Surface Organometallic Chemistry(SOMC)aims at selective preparation of unusual or highly reactive species on the surfaces of inorganic supports in order to reach a better understanding of classical heterogeneous catal...Surface Organometallic Chemistry(SOMC)aims at selective preparation of unusual or highly reactive species on the surfaces of inorganic supports in order to reach a better understanding of classical heterogeneous catalysts and discover new reactivities and catalytic transformations.SOMC relies on the application of both surface science techniques and molecular organometallic chemistry;in particular it requires rational design of the molecular precursors to ensure their selective reactivity with the supports.In this report we apply the SOMC protocols to prepare well-defined silica-supported Zr imido complexes.展开更多
基金financially supported by the Russian Science Foundation(Grant No.19-73-10163)Elemental analyses and solution NMR measurements were performed using the equipment of the Center for Molecular Composition Studies of INEOS RAS supported by the Ministry of Science and Higher Education of the Russian Federation(Contract No.075-03-2023-642)P.Z.thanks Prof.C.Copéret and his group at ETH Zürich where DFT studies,solid-state NMR measurements and certain other experiments were performed.
文摘Surface Organometallic Chemistry(SOMC)aims at selective preparation of unusual or highly reactive species on the surfaces of inorganic supports in order to reach a better understanding of classical heterogeneous catalysts and discover new reactivities and catalytic transformations.SOMC relies on the application of both surface science techniques and molecular organometallic chemistry;in particular it requires rational design of the molecular precursors to ensure their selective reactivity with the supports.In this report we apply the SOMC protocols to prepare well-defined silica-supported Zr imido complexes.
