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新中国天然气勘探开发70年来的重大进展 被引量:84
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作者 戴金星 秦胜飞 +4 位作者 胡国艺 倪云燕 甘利灯 黄士鹏 洪峰 《石油勘探与开发》 SCIE EI CAS CSCD 北大核心 2019年第6期1037-1046,共10页
新中国成立70年来天然气勘探开发取得重大进展,从贫气国跃升为世界第6产气大国。1949年中国年产气为1117×10^4 m^3、探明天然气储量为3.85×10^8 m^3,人均年用气量和储量分别为0.0206 m^3和0.7107 m^3。至2018年,人年均国产气1... 新中国成立70年来天然气勘探开发取得重大进展,从贫气国跃升为世界第6产气大国。1949年中国年产气为1117×10^4 m^3、探明天然气储量为3.85×10^8 m^3,人均年用气量和储量分别为0.0206 m^3和0.7107 m^3。至2018年,人年均国产气114.8576 m^3,人均国内储量12011.08 m^3,70年内人年均国产气量和国内储量分别增加5575倍和16900倍。勘探开发大气田是快速发展天然气工业的主要途径。中国目前已发现大气田共72个,主要分布在四川(25个)、鄂尔多斯(13个)和塔里木(10个)3个盆地,2018年这3个盆地大气田共产气1039.26×10^8 m^3,占中国总产气量65%,至2018年底72个大气田累计探明天然气储量124504×10^8 m^3,占全国天然气储量16.7×10^12 m^3的75%。天然气新理论推动中国天然气工业更好更快发展,1979年以来煤成气新理论助力中国大批以煤系为主要烃源岩的气田的发现,2018年煤成气大气田产量分别占中国产气量和大气田产气量的50.93%和75.47%。页岩气理论推动下,本世纪发现涪陵、长宁、威远和威荣页岩气田,2018年已探明页岩气地质储量10455.67×10^8 m^3,年产气108.8×10^8 m^3,昭示了中国页岩气有较好前景。 展开更多
关键词 中国 天然气 煤成气 页岩气 产量 储量 勘探开发进展
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四川超级气盆地 被引量:76
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作者 戴金星 倪云燕 +7 位作者 刘全有 吴小奇 龚德瑜 洪峰 张延玲 廖凤蓉 严增民 李宏伟 《石油勘探与开发》 SCIE EI CAS CSCD 北大核心 2021年第6期1081-1088,共8页
当沉积盆地累计产量超过50×10^(8)bbl油当量(6.82×10^(8)t油或7931.66×10^(8)m^(3)气)和剩余可采资源量超过50×10^(8)bbl油当量即称之为超级盆地。四川盆地至2019年底油气总产量为6569×10^(8)m^(3),气油比为80... 当沉积盆地累计产量超过50×10^(8)bbl油当量(6.82×10^(8)t油或7931.66×10^(8)m^(3)气)和剩余可采资源量超过50×10^(8)bbl油当量即称之为超级盆地。四川盆地至2019年底油气总产量为6569×10^(8)m^(3),气油比为80︰1,总剩余可采资源量达136404×10^(8)m^(3),属二级超级盆地;由于产出以气为主,故为超级气盆地。四川盆地之所以成为超级气盆地,因其具有4个优势:①气源岩优势,有9组主要气源岩,为全国各盆地之首;②资源量优势,总剩余天然气可采资源量为136404×10^(8)m^(3),全国各盆地中为第1;③大气田优势,有大气田27个,在全国各盆地位列首位;④总产量优势,至2019年底天然气累计总产量6487.8×10^(8)m^(3),是全国各盆地之冠。四川盆地在天然气勘探上有4个方向性的重大突破:①页岩气方向性的重大突破,在中国首先发现开发奥陶系五峰组—志留系龙马溪组页岩气;②致密砂岩气方向性的重大突破,中坝气田三叠系须家河组二段气藏是全国首个高采出度致密砂岩气藏;③碳酸盐岩超大气田方向性重大突破;④超深层气藏方向性重大突破。这些方向性重大突破引领和推动相关领域全国盆地取得重要进展。此外,按累计油气产量和剩余可采资源量、盆地大地构造属性和累计产量中油和气占比3类标准,对超级盆地进行了分类。 展开更多
关键词 四川盆地 超级盆地 油气产量 资源量 烃源岩 大气田 页岩气 致密砂岩气 超深层气藏
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四川盆地超深层天然气地球化学特征 被引量:62
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作者 戴金星 倪云燕 +3 位作者 秦胜飞 黄士鹏 彭威龙 韩文学 《石油勘探与开发》 SCIE EI CAS CSCD 北大核心 2018年第4期588-597,共10页
对四川盆地38口井超深层(埋深大于6 000 m)天然气组分及其地球化学特征进行分析,以判明超深层天然气成因。四川盆地超深层天然气组分具如下特征:甲烷占绝对优势,含量最高达99.56%,平均86.67%;乙烷含量低,平均为0.13%;几乎没有丙、丁烷,... 对四川盆地38口井超深层(埋深大于6 000 m)天然气组分及其地球化学特征进行分析,以判明超深层天然气成因。四川盆地超深层天然气组分具如下特征:甲烷占绝对优势,含量最高达99.56%,平均86.67%;乙烷含量低,平均为0.13%;几乎没有丙、丁烷,为干气,属过成熟度气。硫化氢含量最高为25.21%,平均为5.45%;烷烃气碳同位素组成为:δ^(13)C_1值从-33.6‰变化至-26.7‰,δ^(13)C_2值从-32.9‰变化至-22.1‰,绝大部分没有倒转而主要为正碳同位素组成系列。烷烃气氢同位素组成为:δD_1值从-156‰变化至-113‰,少量井δD_2值从-103‰变化至-89‰。二氧化碳碳同位素组成为:δ^(13)C_(CO_2)值从-17.2‰变化至1.9‰,绝大部分在0±3‰范围。根据δ^(13)C_1-δ^(13)C_2-δ^(13)C_3鉴别图版,盆地超深层烷烃气除个别井外绝大部分为煤成气。根据二氧化碳成因鉴别图和δ^(13)C_(CO_2)值,判定除个别井外,超深层二氧化碳绝大部分为碳酸盐岩变质成因。龙岗气田和元坝气田超深层硫化氢为非生物还原型(热化学硫酸盐还原成因),双探号井的超深层硫化氢可能为裂解型(硫酸盐热裂解成因)。 展开更多
关键词 四川盆地 超深层 煤成气 硫化氢 地球化学 龙岗气田 元坝气田
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致密砂岩气藏与页岩气藏展布模式 被引量:16
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作者 戴金星 董大忠 +7 位作者 倪云燕 龚德瑜 黄士鹏 洪峰 张延玲 刘全有 吴小奇 冯子齐 《石油勘探与开发》 EI CAS CSCD 北大核心 2024年第4期667-678,共12页
在阐述美国和中国致密砂岩气和页岩气资源潜力和年产量的基础上,系统梳理致密砂岩气藏与页岩气藏展布的研究沿革,分析页岩气藏、致密砂岩气藏展布特征及致密砂岩气成因类型。研究表明:(1)美国致密砂岩气在天然气总产量中占比由2008年的... 在阐述美国和中国致密砂岩气和页岩气资源潜力和年产量的基础上,系统梳理致密砂岩气藏与页岩气藏展布的研究沿革,分析页岩气藏、致密砂岩气藏展布特征及致密砂岩气成因类型。研究表明:(1)美国致密砂岩气在天然气总产量中占比由2008年的35%降至2023年的8%左右;美国页岩气2023年产量为8310×10^(8)m^(3),在天然气总产量中占比由2000—2008年的5%~17%升至2023年的70%以上。(2)中国致密砂岩气占天然气总产量比例由2010年的16%升至2023年的28%以上;2012年中国开始生产页岩气,2023年产量达250×10^(8)m^(3),约占天然气全国总产量的11%。(3)页岩气藏展布模式为连续型,根据页岩气藏是否有断层切割及断距与气层厚度的关系,连续型页岩气藏可分为连续式和断续式两种。(4)与以往大部分学者认为致密砂岩气藏展布模式为连续型的认识不同,致密砂岩气藏展布模式不是连续型;根据圈闭类型,致密砂岩气藏可分为岩性型、背斜型和向斜型3种。(5)中国3大克拉通盆地和埃及Obavied次盆的致密砂岩气为煤成气,美国阿巴拉契亚盆地和阿曼迦巴盐盆地的致密砂岩气为油型气。 展开更多
关键词 页岩气 致密砂岩气 气藏特征 连续型成藏 岩性型成藏 背斜型成藏 向斜型成藏 煤成气 油型气
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煤成气在产气大国中的重大作用 被引量:26
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作者 戴金星 倪云燕 +2 位作者 廖凤蓉 洪峰 姚立邈 《石油勘探与开发》 SCIE EI CAS CSCD 北大核心 2019年第3期417-432,共16页
煤成气核心理论是煤系为气源岩,煤系成烃以气为主以油为辅,故与其相关盆地发现以气田为主。发现与开发大气田,特别是可采储量大于1×10^(12) m^3超大型气田,是决定一个国家成为年产500×10~8 m^3以上产气大国的主要途径和关键... 煤成气核心理论是煤系为气源岩,煤系成烃以气为主以油为辅,故与其相关盆地发现以气田为主。发现与开发大气田,特别是可采储量大于1×10^(12) m^3超大型气田,是决定一个国家成为年产500×10~8 m^3以上产气大国的主要途径和关键。世界煤资源和煤成气储量丰富而分布广泛,在世界天然气储量、产量上煤成气占有重要地位。截至2017年底世界发现煤成超大型气田13个,总原始可采储量49.995 28×10^(12) m^3,为该年世界总剩余可采储量193.5×10^(12) m^3的25.8%;2017年世界有产气大国15个,共产气28 567×10~8 m^3,其中6个以产煤成气为主的国家共产气11 369×10~8m^3,占产气大国总产量的39.8%。煤成超大型气田乌连戈伊气田是目前世界上累产气最多的气田,2015年底累产气63 043.96×10~8 m^3,并是世界上年产气量最高的气田,1989年产气3 300×10~8 m^3,分别占当年俄罗斯和世界产量的41.4%和15.7%。此外,分别详细介绍俄罗斯、土库曼斯坦、荷兰、莫桑比克和中国等煤成超大型气田所在盆地气源岩特征等,以及对所在国成为世界产气大国的重大作用。 展开更多
关键词 煤成气 产气大国 中国 俄罗斯 超大型气田 气源岩
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中国大气田烷烃气碳同位素组成的若干特征 被引量:12
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作者 戴金星 倪云燕 +4 位作者 龚德瑜 黄士鹏 刘全有 洪峰 张延玲 《石油勘探与开发》 EI CAS CSCD 北大核心 2024年第2期223-233,共11页
勘探开发大气田是一个国家快速发展天然气工业的重要途径。1991年至2020年,中国新探明大气田68个,促进2020年产气1925×10^(8)m^(3),成为世界第4产气大国。基于中国70个大气田的1696个气样组分和烷烃气碳同位素组成数据,获得中国大... 勘探开发大气田是一个国家快速发展天然气工业的重要途径。1991年至2020年,中国新探明大气田68个,促进2020年产气1925×10^(8)m^(3),成为世界第4产气大国。基于中国70个大气田的1696个气样组分和烷烃气碳同位素组成数据,获得中国大气田烷烃气碳同位素组成特征:①δ^(13)C_(1)、δ^(13)C_(2)、δ^(13)C_(3)和δ^(13)C_(4)的最轻值和平均值,随分子中碳数逐增而变重,而δ^(13)C_(1)、δ^(13)C_(2)、δ^(13)C_(3)和δ^(13)C_(4)的最重值,随分子中碳数逐增而变轻。②中国大气田δ^(13)C_(1)值的分布区间为−71.2‰~−11.4‰,其中生物气δ^(13)C_(1)值的分布区间为−71.2‰~−56.4‰;油型气δ^(13)C_(1)值的分布区间为−54.4‰~−21.6‰;煤成气δ^(13)C_(1)值的分布区间为−49.3‰~−18.9‰;无机成因气δ^(13)C_(1)值的分布区间为−35.6‰~−11.4‰;根据这些数据编制了中国大气田的δ^(13)C_(1)值尺图。③中国天然气δ^(13)C_(1)值的分布区间为−107.1‰~−8.9‰,其中生物气δ^(13)C_(1)值为−107.1‰~−55.1‰;油型气δ^(13)C^(1)值为−54.4‰~−21.6‰;煤成气δ^(13)C_(1)值为−49.3‰~−13.3‰;无机成因气δ13C1值为−36.2‰~−8.9‰;根据上述数据编制了中国天然气的δ^(13)C_(1)值尺图。 展开更多
关键词 中国 大气田 生物气 油型气 煤成气 无机成因气 烷烃气 碳同位素组成 δ_(13)C^(1)值尺
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近10年中国天然气工业快速发展 被引量:6
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作者 戴金星 倪云燕 +3 位作者 董大忠 洪峰 张延玲 康楚娟 《天然气地球科学》 CAS CSCD 北大核心 2022年第12期1907-1910,共4页
近10年(2012—2021年)中国天然气工业快速发展,主要是:(1)近10年共产气15105.2×10^(8)m^(3),是前10年(2002—2011年)总产气量6468.38×10^(8)m^(3)的2.3倍;(2)天然气储量猛增,近10年新增探明天然气地质储量84499.58×10^(8... 近10年(2012—2021年)中国天然气工业快速发展,主要是:(1)近10年共产气15105.2×10^(8)m^(3),是前10年(2002—2011年)总产气量6468.38×10^(8)m^(3)的2.3倍;(2)天然气储量猛增,近10年新增探明天然气地质储量84499.58×10^(8)m^(3),是前10年总储量55696.57×10^(8)m^(3)的1.5倍;(3)页岩气勘探开发开花结硕果,近10年发现并探明7个页岩气田,新增探明页岩气地质储量2.74×10^(12)m^(3),累计生产页岩气920×10^(8)m^(3);(4)年产百亿方大气田前10年2个,近10年为3个;(5)长输气管道四通八达,近10年建成长输气管道60766.5 km,是1949—2011年间建成管道长度的2.6倍。 展开更多
关键词 中国 天然气 产量 储量 大气田 页岩气 长输气管道
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中国煤成气理论形成过程及对天然气工业发展的战略意义 被引量:16
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作者 戴金星 龚剑明 《中国石油勘探》 CAS 北大核心 2018年第4期1-10,共10页
20世纪70年代,国家的能源供给主要是煤炭和石油,作为重要能源的天然气仍被大多数人所忽视,当时盛行的"一元论"油型气理论认为产煤地区是不可能产生天然气的。1978年,中国学者首次提出煤成气概念,此后40年,中国煤成气理论经历... 20世纪70年代,国家的能源供给主要是煤炭和石油,作为重要能源的天然气仍被大多数人所忽视,当时盛行的"一元论"油型气理论认为产煤地区是不可能产生天然气的。1978年,中国学者首次提出煤成气概念,此后40年,中国煤成气理论经历了引进、吸收、创新、发展、形成体系、指导天然气工业生产快速发展的全过程,其理论内涵包括气源鉴别指标体系、煤成气成藏机制与分布规律、评价预测技术方法等,应用中国煤成气理论先后准确预测了5个亿级以上大气田,使中国的煤成气占天然气比重从不足10%提高到67%,推动了中国天然气产量和储量的快速增长,为中国天然气工业快速发展做出重大基础性贡献,具有重要战略意义。 展开更多
关键词 天然气 煤成气 煤成气理论 一元论 二元论 战略
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用显微镜和拉曼光谱研究四川盆地高科1井、五科1井、普光5井、普光3井高密度甲烷包裹体特征与天然气成因 被引量:2
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作者 刘德汉 肖贤明 +8 位作者 田辉 戴金星 彭平安 王云鹏 米敬奎 汪泽成 李剑 李腾飞 程鹏 《地球化学》 CAS CSCD 北大核心 2023年第6期673-684,共12页
用光学显微镜和显微激光拉曼等技术手段综合研究了四川盆地4个钻孔中甲烷包裹体密度和热演化程度,以及甲烷包裹体、盐水包裹体与固体沥青的共生组合形式。结果表明,高密度甲烷包裹体主要形成于原油–沥青和干酪根高温–高压裂解的不混... 用光学显微镜和显微激光拉曼等技术手段综合研究了四川盆地4个钻孔中甲烷包裹体密度和热演化程度,以及甲烷包裹体、盐水包裹体与固体沥青的共生组合形式。结果表明,高密度甲烷包裹体主要形成于原油–沥青和干酪根高温–高压裂解的不混溶体系。研究样品中甲烷包裹体的拉曼位移为2909.76~2911.69 cm-1,计算对应的密度为0.251~0.351 g/cm3,其变化范围不仅与包裹体形成的温度、压力有关,而且还受到矿物包裹体保存条件的影响。样品的甲烷包裹体拉曼镜质体反射率(RMVRo)为3.07%~3.85%,多数>3.15%,其大小取决于地层中局域平衡体系的温度、压力和有效受热时间。各种包裹体与固体沥青的共生产出形式,反映了不同钻孔油气成因演化的重要信息:高科1井石英团块中捕获的高密度甲烷包裹体与储层焦沥青–碳沥青的产出特征,反映本区震旦系–寒武系碳酸盐岩气藏主要为储层油裂解气成因;五科1井志留系黑色页岩中的高密度甲烷包裹体产出形式和气体组成特征,反映志留系页岩气主要为残留烃和干酪根高温裂解成因,一般不含H2S并具有超压现象,据志留系黑色页岩石英脉中个别轻烃包裹体特征,推测部分奥陶系碳酸盐岩储层可能保存少量轻烃;普光5井富含H2S的高密度甲烷包裹体和焦沥青特征,提供了飞仙关组和长兴组碳酸盐岩储层中的油裂解气藏明显受硫酸盐热化学反应(TSR)影响的证据;普光3井须家河组石英脉中捕获的高密度包裹体不含H2S,甲烷包裹体中焦沥青反射率高达3.40%,而须家河组地层中固体沥青反射率为2.48%,两者热演化程度明显不匹配,提供了本区可能有深部含烃热流体沿逆冲断裂带上侵的重要信息。 展开更多
关键词 高密度甲烷包裹体 焦沥青 油裂解气 页岩气
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四川盆地盆外缘安场向斜富有机质页岩储层精细刻画及水平井靶窗优选 被引量:1
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作者 蓝宝锋 杨瑞东 +3 位作者 戴金星 姜海申 赵明芳 龙珍 《天然气地球科学》 CAS CSCD 北大核心 2024年第12期2184-2195,共12页
四川盆地外缘的复杂构造区“窄陡型”向斜内页岩气储层表现出较强的非均质性,给页岩气储层精细刻画及勘探开发井位部署带来挑战。基于安场向斜钻探成果,对盆外缘的安场向斜五峰组—龙马溪组富有机质页岩储层进行刻画。研究表明:(1)五峰... 四川盆地外缘的复杂构造区“窄陡型”向斜内页岩气储层表现出较强的非均质性,给页岩气储层精细刻画及勘探开发井位部署带来挑战。基于安场向斜钻探成果,对盆外缘的安场向斜五峰组—龙马溪组富有机质页岩储层进行刻画。研究表明:(1)五峰组—龙马溪组富有机质页岩以深水陆棚相沉积为主,按岩电特征可将龙马溪组(S_(1)l)划分为2段5个小层,在区域上具有很好的对比性。(2)富有机质页岩储层有机质丰度总体较高,自下而上TOC值呈现先增大后减小的变化趋势,在S_(1)l_(1)~2小层有机质丰度最高(TOC值平均为5.04%),有机质类型主要为Ⅰ型,均进入过成熟中期演化阶段,以生成干气为主。(3)孔隙类型丰富,主要有沥青孔、干酪根孔、粒间孔及晶间孔等,实测孔隙度为1.08%~5.76%,整体较高(平均值为3.46%)。纵向上五峰组(O_(3)w)孔隙度最高,S_(1)l_(2)段最低。(4)现场解吸气量为0.7~3.1 m^(3)/t,平均为1.54 m^(3)/t,测井解释O_(3)w、S_(1)l_(1)~1、S_(1)l_(1)~2和S_(1)l_(1)~3小层总含气量相对较高。富有机质页岩段含气饱和度分布于50%~80%之间,整体较高。(5)页岩储层主要矿物成分为石英、黏土、长石,总体脆性矿物含量较高。其中O3w、S_(1)l_(1)~1、S_(1)l_(1)~2和S_(1)l_(1)~3小层脆性指数相对较高。该地区最小水平主应力平均值为50.0 MPa,最大水平主应力平均值为65.2 MPa,水平地应力差异系数在0.25~0.36之间,向核部应力差有增大的趋势。(6)综合评价认为O_(3)w、S_(1)l_(1)~1、S_(1)l_(1)~2和S_(1)l_(1)~3页岩储层段为Ⅰ类储层,S_(1)l_(1)~4页岩储层段为Ⅱ类储层,S_(1)l_(2)页岩储层段为Ⅲ类储层,S_(1)l_(1)~1-S_(1)l_(1)~3页岩储层段可作为主力开发层系。综合工程因素,S_(1)l_(1)~2页岩储层段为该地区水平井穿行的最优靶窗,压裂时缝网可有效沟通下部S_(1)l_(1)~1和上部S_(1)l_(1)~3储层段。该研究成果可为安场向斜及南方复杂向斜区页岩气开发确定水平井轨迹提供理论指导。 展开更多
关键词 安场向斜 五峰组—龙马溪组 页岩气 小层划分与对比评价 水平井靶窗优选
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Sichuan super gas basin in southwest China 被引量:6
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作者 dai jinxing NI Yunyan +7 位作者 LIU Quanyou WU Xiaoqi GONG Deyu HONG Feng ZHANG Yanling LIAO Fengrong YAN Zengmin LI Hongwei 《Petroleum Exploration and Development》 CSCD 2021年第6期1251-1259,共9页
A sedimentary basin is classified as a super basin when its cumulative production exceeds 5 billion barrels of oil equivalent(6.82×10^(8) t of oil or 7931.66×10^(8) m^(3) of gas)and its remaining recoverable... A sedimentary basin is classified as a super basin when its cumulative production exceeds 5 billion barrels of oil equivalent(6.82×10^(8) t of oil or 7931.66×10^(8) m^(3) of gas)and its remaining recoverable resources are at least 5 billion barrels of oil equivalent.By the end of 2019,the total output of oil and gas in Sichuan Basin had been 6569×10^(8) m^(3),the ratio of gas to oil was 80:1,and the total remaining recoverable resources reached 136404×10^(8) m^(3),which makes it as a second-tier super basin.Because the output is mainly gas,it is a super gas basin.The reason why the Sichuan Basin is a super gas basin is that it has four advantages:(1)The advantage of gas source rocks:it has the most gas source rocks(9 sets)among all the basins in China.(2)The advantage of resource quantity:it has the most total remaining recoverable resources among all the basins in China(136404×10^(8) m^(3)).(3)The advantage of large gas fields:it has the most large gas fields(27)among all the basins in China.(4)The advantage of total production:by the end of 2019,the total gas production had been 6487.8×10^(8) m^(3),which ranked the first among all the basins in China.There are four major breakthroughs in natural gas exploration in Sichuan Basin:(1)Breakthrough in shale gas:shale gas was firstly found in the Ordovician Wufeng-Silurian Longmaxi formations in China.(2)Breakthrough in tight sandstone gas:the Triassic Xu2 Member gas reservoir in Zhongba gas field is the first high recovery tight sandstone gas reservoir in China.(3)Breakthrough in giant carbonate gas fields.(4)Breakthrough in ultra-deep gas reservoir.These breakthroughs have led to important progress in different basins across the country.Super basins are classified according to three criteria:accumulative oil and gas production,remaining recoverable resources,tectonic attributes of the basin and the proportion of oil and gas in accumulative oil and gas production. 展开更多
关键词 Sichuan Basin super basin oil and gas production RESOURCE source rocks large gas fields shale gas tight sandstone gas ultra-deep gas reservoir
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Characteristics of carbon isotopic composition of alkane gas in large gas fields in China 被引量:4
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作者 dai jinxing NI Yunyan +4 位作者 GONG Deyu HUANG Shipeng LIU Quanyou HONG Feng ZHANG Yanling 《Petroleum Exploration and Development》 SCIE 2024年第2期251-261,共11页
Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output t... Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output to 1925×108m3in 2020,making it the fourth largest gas-producing country in the world.Based on 1696 molecular components and carbon isotopic composition data of alkane gas in 70 large gas fields in China,the characteristics of carbon isotopic composition of alkane gas in large gas fields in China were obtained.The lightest and average values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become heavier with increasing carbon number,while the heaviest values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become lighter with increasing carbon number.Theδ^(13)C_(1)values of large gas fields in China range from-71.2‰to-11.4‰(specifically,from-71.2‰to-56.4‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-18.9‰for coal-derived gas,and from-35.6‰to-11.4‰for abiogenic gas).Based on these data,theδ^(13)C_(1)chart of large gas fields in China was plotted.Moreover,theδ^(13)C_(1)values of natural gas in China range from-107.1‰to-8.9‰,specifically,from-1071%o to-55.1‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-13.3‰for coal-derived gas,and from-36.2‰to-8.9‰for abiogenic gas.Based on these data,theδ^(13)C_(1)chart of natural gas in China was plotted. 展开更多
关键词 China large gas field bacterial gas oil-related gas coal-derived gas abiogenic gas alkane gas carbon isotopic composition δ^(13)C_(1)chart
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Major progress in the natural gas exploration and development in the past seven decades in China 被引量:9
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作者 dai jinxing QIN Shengfei +4 位作者 HU Guoyi NI Yunyan GAN Lideng HUANG Shipeng HONG Feng 《Petroleum Exploration and Development》 2019年第6期1100-1110,共11页
China has made significant progress in the exploration and development of natural gas in the past 70 years,from the gas-poor country to the world’s sixth largest gas production country.In 1949,the annual gas output i... China has made significant progress in the exploration and development of natural gas in the past 70 years,from the gas-poor country to the world’s sixth largest gas production country.In 1949,the annual gas output in China was 1117×104 m3,the proved gas reserves were 3.85×108 m3,and the average annual gas consumption and available reserves of per person were 0.0206 m3 and 0.7107 m3,respectively.By 2018,the average domestic annual gas production per person was 114.8576 m3 and the reserves were 12011.08 m3,and the average domestic annual gas production and reserves per person in the past 70 years increased by 5575 times and 16900 times,respectively.The exploration and development of large gas fields is the main way to rapidly develop the natural gas industry.72 large gas fields have been discovered in China so far,mainly distributed in three basins,Sichuan(25),Ordos(13)and Tarim(10).In 2018,the total gas production of the large gas fields in these three basins was 1039.26×108 m3,accounting for 65%of the total gas production in China.By the end of 2018,the cumulative proved gas reserves of the 72 large gas fields had amounted to 124504×108 m3,accounting for 75%of the total national gas reserves(16.7×1012 m3).New theories of natural gas have promoted the development of China’s natural gas industry faster.Since 1979,the new theory of coal-derived gas has boosted the discovery of gas fields mainly from coal-measure source rocks in China.In 2018,the gas production of large coal-derived gas fields in China accounted for 50.93%and 75.47%of the total national gas production and total gas production of large gas fields,respectively.Guided by shale gas theories,shale gas fields such as Fuling,Changning,Weiyuan and Weirong have been discovered.In 2018,the total proved geological reserves of shale gas were 10455.67×108 m3,and the annual gas production was 108.8×108 m3,demonstrating a good prospect of shale gas in China. 展开更多
关键词 China natural GAS coal-derived GAS SHALE GAS GAS production GAS RESERVES exploration and development PROGRESS
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MIL-101的制备与吸附水中亚硝酸盐氮研究 被引量:3
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作者 商鹏溟 贾瑛 +1 位作者 戴津星 许国根 《工业水处理》 CAS CSCD 北大核心 2019年第9期45-48,共4页
通过溶剂热法制备金属有机骨架材料(MOFs)MIL-101(Fe)和MIL-101(Fe)-NH2,并通过X射线衍射(XRD)、傅里叶红外光谱(FT-IR)、扫描电镜(SEM)进行表征。以水中的亚硝酸盐氮(NO2--N)为目标物,研究2种材料对其的吸附作用。结果表明,2种材料对NO... 通过溶剂热法制备金属有机骨架材料(MOFs)MIL-101(Fe)和MIL-101(Fe)-NH2,并通过X射线衍射(XRD)、傅里叶红外光谱(FT-IR)、扫描电镜(SEM)进行表征。以水中的亚硝酸盐氮(NO2--N)为目标物,研究2种材料对其的吸附作用。结果表明,2种材料对NO2--N的吸附符合准二级动力学和Langmuir等温吸附模型,吸附平衡时间为5 h。由于氨基的存在,MIL-101(Fe)-NH2的吸附能力略优于MIL-101(Fe)。 展开更多
关键词 金属有机骨架材料 吸附 亚硝酸盐氮
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真空紫外光-TiO_2催化降解气态偏二甲肼 被引量:2
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作者 戴津星 贾瑛 +1 位作者 许国根 商鹏溟 《化工环保》 CAS CSCD 北大核心 2019年第1期45-49,共5页
以钛箔为载体,采用溶胶-凝胶法及浸渍-烘焙-煅烧法制备了负载型TiO_2薄膜,并进行了SEM,EDS,XRD表征。探讨了TiO_2薄膜对气态偏二甲肼的光催化降解效果,并对比研究了不同紫外光源、不同初始浓度对气态偏二甲肼降解效果的影响。实验结果表... 以钛箔为载体,采用溶胶-凝胶法及浸渍-烘焙-煅烧法制备了负载型TiO_2薄膜,并进行了SEM,EDS,XRD表征。探讨了TiO_2薄膜对气态偏二甲肼的光催化降解效果,并对比研究了不同紫外光源、不同初始浓度对气态偏二甲肼降解效果的影响。实验结果表明:TiO_2均匀负载在钛箔上且为多孔状的薄膜;偏二甲肼质量浓度为877mg/m^3时,反应17 min后偏二甲肼的降解率为99.99%,500 mg/m^3时反应60 min后偏二甲肼的矿化率达到41.58%。 展开更多
关键词 偏二甲肼 废气 光催化 二氧化钛 真空紫外光
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Geochemical characteristics of ultra-deep natural gas in the Sichuan Basin, SW China 被引量:8
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作者 dai jinxing NI Yunyan +3 位作者 QIN Shengfei HUANG Shipeng PENG Weilong HAN Wenxue 《Petroleum Exploration and Development》 2018年第4期619-628,共10页
The natural gas components and geochemistry of 38 ultra-deep gas wells(burial depth greater than 6 000 m) in the Sichuan Basin were analyzed to determine the genesis of ultra-deep natural gas in the basin. The ultra-d... The natural gas components and geochemistry of 38 ultra-deep gas wells(burial depth greater than 6 000 m) in the Sichuan Basin were analyzed to determine the genesis of ultra-deep natural gas in the basin. The ultra-deep natural gas components of the basin have the following characteristics: Methane has an absolute advantage, which can be up to 99.56% with an average of 86.6%; ethane is low, with an average of 0.13%; there is nearly no propane and butane. So it is dry gas at over-mature thermal stage. The content of H2 S can be up to 25.21%, with an average of 5.45%. The alkane gas isotopes are: the carbon isotope varies from-32.3‰ to-26.7‰ for methane and from-32.9‰ to-22.1‰ for ethane. There is nearly no carbon isotopic reversal among methane and its homologues. Hydrogen isotope varies from-156‰ to-114‰ for methane, and from-103‰ to-89‰ for some ethane. The carbon isotope of CO_2 varies from-17.2‰ to 1.9‰ and most of them fall within the range of 0±3‰. According to the δ^(13)C_1-δ^(13)C_2-δ^(13)C_3 plot, except some wells, all other ultra-deep gas wells are dominated by coal-derived gas. Based on the CO_2 origin distinguishing plot and δ^(13)C_(CO_2), except some individual wells, most of the ultra-deep CO_2 are of carbonate metamorphic origin. H2 S in the ultra-deep layer of Longgang and Yuanba gas fields belongs to thermochemical sulfate reduction(TSR), while H2 S from Well Shuangtan belongs to thermal decomposition of sulfides(TDS). 展开更多
关键词 SICHUAN Basin ultra-deep GAS coal-derived GAS H2S origin geochemistry
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Characteristics of Compositional Migration in Mylonites from the Ductile Shear Zones of the Southern Tancheng-Lujiang Fault Belt, Eastern Anhui Province 被引量:1
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作者 YANG Xiaoyong LUI Deliang +2 位作者 YANG Xueming WANG Kuiren dai jinxing 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1998年第1期37-50,共14页
On the basis of field geology, three typical ductile shear zones in the southern part of the Tancheng-Lujiang fault belt have been chosen for a detailed study. Altogether ten samples of the tectonites have been collec... On the basis of field geology, three typical ductile shear zones in the southern part of the Tancheng-Lujiang fault belt have been chosen for a detailed study. Altogether ten samples of the tectonites have been collected for this study. The paper is focused on a comprehensive study of the tectonites in the medium-lower horizons of the ductile shear zones. The mineral compositions of the rocks are analyzed with EPMA and some typical whole-rock samples analyzed by chemical and ICP methods. Based on the comprehensive study of the characteristics of the deformation, the mineral assemblages and the changes of chemical composition of the bulk rocks, this paper presents a discussion on the relationship between the volume loss, the fluid flow and compositional changes during mylonitization of the ductile shear zones in this region. Our study shows that there are a large amount of fluids flowing through the shear zones during the process of mylonization, accompanied by the loss of rock volume and migration of elements and components. Modelling calculation results under different saturation conditions of fluids show that the maximum volume loss of the tectonites is about 60% relative to their protolith, while the fluid/rock ratio ranges from 10 to 103 in different ductile shear zones. 展开更多
关键词 MYLONITE ductile shear zones volume loss fluid-rock interaction compositional migration Tancheng-Lujiang fault belt
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The significance of coal-derived gas in major gas producing countries 被引量:2
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作者 dai jinxing NI Yunyan +2 位作者 LIAO Fengrong HONG Feng YAO Limiao 《Petroleum Exploration and Development》 2019年第3期435-450,共16页
The core of coal-derived gas theory is that coal measure is the gas source, and the hydrocarbon generation of coal measure is dominated by gas and supplemented by oil, so discoveries in related basins are dominated by... The core of coal-derived gas theory is that coal measure is the gas source, and the hydrocarbon generation of coal measure is dominated by gas and supplemented by oil, so discoveries in related basins are dominated by gas fields. Discovering and developing giant gas fields, especially those super giant gas fields with recoverable reserves more than 1×10^12 m^3, plays a key role in determining whether a country can be a major gas producing country with annual output over 500×10^8 m^3. The coal resource and coal-derived gas reserves are abundant and widespread in the world, and coal-derived gas makes a major contribution to the gas reserves and gas production in the world. By the end of 2017, 13 super giant coal-derived gas fields have been discovered in the world. The total initial recoverable reserves were 49.995 28×10^12 m^3, accounting for 25.8% of the total remaining recoverable reserves (193.5×10^12 m^3) in that year in the world. In 2017, there were 15 giant gas producing countries in the world, with a total gas yield of 28 567×10^8 m^3. Among them, six major coal-derived gas producing countries had a total gas yield of 11 369×10^8 m^3, accounting for 39.8% of total gas yield of major gas producing countries. The Urengoi gas field is a super giant coal-derived gas field with the most cumulative gas production in the world. By the end of 2015, the Urengoi gas field had cumulative gas production of 63 043.96×10^8 m^3, with the highest annual gas yield in the world. Its gas output was 3 300×10^8 m^3 in 1989, accounting for 41.4% and 15.7% of the gas output of Russia and the world, respectively. This study introduces the gas source rocks of the basins with super giant coal-derived gas fields in Russia, Turkmenistan, Netherlands, Mozambique and China, and their significances for these countries becoming giant gas producing countries in the world. 展开更多
关键词 coal-derived GAS MAJOR GAS producing COUNTRY China RUSSIA super GIANT GAS field source rock
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Exploration and development of large gas fields in China since 2000 被引量:5
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作者 dai jinxing Wu Wei +1 位作者 Fang Chenchen Liu Dan 《Natural Gas Industry B》 2015年第1期1-8,共8页
Fifty-one large gas fields had been proved in China until 2013.Specifically,exploration characteristics of those discovered since 2000 are as follows:(1)Large gas fields are only found in basins with sedimentary area ... Fifty-one large gas fields had been proved in China until 2013.Specifically,exploration characteristics of those discovered since 2000 are as follows:(1)Large gas fields are only found in basins with sedimentary area larger than 10×10^(4) km^(2);(2)Large gas fields have been proved in 9 basins,with total proved reserves of 27085.88×10^(8) m^(3) before 2005,much less than that after 2005,which reached 81683.77×10^(8) m^(3) by the end of 2013;(3)The reserve abundance of large gas fields varies a lot.The Kela2 gas field has the largest reserve abundance of 59.05×10^(8) m^(3)/km^(2),which is 86 times that of the smallest reserve abundance,i.e.0.684×10^(8) m^(3)/km^(2) of the Jingbian gas field;and(4)The reservoirs of large gas fields between 3000 m and 4500 m share a large proportion of proved reserves,accounting for 46.11%of the total.Development characteristics of the large gas fields in China are as follows:(1)The yield of large gas fields is essential to the natural gas industry of China.In 2013,the total yield was 922.72×10^(8) m^(3),accounting for 76.3%of the nation’s total natural gas yield;(2)The yield is dominated by coal-derived gas,which reached 710.13×10^(8) m^(3) in 2013,accounting for 77.0%of the total yield of large gas fields in China;and(3)The yield of key large gas fields(Sulige,Jingbian,Daniudi,Puguang,and Kela2)is fundamental in making China a major gas producer. 展开更多
关键词 China Large gasfield Coal-derived gas EXPLORATION Development RESERVES YIELD
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Distribution patterns of tight sandstone gas and shale gas
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作者 dai jinxing DONG Dazhong +7 位作者 NI Yunyan GONG Deyu HUANG Shipeng HONG Feng ZHANG Yanling LIU Quanyou WU Xiaoqi FENG Ziqi 《Petroleum Exploration and Development》 SCIE 2024年第4期767-779,共13页
Based on an elaboration of the resource potential and annual production of tight sandstone gas and shale gas in the United States and China,this paper reviews the researches on the distribution of tight sandstone gas ... Based on an elaboration of the resource potential and annual production of tight sandstone gas and shale gas in the United States and China,this paper reviews the researches on the distribution of tight sandstone gas and shale gas reservoirs,and analyzes the distribution characteristics and genetic types of tight sandstone gas reservoirs.In the United States,the proportion of tight sandstone gas in the total gas production declined from 20%-35%in 2008 to about 8%in 2023,and the shale gas production was 8310×10^(8)m^(3)in 2023,about 80%of the total gas production,in contrast to the range of 5%-17%during 2000-2008.In China,the proportion of tight sandstone gas in the total gas production increased from 16%in 2010 to 28%or higher in 2023.China began to produce shale gas in 2012,with the production reaching 250×10^(8)m^(3)in 2023,about 11%of the total gas production of the country.The distribution of shale gas reservoirs is continuous.According to the fault presence,fault displacement and gas layer thickness,the continuous shale gas reservoirs can be divided into two types:continuity and intermittency.Most previous studies believed that both tight sandstone gas reservoirs and shale gas reservoirs are continuous,but this paper holds that the distribution of tight sandstone gas reservoirs is not continuous.According to the trap types,tight sandstone gas reservoirs can be divided into lithologic,anticlinal,and synclinal reservoirs.The tight sandstone gas is coal-derived in typical basins in China and Egypt,but oil-type gas in typical basins in the United States and Oman. 展开更多
关键词 shale gas tight sandstone gas reservoir characteristics continuous accumulation lithologic accumulation anticlinal accumulation synclinal accumulation coal-derived gas oil-type gas
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