The directionality of the[N–I–N]^(+)halogen bond makes iodine(I)ions impeccable tools in the design and construction of[N–I–N]^(+)halogen-bonded assemblies.The synthesis of dimeric iodine(I)cages with imidazole-de...The directionality of the[N–I–N]^(+)halogen bond makes iodine(I)ions impeccable tools in the design and construction of[N–I–N]^(+)halogen-bonded assemblies.The synthesis of dimeric iodine(I)cages with imidazole-derived N-donor tripodal ligands is described,as well as their corresponding silver(I)precursors.The addition of elemental iodine to the parent two-coordinate Ag(I)complexes produces iodine(I)complexes with three-center four-electron(3c–4e)[N–I–N]^(+)bonds.展开更多
基金Academy of Finland(K.R.grant no.317259)Finnish Cultural Foundation Central Fund(J.S.W.grant number 00201148)+1 种基金the Magnus Ehrnrooth Foundation(J.S.W.),European Union NOAH project(D.L.S,H2020-MSCA-ITN project ref.765297the Core Facility BioSupraMol(supported by the Deutsche Forschungsgemeinschaft,DFG)and the University of Jyväskylä,Finland for financial support.
文摘The directionality of the[N–I–N]^(+)halogen bond makes iodine(I)ions impeccable tools in the design and construction of[N–I–N]^(+)halogen-bonded assemblies.The synthesis of dimeric iodine(I)cages with imidazole-derived N-donor tripodal ligands is described,as well as their corresponding silver(I)precursors.The addition of elemental iodine to the parent two-coordinate Ag(I)complexes produces iodine(I)complexes with three-center four-electron(3c–4e)[N–I–N]^(+)bonds.
