60) crystal samples reveal that the PL efficiency of the crystals decreases with increasing crystalline order and that the disordered C_(60) crystals synthesized at the ratio of 1:2 show 10 times higher PL efficiency than that of pristine C_(60).The mechanism of the growth process of these C_(60) crystals was also studied by replacing the good solvents m-xylene with toluene and mesitylene.展开更多
We develop a new kind of underwater inductive coupling power transfer(ICPT)system to evaluate wireless power transfer in autonomous underwater vehicle(AUV)docking applications.Parameters that determine the performance...We develop a new kind of underwater inductive coupling power transfer(ICPT)system to evaluate wireless power transfer in autonomous underwater vehicle(AUV)docking applications.Parameters that determine the performance of the system are systematically analyzed through mathematical methods.A circuit simulation model and a finite element analysis(FEA)simulation model are developed to study the power losses of the system,including copper loss in coils,semiconductor loss in circuits,and eddy current loss in transmission media.The characteristics of the power losses can provide guidelines to improve the efficiency of ICPT systems.Calculation results and simulation results are validated by relevant experiments of the prototype system.The output power of the prototype system is up to 45 W and the efficiency is up to 0.84.The preliminary results indicate that the efficiency will increase as the transmission power is raised by increasing the input voltage.When the output power reaches 500 W,the efficiency is expected to exceed 0.94.The efficiency can be further improved by choosing proper semiconductors and coils.The analysis methods prove effective in predicting the performance of similar ICPT systems and should be useful in designing new systems.展开更多
In underwater applications of contactless power transmission(CLPT)systems,high pressure and noncoaxial operations will change the parameters of electromagnetic(EM)couplers.As a result,the system will divert from its o...In underwater applications of contactless power transmission(CLPT)systems,high pressure and noncoaxial operations will change the parameters of electromagnetic(EM)couplers.As a result,the system will divert from its optimum performance.Using a reluctance modeling method,we investigated the gap effects on the EM coupler in deep-sea environment.Calculations and measurements were performed to analyze the influence of high pressure and noncoaxial alignments on the coupler.It was shown that it is useful to set a relatively large gap between cores to reduce the influence of pressure.Experiments were carried out to verify the transferring capacity of the designed coupler and system for a fixed frequency.The results showed that an EM coupler with a large gap can serve a stable and efficient power transmission for the CLPT system.The designed system can transfer more than 400 W electrical power with a 2-mm gap in the EM coupler,and the efficiency was up to 90%coaxially and 87%non-coaxially in 40 MPa salt water.Finally,a mechanical layout of a 400 W EM coupler for the underwater application in 4000-m deep sea was proposed.展开更多
In underwater applications of contactless power transmission(CLPT)systems,high pressure and noncoaxial operations will change the parameters of electromagnetic(EM)couplers.As a result,the system will divert from its o...In underwater applications of contactless power transmission(CLPT)systems,high pressure and noncoaxial operations will change the parameters of electromagnetic(EM)couplers.As a result,the system will divert from its optimum performance.Using a reluctance modeling method,we investigated the gap effects on the EM coupler in deep-sea environment.Calculations and measurements were performed to analyze the influence of high pressure and noncoaxial alignments on the coupler.It was shown that it is useful to set a relatively large gap between cores to reduce the influence of pressure.Experiments were carried out to verify the transferring capacity of the designed coupler and system for a fixed frequency.The results showed that an EM coupler with a large gap can serve a stable and efficient power transmission for the CLPT system.The designed system can transfer more than 400 W electrical power with a 2-mm gap in the EM coupler,and the efficiency was up to 90%coaxially and 87%non-coaxially in 40 MPa salt water.Finally,a mechanical layout of a 400 W EM coupler for the underwater application in 4000-m deep sea was proposed.展开更多
A power monitoring and protection system based on an embedded processor was designed for the junction boxes(JBs) of an experimental seafloor observatory network in China. The system exhibits high reliability, fast res...A power monitoring and protection system based on an embedded processor was designed for the junction boxes(JBs) of an experimental seafloor observatory network in China. The system exhibits high reliability, fast response, and high real-time performance. A two-step power management method which uses metal-oxide-semiconductor field-effect transistors(MOSFETs) and a mechanical contactor in series was adopted to generate a reliable power switch, to limit surge currents and to facilitate automatic protection. Grounding fault diagnosis and environmental monitoring were conducted by designing a grounding fault detection circuit and by using selected sensors, respectively. The data collected from the JBs must be time-stamped for analysis and for correlation with other events and data. A highly precise system time, which is necessary for synchronizing the times within and across nodes, was generated through the IEEE 1588(precision clock synchronization protocol for networked measurement and control systems) time synchronization method. In this method, time packets were exchanged between the grandmaster clock at the shore station and the slave clock module of the system. All the sections were verified individually in the laboratory prior to a sea trial. Finally, a subsystem for power monitoring and protection was integrated into the complete node system, installed in a frame, and deployed in the South China Sea. Results of the laboratory and sea trial experiments demonstrated that the developed system was effective, stable, reliable, and suitable for continuous deep-sea operation.展开更多
Due to the shortage of suitable research methods for real-time and long-term observation of oceans,an innovative approach that can provide abundant power and wide bandwidth is being developed worldwide for undersea in...Due to the shortage of suitable research methods for real-time and long-term observation of oceans,an innovative approach that can provide abundant power and wide bandwidth is being developed worldwide for undersea instruments.In this paper,we develop a direct current(DC) power system which is applied to a multi-node cabled ocean observatory system named ZERO(Zhejiang University Experimental and Research Observatory).The system addresses significant issues ranging from terrestrial facility to subsea infrastructure,and focuses on using appropriate methods to deal with several key challenges,including delivery,conversion,distribution,and management of power,and heat dissipation in pressure vessels.A basic laboratory platform consisting of a shore station,a primary node in a water tank,and a secondary node in a deep-sea simulation chamber under 42 MPa pressure was built and fully tested.An improved secondary node was deployed in Monterey Bay in California for a deep-sea trial.An 11-day laboratory test and a half-year sea trial proved that the DC power system based on our proposed methods is viable for the underwater multi-node observatory system.展开更多
The effect of a constant current(CC)power supply on the CC ocean observation system is a problem that once was neglected.The dynamic characteristics of the CC power supply may have great influence on the whole system,...The effect of a constant current(CC)power supply on the CC ocean observation system is a problem that once was neglected.The dynamic characteristics of the CC power supply may have great influence on the whole system,especially the voltage behavior in the event of load change.This needs to be examined.In this paper,a method is introduced to check whether the CC power supply can satisfy the dynamic requirements of the CC ocean observation system.An equivalent model to describe the non-ideal CC power supply is presented,through which the dynamic characteristics can be standardized.To verify the feasibility of this model,a minimum system of a single node in the CC ocean observation system is constructed,from which the model is derived.Focusing on the power failure problem,the output voltage responses are performed and the models are validated.Through the model,the dynamic behavior of the CC power supply is checked in a practical design.展开更多
An IEEE 1588 based application scheme was proposed to achieve accurate time synchronization for a deep seafloor observatory network based on the communication topological structure of the Zhejiang University Experimen...An IEEE 1588 based application scheme was proposed to achieve accurate time synchronization for a deep seafloor observatory network based on the communication topological structure of the Zhejiang University Experimental and Research Observatory.The principles of the network time protocol(NTP)and precision time protocol(PTP)were analyzed.The framework for time synchronization of the shore station,undersea junction box layer,and submarine science instrument layer was designed.NTP and PTP network signals were decoded by a PTP master clock on a shore station that receives signals from the Global Positioning System and the BeiDou Navigation Satellite System as reference time sources.These signals were remotely transmitted by a subsea optical–electrical composite cable through an Ethernet passive optical network.Accurate time was determined by time synchronization devices in each layer.Synchronization monitoring experiments performed within a laboratory environment indicated that the proposed system is valid and has the potential to realize microsecond accuracy to satisfy the time synchronization requirements of a high-precision seafloor observatory network.展开更多
Cabled seafloor observatories play an important role in ocean exploration for its long-term, real-time, and in-situ observation characteristics. In establishing a permanent, reliable, and robust seafloor observatory, ...Cabled seafloor observatories play an important role in ocean exploration for its long-term, real-time, and in-situ observation characteristics. In establishing a permanent, reliable, and robust seafloor observatory, a highly reliable cable switching and fault isolation method is essential. After reviewing the advantages and disadvantages of existing switching methods, we propose a novel active switching method for network configuration. Without additional communication path requirements, the switching method provides a way to communicate with a shore station through an existing power transmission path. A coded voltage signal with a distinct sequence is employed as the communication medium to transmit commands. The analysis of the maximum bit frequency of the voltage signals guarantees the accuracy of command recognition. A prototype based on the switching method is built and tested in a laboratory environment, which validated the functionality and reliability of the method.展开更多
Constant current power transmission is considered a good choice for subsea observatories due to its high resistance to shunt faults. A constant current subsea observatory is planned to be constructed in the East China...Constant current power transmission is considered a good choice for subsea observatories due to its high resistance to shunt faults. A constant current subsea observatory is planned to be constructed in the East China Sea. We discuss a constant current subsea observatory system used for scientific experiments. The power system and its heat dissipation system are carefully designed. The power conversion method is challenging due to the use of constant current power, which is considerably different from traditional power systems. Thus, we adopt power compensation circuits in the conversion system to obtain a constant 48-V output for science users. A power management system that performs overvoltage protection and real-time monitoring and control of junction box is discussed. An innovative heat dissipation structure of a junction box is designed in consideration of a sealed working environment to extend the useful life of the junction box. Simulations and experiments reveal that the system has high efficiency and stability, especially in long-term applications.展开更多
基金the National Natural Science Foundation of China(Grant No.51904146)the Doctor Start-up Fund of Liaoning Province(Grant No.2019-BS-125)the National Key Laboratory of Marine Engineering of China(Grant No.SKLMEA-USTL-201707)。
文摘This study aims to investigate the primary carbides precipitation in H13 steel solidified at relatively high cooling rates,ranging from 300 to 6,000℃·min^-1,based on in situ observations with a high temperature confocal laser scanning microscope.In the cooling rate range investigated,the solidification microstructure becomes more refined as cooling rate increases and the relationship between the secondary dendrite arm spacing(SDAS),λ2,and cooling rate,.T,can be expressed asλ2=128.45.T-0.124.Regardless of cooling rates,two kinds of primary carbides,i.e.,the Mo-Cr-rich and V-rich carbides,are precipitated along the interdendritic region and most of them are the Mo-Cr-rich carbides.The morphology of Mo-Cr-rich carbide is not obviously influenced by the cooling rate,but that of V-rich carbide is obviously affected.The increasing cooling rate markedly refines the primary carbides and reduces their volume fractions,but their precipitations cannot be inhibited even when the cooling rate is increased to 6,000℃·min^-1.Besides,the segregation ratios(SRs)of the carbides forming elements are not obviously affected by the cooling rate.However,compared with the conventionally cast ingot,the SDAS and primary carbides in the steel solidified at the investigated cooling rates are much finer,morphologies of the carbides have changed significantly,and SRs of the carbides forming elements are markedly greater.The variation of primary carbide characteristics with cooling rate is mainly due to the change in SDAS.
基金the National Natural Science Foundation of China(Nos.51974153,U1960203,and 51974156)the Joint Fund of State Key Laboratory of Marine Engineering and University of Science and Technology Liaoning(SKLMEA-USTL-201901,SKLMEA-USTL-201707)China Scholarship Council(201908210457).
文摘The determination of the local cooling rate has a great significance in optimizing the parameters of electroslag remelting(ESR)and improving the quality of the ingots.An innovative method was proposed for calibrating the local cooling rate of M42 high-speed steel(HSS)in the ESR process.After resolidification at different cooling rates under high-temperature laser confocal microscopy,the carbide network spacing of the specimen was observed using a scanning electron microscope.A functional relationship between the cooling rate and average carbide network spacing was established.The average local cooling rate of the solidification process of the M42 HSS ingot was calibrated.The results show that the higher the cool-ing rate,the smaller the network spacing of the carbides.For the steel ingot with a diameter of 360 mm,the average local cooling rate was 0.562℃/s at the surface,0.057℃/s at the position of 0.25D(where D is the diameter of the ingot),and 0.046℃/s at the center of the ingot.
基金Sponsored by Science and Techonlogy Program of Liaoning Province of China(2008221015)
文摘Steel teeming time is a very important parameter in the new slide gate system with electromagnetic induction （called electromagnetic steel teeming system）, and how to shorten this time is a key to realize application of the new system in continuous casting. The effects of power parameters, coil position, nozzle material and other factors on the steel teeming time were investigated by a self-designed electromagnetic steel teeming system in detail. The experimental results show that the relationship between power and steel teeming time is nonlinear. The coil position has great in- fluence on steel teeming time. And the upper nozzle with high permeability can reduce the teeming time. In addition, the steel teeming time becomes minimum when the size of the spherical cast iron particles is 2.0 ram. This research can provide technical references for the industrial application of the new electromagnetic steel teeming system.
基金financially supported by the National Natural Science Foundation of China(No.52202338)。
文摘Efficient extraction of electrode components from recycled lithium-ion batteries(LIBs)and their highvalue applications are critical for the sustainable and ecofriendly utilization of resources.This work demonstrates a novel approach to stripping graphite anodes embedded with Li^(+)from spent LIBs directly in anhydrous ethanol which can be utilized as high efficiency cathodes for aluminum-ion batteries(AIBs).Recycled graphite(RG)with foam morphology and crystal structure defects was obtained under the action of ultrasonic peeling and gas generation reaction between residual lithium-graphite interlayer compound and ethanol.The inherent open structure of RG facilitates the intercalation/deintercalation of chloralum anions(AlCl_(4)^(-))and enhances its AIB cathode performance.The electrochemical measurements revea that the RG cathode has a specific capacity of 123 m Ah·g^(-1)at a current of 5 A·g^(-1),which is 1.55 times higher than tha of unprocessed natural graphite and 1.25 times higher than that of commercial artificial graphite.Additionally,the RG cathode demonstrated remarkable stability,retaining its high particular capacity of 138.15 mAh·g^(-1)even through2000 times at 10 A·g^(-1)in a low-cost electrolyte consisting of an ionic liquid/urea/AlCl_(3)mixture.This work offers a novel approach to reusing of graphite anode waste materials from LIBs.
基金gratefully express their appreciation to National Natural Science Foundation of China(Nos.51974153 and U1960203)the Joint Fund of State Key Laboratory of Marine Engineering and University of Science and Technology Liaoning(SKLMEA-USTL-201707)the China Scholarship Council(201908210457).
文摘The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;however,it is difficult to be studied in situ.Here,a new method of measuring the oxygen transfer rate at the gas-slag and slag-metal interfaces was reported based on electrochemical analyses.The interfacial oxygen transfer rate in the smelting process of Inconel 718 superalloy was investigated at 1723,1773,1823,and 1873 K.The experimental results show that the electrochemical method can measure the real-time oxygen content;hence,this method is promising in controlling the oxygen content in alloys.As the temperature increased,both the equilibrium oxygen content and the rate of oxygen absorption increased significantly,and the increase was the most obvious when the temperature was 1873 K.The possible reason is that the increase in temperature weakens the mass transfer resistance of the electric double layer at the interface,thus accelerating the oxygen transfer rate.
基金financially supported by the Application Development Foundation of Guangzhou Lu Chao Science and Technology Company (No. 53H19044)the National Natural Science Foundation of China (No. U20A20238)+1 种基金the Talents Project of Beijing Municipal Committee Organization Department (No. 2018000021223ZK21)the Key Research & Development and Transformation Projects in Qinghai Province (No. 2021-HZ-808)。
文摘Zn_(2)SnO_(4)plates,particles and spheres are suc-cessfully prepared via a facile synthesis way by carefully adjusting the solvothermal conditions,which are further applied as photoanodes in dye-sensitized solar cells(DSSCs)to explore the relationships between the pho-toanode nanostructure and the photovoltaic performances.As a result,the DSSCs based on Zn_(2)SnO_(4)spheres pho-toanode showcased the best power conversion efficiency(PCE,4.85%),compared to Zn_(2)SnO_(4)plates(3.80%)and particles(4.13%).It is found that Zn_(2)SnO_(4)spheres exhibit the highest light-scattering abilities,as evidenced by ultraviolet–visible(UV–Vis)diffuse reflectance spectra.Additionally,investigations on dynamic electron transport and recombination properties via intensity-modulated photovoltage/photocurrent spectroscopy(IMVS/IMPS),and electrochemical impedance spectroscopy(EIS)mea-surements demonstrate that the Zn_(2)SnO_(4)spheres-based DSSCs possess the fastest electron transport rate,the longest electron lifetime,the highest electron collection efficiency(ηc c),and the largest charge recombination resistance,compared with the Zn_(2)SnO_(4)plates and particles,all of which are highly beneficial for the powder conversion efficiency enhancements.
基金supported by the National Natural Science Foundation of China(Grant No.11005080)
文摘By using a simplified Coulomb explosion model, the laser-driven Coulomb explosion processes of three deuterated alkane clusters, i.e., deuterated methane（CD4）N, ethane（C2D6）N and propane（C3D8）N clusters are simulated numerically.The overrun phenomenon that the deuterons overtake the carbon ions inside the expanding clusters, as well as the dependence of the energetic deuterons and fusion neutron yield on cluster size, is discussed in detail. Researches show that the average kinetic energy of deuterons and neutron yield generated in the Coulomb explosion of（C2D6）N cluster are higher than those of（CD4）N cluster with the same size, in qualitative agreement with the reported conclusions from the experiments of（C2 H6）N and（CH4）N clusters. It is indicated that（C2D6）N clusters are superior to（CD4）N clusters as a target for the laser-induced nuclear fusion reaction to achieve a higher neutron yield. In addition, by comparing the relevant data of（C3D8）N cluster with those of（C2D6）N cluster with the same size, it is theoretically concluded that（C3D8）N clusters with a larger competitive parameter might be a potential candidate for improving neutron generation. This will provide a theoretical basis for target selection in developing experimental schemes on laser-driven nuclear fusion in the future.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11504269 and 11504267)Tianjin Natural Science Foundation(Grant No.20JCQNJC00660)the Program for Innovative Research in University of Tianjin(Grant No.TD13-5077).
文摘Different C_(60) crystals were synthesized by precipitation from a mixture of the good solvent m-xylene and the poor solvent isopropyl alcohol.The samples were characterized by scanning electron microscopy(SEM),Raman spectroscopy,thermogravimetric analysis,and high resolution transmission electron microscope(HRTEM).We found that the morphologies and sizes of the samples could be controlled by adjusting the volume ratio between the good and poor solvents.Especially,an unexpected short flower column-like crystal was synthesized at low ratios(from 1:6 to 1:12).Room temperature photoluminescence(PL)and HRTEM studies of the C_(60) crystal samples reveal that the PL efficiency of the crystals decreases with increasing crystalline order and that the disordered C_(60) crystals synthesized at the ratio of 1:2 show 10 times higher PL efficiency than that of pristine C_(60).The mechanism of the growth process of these C_(60) crystals was also studied by replacing the good solvents m-xylene with toluene and mesitylene.
基金Project supported by the National High-Tech R&D Program of China(No.2013AA09A414)the National Natural Science Foundation of China(No.51221004)the Interdisciplinary Research Foundation of Zhejiang University(No.2012HY003A)
文摘We develop a new kind of underwater inductive coupling power transfer(ICPT)system to evaluate wireless power transfer in autonomous underwater vehicle(AUV)docking applications.Parameters that determine the performance of the system are systematically analyzed through mathematical methods.A circuit simulation model and a finite element analysis(FEA)simulation model are developed to study the power losses of the system,including copper loss in coils,semiconductor loss in circuits,and eddy current loss in transmission media.The characteristics of the power losses can provide guidelines to improve the efficiency of ICPT systems.Calculation results and simulation results are validated by relevant experiments of the prototype system.The output power of the prototype system is up to 45 W and the efficiency is up to 0.84.The preliminary results indicate that the efficiency will increase as the transmission power is raised by increasing the input voltage.When the output power reaches 500 W,the efficiency is expected to exceed 0.94.The efficiency can be further improved by choosing proper semiconductors and coils.The analysis methods prove effective in predicting the performance of similar ICPT systems and should be useful in designing new systems.
基金supported by the National High-Tech R&D Program(863)of China(No 2007AA091201)the Natural Science Foundation of Zhejiang Province,China(No Y5090117)the Qianjiang Excellence Project of Zhejiang Province,China(No 2009R10036)
文摘In underwater applications of contactless power transmission(CLPT)systems,high pressure and noncoaxial operations will change the parameters of electromagnetic(EM)couplers.As a result,the system will divert from its optimum performance.Using a reluctance modeling method,we investigated the gap effects on the EM coupler in deep-sea environment.Calculations and measurements were performed to analyze the influence of high pressure and noncoaxial alignments on the coupler.It was shown that it is useful to set a relatively large gap between cores to reduce the influence of pressure.Experiments were carried out to verify the transferring capacity of the designed coupler and system for a fixed frequency.The results showed that an EM coupler with a large gap can serve a stable and efficient power transmission for the CLPT system.The designed system can transfer more than 400 W electrical power with a 2-mm gap in the EM coupler,and the efficiency was up to 90%coaxially and 87%non-coaxially in 40 MPa salt water.Finally,a mechanical layout of a 400 W EM coupler for the underwater application in 4000-m deep sea was proposed.
文摘In underwater applications of contactless power transmission(CLPT)systems,high pressure and noncoaxial operations will change the parameters of electromagnetic(EM)couplers.As a result,the system will divert from its optimum performance.Using a reluctance modeling method,we investigated the gap effects on the EM coupler in deep-sea environment.Calculations and measurements were performed to analyze the influence of high pressure and noncoaxial alignments on the coupler.It was shown that it is useful to set a relatively large gap between cores to reduce the influence of pressure.Experiments were carried out to verify the transferring capacity of the designed coupler and system for a fixed frequency.The results showed that an EM coupler with a large gap can serve a stable and efficient power transmission for the CLPT system.The designed system can transfer more than 400 W electrical power with a 2-mm gap in the EM coupler,and the efficiency was up to 90%coaxially and 87%non-coaxially in 40 MPa salt water.Finally,a mechanical layout of a 400 W EM coupler for the underwater application in 4000-m deep sea was proposed.
基金Project supported by the National High-Tech R&D Program(863 Program)of China(Nos.2012AA09A408 and 2012AA09A402)the National Natural Science Foundation of China(No.51409229)the Zhejiang Provincial Natural Science Foundation of China(No.LQ14E070002)
文摘A power monitoring and protection system based on an embedded processor was designed for the junction boxes(JBs) of an experimental seafloor observatory network in China. The system exhibits high reliability, fast response, and high real-time performance. A two-step power management method which uses metal-oxide-semiconductor field-effect transistors(MOSFETs) and a mechanical contactor in series was adopted to generate a reliable power switch, to limit surge currents and to facilitate automatic protection. Grounding fault diagnosis and environmental monitoring were conducted by designing a grounding fault detection circuit and by using selected sensors, respectively. The data collected from the JBs must be time-stamped for analysis and for correlation with other events and data. A highly precise system time, which is necessary for synchronizing the times within and across nodes, was generated through the IEEE 1588(precision clock synchronization protocol for networked measurement and control systems) time synchronization method. In this method, time packets were exchanged between the grandmaster clock at the shore station and the slave clock module of the system. All the sections were verified individually in the laboratory prior to a sea trial. Finally, a subsystem for power monitoring and protection was integrated into the complete node system, installed in a frame, and deployed in the South China Sea. Results of the laboratory and sea trial experiments demonstrated that the developed system was effective, stable, reliable, and suitable for continuous deep-sea operation.
基金Project (No. 2007AA091201-1) supported by the National High-Tech R&D (863) Program of China
文摘Due to the shortage of suitable research methods for real-time and long-term observation of oceans,an innovative approach that can provide abundant power and wide bandwidth is being developed worldwide for undersea instruments.In this paper,we develop a direct current(DC) power system which is applied to a multi-node cabled ocean observatory system named ZERO(Zhejiang University Experimental and Research Observatory).The system addresses significant issues ranging from terrestrial facility to subsea infrastructure,and focuses on using appropriate methods to deal with several key challenges,including delivery,conversion,distribution,and management of power,and heat dissipation in pressure vessels.A basic laboratory platform consisting of a shore station,a primary node in a water tank,and a secondary node in a deep-sea simulation chamber under 42 MPa pressure was built and fully tested.An improved secondary node was deployed in Monterey Bay in California for a deep-sea trial.An 11-day laboratory test and a half-year sea trial proved that the DC power system based on our proposed methods is viable for the underwater multi-node observatory system.
基金Project supported by the National Natural Science Foundation of China(No.41676089)the Natural Science Foundation of Zhejiang Province,China(No.LY18E090003)the Fundamental Research Funds for the Central Universities,China(No.2018QNA4005)。
文摘The effect of a constant current(CC)power supply on the CC ocean observation system is a problem that once was neglected.The dynamic characteristics of the CC power supply may have great influence on the whole system,especially the voltage behavior in the event of load change.This needs to be examined.In this paper,a method is introduced to check whether the CC power supply can satisfy the dynamic requirements of the CC ocean observation system.An equivalent model to describe the non-ideal CC power supply is presented,through which the dynamic characteristics can be standardized.To verify the feasibility of this model,a minimum system of a single node in the CC ocean observation system is constructed,from which the model is derived.Focusing on the power failure problem,the output voltage responses are performed and the models are validated.Through the model,the dynamic behavior of the CC power supply is checked in a practical design.
基金Project supported by the National High-Tech R&D(863)Program ofChina(No.2012AA09A408)the National Natural ScienceFoundation of China(No.51221004)
文摘An IEEE 1588 based application scheme was proposed to achieve accurate time synchronization for a deep seafloor observatory network based on the communication topological structure of the Zhejiang University Experimental and Research Observatory.The principles of the network time protocol(NTP)and precision time protocol(PTP)were analyzed.The framework for time synchronization of the shore station,undersea junction box layer,and submarine science instrument layer was designed.NTP and PTP network signals were decoded by a PTP master clock on a shore station that receives signals from the Global Positioning System and the BeiDou Navigation Satellite System as reference time sources.These signals were remotely transmitted by a subsea optical–electrical composite cable through an Ethernet passive optical network.Accurate time was determined by time synchronization devices in each layer.Synchronization monitoring experiments performed within a laboratory environment indicated that the proposed system is valid and has the potential to realize microsecond accuracy to satisfy the time synchronization requirements of a high-precision seafloor observatory network.
基金supported by the National Natural Science Foundation of China(Nos.51409229,41676089,and 51521064)the National High-Tech R&D Program(863)of China(No.2012AA09A410)the Zhejiang Provincial Natural Science Foundation of China(No.LQ14E070002)
文摘Cabled seafloor observatories play an important role in ocean exploration for its long-term, real-time, and in-situ observation characteristics. In establishing a permanent, reliable, and robust seafloor observatory, a highly reliable cable switching and fault isolation method is essential. After reviewing the advantages and disadvantages of existing switching methods, we propose a novel active switching method for network configuration. Without additional communication path requirements, the switching method provides a way to communicate with a shore station through an existing power transmission path. A coded voltage signal with a distinct sequence is employed as the communication medium to transmit commands. The analysis of the maximum bit frequency of the voltage signals guarantees the accuracy of command recognition. A prototype based on the switching method is built and tested in a laboratory environment, which validated the functionality and reliability of the method.
基金Project supported by the National Natural Science Foundation of China(No.41676089),the Natural Science Foundation of Zhejiang Province,China(No.LY18E090003)the Fundamental Research Funds for the Central Universities,China(No.2018QNA4005)。
文摘Constant current power transmission is considered a good choice for subsea observatories due to its high resistance to shunt faults. A constant current subsea observatory is planned to be constructed in the East China Sea. We discuss a constant current subsea observatory system used for scientific experiments. The power system and its heat dissipation system are carefully designed. The power conversion method is challenging due to the use of constant current power, which is considerably different from traditional power systems. Thus, we adopt power compensation circuits in the conversion system to obtain a constant 48-V output for science users. A power management system that performs overvoltage protection and real-time monitoring and control of junction box is discussed. An innovative heat dissipation structure of a junction box is designed in consideration of a sealed working environment to extend the useful life of the junction box. Simulations and experiments reveal that the system has high efficiency and stability, especially in long-term applications.
