A detailed study of the cyclic voltammtry curve of Pt(111) electrode in H2SO4 solution by X-ray photoe1ectron spectroscopy (XPS) and a low energy electron diffeaction (LEED) has provided firstly direct evidence that t...A detailed study of the cyclic voltammtry curve of Pt(111) electrode in H2SO4 solution by X-ray photoe1ectron spectroscopy (XPS) and a low energy electron diffeaction (LEED) has provided firstly direct evidence that the anomalous features reported originally by Clavilier et al. are associated with the specific adsorption of sulfate ainons rather than hydrogen adsorption. The ()R30 structure on Pt(111) obtained after electrode emersion on the positive scan at more positive potentials than 0.23V vs. Ag/AgCl appears sedtaneously with sharp increase of XPS of O1s and S2p. This implies the relationship between anomalous peak and sulfate anion adsorption on emersed Pt(111 ) electrode.展开更多
文摘A detailed study of the cyclic voltammtry curve of Pt(111) electrode in H2SO4 solution by X-ray photoe1ectron spectroscopy (XPS) and a low energy electron diffeaction (LEED) has provided firstly direct evidence that the anomalous features reported originally by Clavilier et al. are associated with the specific adsorption of sulfate ainons rather than hydrogen adsorption. The ()R30 structure on Pt(111) obtained after electrode emersion on the positive scan at more positive potentials than 0.23V vs. Ag/AgCl appears sedtaneously with sharp increase of XPS of O1s and S2p. This implies the relationship between anomalous peak and sulfate anion adsorption on emersed Pt(111 ) electrode.
