Catalytic direct functionalization of unreactive C--H bonds represents a sustainable and more atom economical transformation process. Porphyrin and pbthalocyanine derivatives show promising catalytic activities in dir...Catalytic direct functionalization of unreactive C--H bonds represents a sustainable and more atom economical transformation process. Porphyrin and pbthalocyanine derivatives show promising catalytic activities in direct C-- H arylation reactions. These reactions share a common C--C bond formation process via homolytic radical substi- tution. This review summarizes the catalytic direct C--H arylation reactions catalyzed by metalloporphyrins, free base porphyrins and free base phthalocyanines.展开更多
文摘Catalytic direct functionalization of unreactive C--H bonds represents a sustainable and more atom economical transformation process. Porphyrin and pbthalocyanine derivatives show promising catalytic activities in direct C-- H arylation reactions. These reactions share a common C--C bond formation process via homolytic radical substi- tution. This review summarizes the catalytic direct C--H arylation reactions catalyzed by metalloporphyrins, free base porphyrins and free base phthalocyanines.
