Several novel pyridine-oxadiazole iridium complexes were synthesized and characterized through X-ray crystallography.The designed iridium.complexes revealed surprisingly high catalytic activity in C-N bondformation of...Several novel pyridine-oxadiazole iridium complexes were synthesized and characterized through X-ray crystallography.The designed iridium.complexes revealed surprisingly high catalytic activity in C-N bondformation of amides and benzyl alcohols with the assistance of non-coordinating anions.In an attempt to achieve borrowing hydrogen reactions of amides with benzyl alcohols,N,N'-(phenylmethylene)dibenzamide products we re unexpectedly isolated under non-coordinating anion conditions,whereas N-benzylbenzamide products were achieved in the absence of non-coordinating anions.The mechanism explorations excluded the possibility of"silver effect"(silver-assisted or bimetallic catalysis)and revealed that the reactivity of iridium catalyst was varied by non-coordinating anions.This work provided a convenient and useful methodology that allowed the iridium complex to be a chemoselective catalyst and demonstrated the first example of non-coordinating-anion-tuned selective C-N bond formation.展开更多
This paper presents a new implementation of a high-definition image-processing engine,which mainly targets the 3-dimensional(3D)visualization and stereo video stream display of binocular display equipment.The engine i...This paper presents a new implementation of a high-definition image-processing engine,which mainly targets the 3-dimensional(3D)visualization and stereo video stream display of binocular display equipment.The engine is compatible with the mainstream analog and digital stereo videos in component format and is able to receive stereo composite video broadcast signals using an integrated analog stereo video decoder.The four modules include a spatiotemporal scaling transform engine,a 2D–3D converter,an image animating engine,and a 2D scalar operating in pipeline architecture to implement the video format conversion and the stereo effect enhancement.Furthermore,the data access,hardware structure,and system-level configurations are optimized.Finally,the proposed architecture is realized by 0.18 lm CMOS technology.The application-specific integrated circuit verification results show that the engine can generate a strong feeling of 3D immersion and highdefinition image quality with minimal flicker.The chip has wide compatibility and an uppermost 1080P-processing capacity,which has approximately 3.5 million gates with about 43 mm2 die size.展开更多
基金financial support from the National Natural Science Foundation of China(Nos.21776111,21861039)the Fundamental Research Funds for the Central Universities(No.JUSRP 51627B)the Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project(No.B13025)。
文摘Several novel pyridine-oxadiazole iridium complexes were synthesized and characterized through X-ray crystallography.The designed iridium.complexes revealed surprisingly high catalytic activity in C-N bondformation of amides and benzyl alcohols with the assistance of non-coordinating anions.In an attempt to achieve borrowing hydrogen reactions of amides with benzyl alcohols,N,N'-(phenylmethylene)dibenzamide products we re unexpectedly isolated under non-coordinating anion conditions,whereas N-benzylbenzamide products were achieved in the absence of non-coordinating anions.The mechanism explorations excluded the possibility of"silver effect"(silver-assisted or bimetallic catalysis)and revealed that the reactivity of iridium catalyst was varied by non-coordinating anions.This work provided a convenient and useful methodology that allowed the iridium complex to be a chemoselective catalyst and demonstrated the first example of non-coordinating-anion-tuned selective C-N bond formation.
基金supported by the Important Specific Projects of National Science and Technology of China(2009ZX01033-001-010)
文摘This paper presents a new implementation of a high-definition image-processing engine,which mainly targets the 3-dimensional(3D)visualization and stereo video stream display of binocular display equipment.The engine is compatible with the mainstream analog and digital stereo videos in component format and is able to receive stereo composite video broadcast signals using an integrated analog stereo video decoder.The four modules include a spatiotemporal scaling transform engine,a 2D–3D converter,an image animating engine,and a 2D scalar operating in pipeline architecture to implement the video format conversion and the stereo effect enhancement.Furthermore,the data access,hardware structure,and system-level configurations are optimized.Finally,the proposed architecture is realized by 0.18 lm CMOS technology.The application-specific integrated circuit verification results show that the engine can generate a strong feeling of 3D immersion and highdefinition image quality with minimal flicker.The chip has wide compatibility and an uppermost 1080P-processing capacity,which has approximately 3.5 million gates with about 43 mm2 die size.
