1 Results Introduction of functional groups at the frameworks of the centropolyindanes is a non-trivial task since the construction of the rigid and massive skeletons of,e.g.,tribenzotriquinacene and fenestrindane req...1 Results Introduction of functional groups at the frameworks of the centropolyindanes is a non-trivial task since the construction of the rigid and massive skeletons of,e.g.,tribenzotriquinacene and fenestrindane requires well-balanced synthesis strategies[1,2].In the present contribution,some selected examples are presented for the recent multiple functionalization of tribenzotriquinacenes,such as compound 1,and fenestrindanes,such as compound 2,preformed in our laboratory.See Fig.1.展开更多
1 Results The centropolyindanes represent a family of novel polycyclic aromatic hydrocarbons that are characterized by particularly rigid,three-dimensional frameworks.Mutual fusion of up to six indane units about a co...1 Results The centropolyindanes represent a family of novel polycyclic aromatic hydrocarbons that are characterized by particularly rigid,three-dimensional frameworks.Mutual fusion of up to six indane units about a common neopentane core gives rise to various closely related,prototypical molecular scaffolds of high symmetry,and the indane units stretching out into the 3-space along the axes of the Cartesian coordinate system[1-2].Among the parent centropolyindanes,tribenzotriquinacene 1 is chemically mo...展开更多
文摘1 Results Introduction of functional groups at the frameworks of the centropolyindanes is a non-trivial task since the construction of the rigid and massive skeletons of,e.g.,tribenzotriquinacene and fenestrindane requires well-balanced synthesis strategies[1,2].In the present contribution,some selected examples are presented for the recent multiple functionalization of tribenzotriquinacenes,such as compound 1,and fenestrindanes,such as compound 2,preformed in our laboratory.See Fig.1.
文摘1 Results The centropolyindanes represent a family of novel polycyclic aromatic hydrocarbons that are characterized by particularly rigid,three-dimensional frameworks.Mutual fusion of up to six indane units about a common neopentane core gives rise to various closely related,prototypical molecular scaffolds of high symmetry,and the indane units stretching out into the 3-space along the axes of the Cartesian coordinate system[1-2].Among the parent centropolyindanes,tribenzotriquinacene 1 is chemically mo...
