Signatures of superconductivity near 80 K have recently been discovered in single crystals of La_(3)Ni_(2)O_(7)under pressure,which makes it a new candidate for high-temperature superconductors dominated by 3d transit...Signatures of superconductivity near 80 K have recently been discovered in single crystals of La_(3)Ni_(2)O_(7)under pressure,which makes it a new candidate for high-temperature superconductors dominated by 3d transition elements,following the cuprate and iron-pnictide superconductors.However,there are several critical questions that have been perplexing the scientificommunity:(1)What factors contribute to the inconsistent reproducibility of the experimental results?(2)What is the fundamental nature of pressure-induced superconductivity:bulk or nonbulk(filamentary-like)(3)Where is the superconducting phase located within the sample if it is filamentary-like(4)Is the oxygen content important for the development and stabilization of superconductivity?In this study,we employ comprehensive high-pressure techniques to address these questions.Through our modulated ac susceptibility measurements,we are the firs to fin that the superconductivity in this nickelate is filamentary-like Our scanning transmission electron microscopy investigations suggest that the filamentary-lik superconductivity most likely emerges at the interface between La_(3)Ni_(2)O_(7)and La_(4)Ni_(3)O_(10)phases.By tuning the oxygen content of polycrystalline La_(3)Ni_(2)O_(7),we also fin that it plays vital role in the development and stabilization of superconductivity in this material.The upper and lower bounds on the oxygen content are 7.35 and 6.89,respectively.Our results provide not only new insights into the puzzling issues regarding this material,but also significan information that will enable a better understanding of its superconductivity.展开更多
Although flexible,stretchable,and conductive core-sheath structured smart fibers have propelled to the forefront research in wearable strain sensors and self-powered electronics,challenges related to scalability,compl...Although flexible,stretchable,and conductive core-sheath structured smart fibers have propelled to the forefront research in wearable strain sensors and self-powered electronics,challenges related to scalability,complexity,and mechanical durability remain.In this study,we propose a strategy for the scalable production of conductive coaxial fiber(CCF)with superior durability through one-step direct wet spinning coherent solutions.By introducing the polystyrene-block-polyisoprene-block-polystyrene phase in both inner and outer layers,CCFs feature an interleaved topology and share a similar modulus,successfully resolving the issue of layer separation over time.They can endure up to 15,000 cycles with no damage at a strain of 100%.In addition,the topological entanglement CCF as a strain sensor exhibits a broad operational range of up to 398.3%strain,outstanding sensitivity(i.e.,gauge factor=6713 at 398.3%strain)and swift response time(248 ms).Enhanced by machine learning,the system achieves a high accuracy rate of 95%in gait recognition and 100%in American Sign Language identification.Furthermore,the CCF can function as a wearable triboelectric nanogenerator(TENG)for self-powered sensing and mechanical energy harvesting.This study represents a significant step toward the development of multifunctional micro-wearable electronic devices,which hold immense promise for medical sensing and energy harvesting in smart wearable electronics,human-computer interaction,and artificial intelligence.展开更多
The surface injection and production system(SIPS)is a critical component for effective injection and production processes in underground natural gas storage.As a vital channel,the rational design of the surface inject...The surface injection and production system(SIPS)is a critical component for effective injection and production processes in underground natural gas storage.As a vital channel,the rational design of the surface injection and production(SIP)pipeline significantly impacts efficiency.This paper focuses on the SIP pipeline and aims to minimize the investment costs of surface projects.An optimization model under harmonized injection and production conditions was constructed to transform the optimization problem of the SIP pipeline design parameters into a detailed analysis of the injection condition model and the production condition model.This paper proposes a hybrid genetic algorithm generalized reduced gradient(HGA-GRG)method,and compares it with the traditional genetic algorithm(GA)in a practical case study.The HGA-GRG demonstrated significant advantages in optimization outcomes,reducing the initial cost by 345.371×10^(4) CNY compared to the GA,validating the effectiveness of the model.By adjusting algorithm parameters,the optimal iterative results of the HGA-GRG were obtained,providing new research insights for the optimal design of a SIPS.展开更多
A series of novel red-emitting BaLiZn_(3)(BO_(3))_(3):Eu^(3+)phosphors were synthesized through the high temperature solid state reaction method.The phase composition,crystal structure,morphology and photo luminescenc...A series of novel red-emitting BaLiZn_(3)(BO_(3))_(3):Eu^(3+)phosphors were synthesized through the high temperature solid state reaction method.The phase composition,crystal structure,morphology and photo luminescence property of the BaLiZn_(3)(BO_(3))_(3):Eu^(3+)samples were systematically investigated.The phosphor can be efficiently excited by the near ultraviolet light(NUV)of 396 nm and blue light of 466 nm,and give out red light emission at 618 nm corresponding to the electric dipole transition(^(5)D_(0)→^(7)E_(2)).The optimal doping concentration of Eu^(3+)ions in BaLiZn_(3)(BO_(3))_(3)is determined to be about 3 mol%,and the concentration-quenching phenomenon arise from the electric dipole-dipole interaction.The temperature dependent luminescence behavior of BaLiZn_(3)(BO_(3))_(3):0.03 Eu^(3+)phosphor exhibits its good thermal stability,and the activation energy for thermal quenching characteristics is calculated to be 0.1844 eV.The decay lifetime of the BaLiZn_(3)(BO_(3))_(3):0.03 Eu^(3+)is measured to be 1.88 ms.These results suggest that the BaLiZn_(3)(BO_(3))_(3):Eu^(3+)phosphors have the potential application as a red component in white light emitting diodes(WLEDs)with NUV or blue chips.展开更多
Leaf color is an important target trait in Chinese cabbage breeding programs.Leaf yellowing may reduce crop commercial and nutritional values.Some plants with the“stay-green”trait maintain leaf greenness during sene...Leaf color is an important target trait in Chinese cabbage breeding programs.Leaf yellowing may reduce crop commercial and nutritional values.Some plants with the“stay-green”trait maintain leaf greenness during senescence and even after death.Stay-green Chinese cabbage may be a focal point of future breeding projects because it could improve crop quality and yield and prolong shelf life.A new stay-green mutant,non-yellowing mutant 1(nym1),was identified in Chinese cabbage derived from an ethyl methane sulfonate(EMS)-mutagenized population.The mutant had stay-green characteristics and a higher chlorophyll content than the wild-type during leaf senescence.The staygreen trait in the mutant Chinese cabbage was controlled by the recessive gene Brnym1.MutMap and KASP analyses showed that Brnym1(BraA03g050600.3C)encodes an mg-dechelatase(SGR protein),which might be the causal gene of the mutation in Chinese cabbage.A nonsynonymous single nucleotide base substitution(G to A)in the third exon of Brnym1 caused an amino acid substitution from L to F in the highly conserved domain of the magnesiumdechelatase.Ectopic overexpression showed that the BrNYM1 gene of wild-type Chinese cabbage complemented the SGR-defective stay-green mutant nye1-1 of Arabidopsis.The magnesium-dechelatase activity in the nym1 mutant was significantly downregulated compared to that in the wild type.Brnym1 was relatively upregulated in the mutant during late senescence,and BrNYM1 was localized to the chloroplasts.These results indicate that Brnym1(BraA03g050600.3C)is the causal gene of the stay-green mutation and could be of particular significance in the genetic improvement of Chinese cabbage.展开更多
Anode SnO_(2)in lithium-ion batteries suffers from volume expansion and agglomeration.Here,the SnO_(2)nanoparticles are hybrided with ZrO_(2)particles by the support of carbon nanotube networks.The obtained SnO_(2)/C/...Anode SnO_(2)in lithium-ion batteries suffers from volume expansion and agglomeration.Here,the SnO_(2)nanoparticles are hybrided with ZrO_(2)particles by the support of carbon nanotube networks.The obtained SnO_(2)/C/ZrO_(2)composite shows improved electrochemical performances.Investigations reveal that the carbon nanotubes shorten the transmission path of electrons and Li^(+) ions.Ball milling with ZrO_(2)promotes the formation of nanosized SnO_(2)to weaken the internal strain change,being beneficial to buffering volume change during electrochemical cycling afterwards.High-resolution 6.7Li NMR investigations indicate that conversion and alloying reactions are stepwise involved for SnO_(2)/C/ZrO_(2)anode.The strategy of designing SnO_(2)/C/ZrO_(2)composite from the morphology-controlled metal-organic frameworks for energy storage widens the possibility to fabricate promising materials with enhanced performances.展开更多
Rare-earth sulfides are of research interest for lithium-ion batteries(LIBs)due to their abundant lithium intercalation sites and low redox voltage.However,their electrochemical performances are not satisfactory becau...Rare-earth sulfides are of research interest for lithium-ion batteries(LIBs)due to their abundant lithium intercalation sites and low redox voltage.However,their electrochemical performances are not satisfactory because of poor conductivity and volume change upon electrochemical cycling.Herein,nanoarchitectures ofγ-Ce_(2)S_(3)encapsulated in a hollow mesoporous carbon nanosphere(Ce_(2)S_(3)@HMCS)are fabricated using the self-template strategy combined with the in-sphere sulfuration method and tested as an LIB anode.The void space between the Ce_(2)S_(3)core and the outer layer of the carbon nanosphere has been properly designed and modulated to achieve excellent electrochemical performance in terms of electronic conductivity,reversibility,and rate capability.The reversible capacity of Ce_(2)S_(3)@HMCS is 2.6 times that of the pure Ce_(2)S_(3)anode,which can gradually increase and maintain a capacity of 282 mAh·g^(−1)at a current density of 1 A·g^(-1),and a high Coulombic efficiency(~100%)can be achieved even after 1000 cycles.This good performance is attributed to the unique yolk-shell nanostructure with a highly crystallized and stable Ce3S2 core and volume expansion buffer space upon lithiation/delithiation.Ex situ X-ray diffraction and nuclear magnetic resonance results indicate that the lithiation of Ce_(2)S_(3)@HMCS is an intercalation process.This study represents an important advancement in precise structural design with in-sphere sulfuration and sheds light on a potential direction for highperformance lithium storage.展开更多
It is important to understand the impact of wing-morphing on aerodynamic performance in the study of flapping-wing flight of birds and insects. We use a flapping plate hinged with a trailing-edge flap as a simplified ...It is important to understand the impact of wing-morphing on aerodynamic performance in the study of flapping-wing flight of birds and insects. We use a flapping plate hinged with a trailing-edge flap as a simplified model for flexible/morphing wings in hovering. The trailing-edge flapping motion is opti- mized by an adjoint-based approach. The optimized configuration suggests that the trailing-edge flap can substantially enhance the overall lift. Further analysis indicates that the lift enhancement by the trailing- edge flapping is from the change of circulation in two ways: the local circulation change by the rotational motion of the flap, and the modification of vortex shedding process by the relative location between the trailing-edge flao and leading-edge main plate.展开更多
Non-toxic rare earth(RE) composite materials are promising and active in optoelectronic fields,such as pigment.In this work,Na ions doped γ-Ce_(2) S_(3) pigments were synthesized by solid-phase vulcanization and foll...Non-toxic rare earth(RE) composite materials are promising and active in optoelectronic fields,such as pigment.In this work,Na ions doped γ-Ce_(2) S_(3) pigments were synthesized by solid-phase vulcanization and followed by in-situ synthesis to prepare an outer layer of CePO_(4) film.The characterizations of X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),solid state nuclear magnetic resonance(NMR) indicate that Na-dopedγ-Ce_(2) S_(3) and CePO_(4) uniformly and tightly coated core-shell structure was successfully synthesized.The thermogravimetric analysis(TG) and reflection spectrum(RS) reveal that the CePO_(4) coating significantly improves the colorant and thermal stability performance of γ-Ce_(2) S_(3) .The excellent color quality of γ-Ce_(2) S_(3) @CePO_(4)(L*=45.16,a*=55.94.b*=44.53) is achieved and the red color(L*=43.82,a*=49.79,b*=38.04) is still retained even if the sample is heated in air at 400℃ for 30 min.展开更多
Objective:To evaluate the efficacy and safety of Shen Zhi Ling oral liquid(SZL)alone or combined with basic treatment in treating Alzheimer's Disease(AD).Methods:Databases including PubMed,the Cochrane Library,Emb...Objective:To evaluate the efficacy and safety of Shen Zhi Ling oral liquid(SZL)alone or combined with basic treatment in treating Alzheimer's Disease(AD).Methods:Databases including PubMed,the Cochrane Library,Embase,Web of science,China National Knowledge Infrastructure(CNKI),Wanfang Database and the Chinese Science and Technology Journal Database(VIP)were searched from inception to September 20,2020 to collect relevant randomized controlled trials(RCTs)comparing SZL with other nootropic drugs for AD.The primary clinical outcomes were scores of the Mini Mental State Examination(MMSE)and the Activities of Daily Living(ADL)during treatment.The secondary outcomes of our study included other neuropsychological scale scores including Rapid Verbal Retrieve(RVR),Digit Span(DS),Fuld Object-Memory Evaluation(FOM)and adverse events or reactions.Two authors searched and screened the literature independently,then extracted the data and evaluated the methodological quality by using the handbook of Cochrane Collaboration,and analyzed the data via the Review Manager 5.3 software.Results:In total,we included four studies,covering 217 participants.All studies were in a low methodological quality.The result of MMSE score,ADL score,RVR score,DS score and FOM score in the meta-analysis showed that no statistically significant difference(P>0.05)between the treatment groups and control groups,and the statistical heterogeneity of all meta-analyses was small(I2<50%).SZL was indicated no better than other nootropic drugs.Among the included studies,no study described adverse events.Conclusions:Considering the low quality of the included trials and the different levels of AD patients,we are unable to come to any conclusion about the efficacy and safety of SZL compared with other nootropic drugs.Moreover,we still need rigorously designed,multi-center,large-scale trials to further confirm the efficacy and safety of SZL.展开更多
A novel orange-red emitting Ba3 Y4 O9:Sm^(3+) phosphors were prepared by a high temperature solidstate reaction in air. X-ray diffraction(XRD), photoluminescence spectra, fluorescence decay and temperature-depen...A novel orange-red emitting Ba3 Y4 O9:Sm^(3+) phosphors were prepared by a high temperature solidstate reaction in air. X-ray diffraction(XRD), photoluminescence spectra, fluorescence decay and temperature-dependent emission spectra were utilized to characterize the structure and luminescence properties. The results show that the excitation spectrum includes a series of linear peaks at350, 367, 382, 410, 424, 445, 470 and 495 nm, respectively. Under 410 nm excitation, the emission peaks were located at 574 nm(~4 G(5/2)-~6 H(5/2)), 608 nm(~4 G(5/2)-~6 H(7/2)),659 nm(~4 G(5/2)-~6 H(9/2)) and722 nm(~4 G(5/2)-~6 H(11/2)), respectively. The concentration quenching occurs when x equals 0.08 for Ba3 Y(4-x)O9:xSm^(3+) phosphor and its mechanism is ascribed to the dipole-dipole interaction. The chromaticity coordinates of Ba3 Y(3.92)O9:0.08 Sm^(3+) phosphor are in the orange-red region. The temperature-dependent study shows that this phosphor has excellent luminescence thermal-stability.And the luminescence intensity of Ba3 Y(3.92)O9:0.08 Sm^(3+) phosphor at 473 K only declines by about25.75% of its initial intensity. The experimental data indicate that Ba3 Y4 O9:Sm^(3+) phosphor may be promising as an orange-red emitting phosphor for white light emitting diodes.展开更多
The powder samples of Ca_(9)Sc(PO_(4))_(7):xDy^(^(3+))white emitting phosphors were prepared via a solid state reaction technique.The Ca_(9)Sc(PO_(4))_(7):Dy^(3+)samples were researched by using the GSAS Rietveld refi...The powder samples of Ca_(9)Sc(PO_(4))_(7):xDy^(^(3+))white emitting phosphors were prepared via a solid state reaction technique.The Ca_(9)Sc(PO_(4))_(7):Dy^(3+)samples were researched by using the GSAS Rietveld refinement and X-ray diffraction(XRD) methods,and SEM images and elemental maps were recorded.Under 350 nm excitatio n,the emission spectra of Ca_(9)Sc(PO_(4))_(7):xDy^(3+)samples have two obvious peaks and one weak peak at 484,572 and660 nm,corresponding to the characteristic electron transitions of(^(4)F_(9/2)→ ^(6)H_(15/2),blue),(^(4)F_(9/2)→ ^(6)H_(13/2),yellow) and(^(4)F_(9/2)→ 6 H11/2,red),respectively.The concentration quenching effect,decay lifetime and thermal quenching of the as-synthesized Ca_(9)Sc(PO_(4))_(7):Dy^(3+)samples were researched systematically.The Ca_(9)Sc(PO_(4))_(7):0.02 Dy^(3+)phosphor possesses a good thermal stability,of which the emission intensity at 423 K can maintain 79% of the initial value(273 K).In addition,through the study of the chro maticity coordinates of the Ca_(9)Sc(PO_(4))_(7):0.02 Dy^(3+)phosphor,it is found that it is located in the white region,and the Commission Internationalede L’Eclairage(CIE) chromaticity coordinates are(0.339,0.389),The above results show that Ca_(9)Sc(PO_(4))_(7):xDy^(3+)phosphors can be excellent candidate material for applications in NUV-excited white LEDs.展开更多
It is of great importance to explore a creative route to improve the degradation e ciency of organic pollutants in wastewater.Herein,we construct a unique hybrid system by combining self-powered triboelectric nanogene...It is of great importance to explore a creative route to improve the degradation e ciency of organic pollutants in wastewater.Herein,we construct a unique hybrid system by combining self-powered triboelectric nanogenerator(TENG)with carbon dots-TiO_(2)sheets doped three-dimensional graphene oxide photocatalyst(3 DGA@CDs-TNs),which can significantly enhance the degradation e ciency of brilliant green(BG)and direct blue 5 B(DB)owing to the powerful interaction of TENG and 3 DGA@CDs-TNs photocatalyst.The power output of TENG can be applied for wastewater purification directly,which exhibits a selfpowered electrocatalytic technology.Furthermore,the results also verify that TENG can replace conventional electric catalyst to remove pollutants e ectively from wastewater without any consumption.Subsequently,the unstable fragments and the plausible removal pathways of the two pollutants are proposed.Our work sheds light on the development of e cient and sustainable TENG/photocatalyst system,opening up new opportunities and possibilities for comprehensive utilization of random energy.展开更多
The tilt-blade mechanical stirring of A356-2.5vol.%SiCp liquid was conducted in a cylindrical crucible to solve the problem of nonhomogeneous radial distribution of SiC particles in conventional straight-blade mechani...The tilt-blade mechanical stirring of A356-2.5vol.%SiCp liquid was conducted in a cylindrical crucible to solve the problem of nonhomogeneous radial distribution of SiC particles in conventional straight-blade mechanical stirring. The radial distribution of SiC particles in A356 liquid was studied under the conditions of 25° for horizontal tilt angle α of the blade, 200 r/min for rotating speed of stirrer and 10 mm/s for speed of moving up and down of stirrer. The results show that there exists a nonlinear relationship between circumferential tilt angle β of the blade and radial relative deviation d of SiCp content in A356 liquid. When β is smaller than 20°, the d of SiCp content in A356 liquid between the center and the periphery of crucible decreases with increasing β. Conversely, when β is bigger than 26°, d increases with increasing β. Only when β is about 20°, d can be equal to nought i.e. uniform radial distribution of SiC particles can be realized. It can be seen that the nonhomogeneous radial distribution of SiC particles in conventional straight-blade mechanical stirring can be eliminated in this tilt-blade mechanical stirring of A356-SiCp liquid.展开更多
A series of Eu^(2+)/Dy^(3+) single doped and co-doped Na_(3)Sc_(2)(PO_(4))_(3) phosphors were synthesized by the high-temperature solid-state method,and their phase,morphology,and luminescence properties were characte...A series of Eu^(2+)/Dy^(3+) single doped and co-doped Na_(3)Sc_(2)(PO_(4))_(3) phosphors were synthesized by the high-temperature solid-state method,and their phase,morphology,and luminescence properties were characterized.Under the excitation of 370 nm,the Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+),Dy^(3+) phosphor can emit white light whose spectrum is composed of a broad emission band centered at 460 nm and the other three peaks at 483,577,and 672 nm,respectively.There is energy transfer from Eu^(2+)to Dy^(3+)ion in Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+),Dy^(3+) phosphor due to the good overlap between the emission spectrum of Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+) and the excitation spectrum of Na_(3)Sc_(2)(PO_(4))_(3):Dy^(3+),which is further confirmed by the fluorescence lifetime decrease of Eu^(2+)ion with the increase of Dy^(3+) concentration.The process of energy transfer is via dipole–quadruple interaction which is confirmed by applying Dexter's theory.By increasing the Dy^(3+)concentration,the color coordinates of the Na_(3)Sc_(2)(PO_(4))_(3):0.01Eu^(2+),xDy^(3+)phosphors can be adjusted from blue to white,and then to yellow.The optimized concentration of Dy^(3+)ions is 4.0 mol%,beyond which the concentration quenching will take place.The Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+),Dy^(3+)phosphor shows fairly good resistance to thermal quenching behavior,of which the emission intensity at 423 K can maintain 90.3%of the initial value(298 K).These results suggest that the Na_(3)Sc_(2)(PO_(4))_(3):0.01Eu^(2+),xDy^(3+)phosphors have potential applications as the color-tunable or a single-phase white emitting phosphor in white LEDs.展开更多
Cubic rock salt can lower down or break the rare earth transition barrier through interstitial or vacancy defects owing to its great deformation and rotationflexibility.Here,we demonstrate that oxygen vacancies in SrO ...Cubic rock salt can lower down or break the rare earth transition barrier through interstitial or vacancy defects owing to its great deformation and rotationflexibility.Here,we demonstrate that oxygen vacancies in SrO are induced by proper oxidization and atmosphere adjustment,resulting in defects with various depths and crystalfield distortion.The thermally assisted tunneling from defects to 5 D_(4) state and electronic population decrease on 5 D_(3) state of Tb^(3+)þare observed by the deformation of adjacent oxygen octahedral structure.Finally,the asprepared SrO:0.01 Tb^(3+)þphosphors,commercial BaMgAl10O17:Eu^(2+)þblue phosphor,and CaAlSiN3:Eu^(2+)þred phosphor are mixed and coated onto 280 nm deep-ultraviolet LED chip to assemble white light-emitting LED device.The LEDs show CCT of 3850 K,4136 K,and 4741 K,with color rendering index of 90.3,90.8,and 92.1,respectively.These insights will advance the fundamental knowledge of crystal engineering in cubic rock salt,and enable new ways to manipulate energy transfer and electronic transition via defects.展开更多
The authors regret that Chengyu Li’s affiliation was incorrect in the original manuscript.The corrected list of affiliations for this paper is as shown here.The Royal Society of Chemistry apologises for these errors ...The authors regret that Chengyu Li’s affiliation was incorrect in the original manuscript.The corrected list of affiliations for this paper is as shown here.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.展开更多
Severe pneumonia is one of the most serious infectious diseases.Delayed intervention may lead to pulmonary fibrosis,which greatly threatens people’s life and health.Blood stasis syndrome is an important underlying sy...Severe pneumonia is one of the most serious infectious diseases.Delayed intervention may lead to pulmonary fibrosis,which greatly threatens people’s life and health.Blood stasis syndrome is an important underlying syndrome throughout the evolution of severe pneumonia-pulmonary fibrosis.Xuebijing injection(XBJ)was developed under the theoretical system of“Three syndromes and three methods”,demonstrating a good efficacy in treating severe pneumonia and pulmonary fibrosis due to its effect of removing blood stasis and dispersing toxins.Previous studies have shown that XBJ can protect vascular endothelial function,improve coagulation function and regulate immunity by inhibiting inflammatory.Hence,the research hypothesis is put forward that XBJ treats blood stasis syndrome by removing blood stasis and dredging blood vessels,to inhibit the disease progress of severe pneumonia to pulmonary fibrosis.Further researches are need to confirm the function and explore the mechanism of XBJ.展开更多
Muscle strength(MS)is related to our neural and muscle systems,essential for clinical diagnosis and rehabilitation evaluation.Although emerging wearable technology seems promising for MS assessment,problems still exis...Muscle strength(MS)is related to our neural and muscle systems,essential for clinical diagnosis and rehabilitation evaluation.Although emerging wearable technology seems promising for MS assessment,problems still exist,including inaccuracy,spatiotemporal differences,and analyzing methods.In this study,we propose a wearable device consisting of myoelectric and strain sensors,synchronously acquiring surface electromyography and mechanical signals at the same spot during muscle activities,and then employ a deep learning model based on temporal convolutional network(TCN)+Transformer(Tcnformer),achieving accurate grading and prediction of MS.Moreover,by combining with deep clustering,named Tcnformer deep cluster(TDC),we further obtain a 25-level classification for MS assessment,refining the conventional 5 levels.Quantification and validation showcase a patient's postoperative recovery from level 3.2 to level 3.6 in the first few days after surgery.We anticipate that this system will importantly advance precise MS assessment,potentially improving relevant clinical diagnosis and rehabilitation outcomes.展开更多
基金supported by the National Key Research and Development Program of China(Grant Nos.2022YFA1403900 and 2021YFA1401800)the NSF of China(Grant Nos.U2032214,12122414,12104487,and 12004419)+2 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB25000000)support from the Youth Innovation Promotion Association of the CAS(2019008)supported by the Synergetic Extreme Condition User Facility(SECUF)。
文摘Signatures of superconductivity near 80 K have recently been discovered in single crystals of La_(3)Ni_(2)O_(7)under pressure,which makes it a new candidate for high-temperature superconductors dominated by 3d transition elements,following the cuprate and iron-pnictide superconductors.However,there are several critical questions that have been perplexing the scientificommunity:(1)What factors contribute to the inconsistent reproducibility of the experimental results?(2)What is the fundamental nature of pressure-induced superconductivity:bulk or nonbulk(filamentary-like)(3)Where is the superconducting phase located within the sample if it is filamentary-like(4)Is the oxygen content important for the development and stabilization of superconductivity?In this study,we employ comprehensive high-pressure techniques to address these questions.Through our modulated ac susceptibility measurements,we are the firs to fin that the superconductivity in this nickelate is filamentary-like Our scanning transmission electron microscopy investigations suggest that the filamentary-lik superconductivity most likely emerges at the interface between La_(3)Ni_(2)O_(7)and La_(4)Ni_(3)O_(10)phases.By tuning the oxygen content of polycrystalline La_(3)Ni_(2)O_(7),we also fin that it plays vital role in the development and stabilization of superconductivity in this material.The upper and lower bounds on the oxygen content are 7.35 and 6.89,respectively.Our results provide not only new insights into the puzzling issues regarding this material,but also significan information that will enable a better understanding of its superconductivity.
基金supported by the National Natural Science Foundation of China(Nos.52073032 and 52192611)the National Key R&D Project from Ministry of Science and Technology,China(No.2021YFA1201603)the Fundamental Research Funds for the Central Universities.
文摘Although flexible,stretchable,and conductive core-sheath structured smart fibers have propelled to the forefront research in wearable strain sensors and self-powered electronics,challenges related to scalability,complexity,and mechanical durability remain.In this study,we propose a strategy for the scalable production of conductive coaxial fiber(CCF)with superior durability through one-step direct wet spinning coherent solutions.By introducing the polystyrene-block-polyisoprene-block-polystyrene phase in both inner and outer layers,CCFs feature an interleaved topology and share a similar modulus,successfully resolving the issue of layer separation over time.They can endure up to 15,000 cycles with no damage at a strain of 100%.In addition,the topological entanglement CCF as a strain sensor exhibits a broad operational range of up to 398.3%strain,outstanding sensitivity(i.e.,gauge factor=6713 at 398.3%strain)and swift response time(248 ms).Enhanced by machine learning,the system achieves a high accuracy rate of 95%in gait recognition and 100%in American Sign Language identification.Furthermore,the CCF can function as a wearable triboelectric nanogenerator(TENG)for self-powered sensing and mechanical energy harvesting.This study represents a significant step toward the development of multifunctional micro-wearable electronic devices,which hold immense promise for medical sensing and energy harvesting in smart wearable electronics,human-computer interaction,and artificial intelligence.
基金the National Natural Science Foundation of China,grant numbers 51704253 and 52474084.
文摘The surface injection and production system(SIPS)is a critical component for effective injection and production processes in underground natural gas storage.As a vital channel,the rational design of the surface injection and production(SIP)pipeline significantly impacts efficiency.This paper focuses on the SIP pipeline and aims to minimize the investment costs of surface projects.An optimization model under harmonized injection and production conditions was constructed to transform the optimization problem of the SIP pipeline design parameters into a detailed analysis of the injection condition model and the production condition model.This paper proposes a hybrid genetic algorithm generalized reduced gradient(HGA-GRG)method,and compares it with the traditional genetic algorithm(GA)in a practical case study.The HGA-GRG demonstrated significant advantages in optimization outcomes,reducing the initial cost by 345.371×10^(4) CNY compared to the GA,validating the effectiveness of the model.By adjusting algorithm parameters,the optimal iterative results of the HGA-GRG were obtained,providing new research insights for the optimal design of a SIPS.
基金Project supported by the National Key R&D Program of China(2019YFA0709101)National Natural Science Foundation of China(52072364,51902305)the Fund for Creative Research Groups(21221061)。
文摘A series of novel red-emitting BaLiZn_(3)(BO_(3))_(3):Eu^(3+)phosphors were synthesized through the high temperature solid state reaction method.The phase composition,crystal structure,morphology and photo luminescence property of the BaLiZn_(3)(BO_(3))_(3):Eu^(3+)samples were systematically investigated.The phosphor can be efficiently excited by the near ultraviolet light(NUV)of 396 nm and blue light of 466 nm,and give out red light emission at 618 nm corresponding to the electric dipole transition(^(5)D_(0)→^(7)E_(2)).The optimal doping concentration of Eu^(3+)ions in BaLiZn_(3)(BO_(3))_(3)is determined to be about 3 mol%,and the concentration-quenching phenomenon arise from the electric dipole-dipole interaction.The temperature dependent luminescence behavior of BaLiZn_(3)(BO_(3))_(3):0.03 Eu^(3+)phosphor exhibits its good thermal stability,and the activation energy for thermal quenching characteristics is calculated to be 0.1844 eV.The decay lifetime of the BaLiZn_(3)(BO_(3))_(3):0.03 Eu^(3+)is measured to be 1.88 ms.These results suggest that the BaLiZn_(3)(BO_(3))_(3):Eu^(3+)phosphors have the potential application as a red component in white light emitting diodes(WLEDs)with NUV or blue chips.
基金supported by grants from the National Natural Science Foundation of China(No.31972405).
文摘Leaf color is an important target trait in Chinese cabbage breeding programs.Leaf yellowing may reduce crop commercial and nutritional values.Some plants with the“stay-green”trait maintain leaf greenness during senescence and even after death.Stay-green Chinese cabbage may be a focal point of future breeding projects because it could improve crop quality and yield and prolong shelf life.A new stay-green mutant,non-yellowing mutant 1(nym1),was identified in Chinese cabbage derived from an ethyl methane sulfonate(EMS)-mutagenized population.The mutant had stay-green characteristics and a higher chlorophyll content than the wild-type during leaf senescence.The staygreen trait in the mutant Chinese cabbage was controlled by the recessive gene Brnym1.MutMap and KASP analyses showed that Brnym1(BraA03g050600.3C)encodes an mg-dechelatase(SGR protein),which might be the causal gene of the mutation in Chinese cabbage.A nonsynonymous single nucleotide base substitution(G to A)in the third exon of Brnym1 caused an amino acid substitution from L to F in the highly conserved domain of the magnesiumdechelatase.Ectopic overexpression showed that the BrNYM1 gene of wild-type Chinese cabbage complemented the SGR-defective stay-green mutant nye1-1 of Arabidopsis.The magnesium-dechelatase activity in the nym1 mutant was significantly downregulated compared to that in the wild type.Brnym1 was relatively upregulated in the mutant during late senescence,and BrNYM1 was localized to the chloroplasts.These results indicate that Brnym1(BraA03g050600.3C)is the causal gene of the stay-green mutation and could be of particular significance in the genetic improvement of Chinese cabbage.
基金support from the National Natural Science Foundation of China(Nos.21974007 and 22090043).
文摘Anode SnO_(2)in lithium-ion batteries suffers from volume expansion and agglomeration.Here,the SnO_(2)nanoparticles are hybrided with ZrO_(2)particles by the support of carbon nanotube networks.The obtained SnO_(2)/C/ZrO_(2)composite shows improved electrochemical performances.Investigations reveal that the carbon nanotubes shorten the transmission path of electrons and Li^(+) ions.Ball milling with ZrO_(2)promotes the formation of nanosized SnO_(2)to weaken the internal strain change,being beneficial to buffering volume change during electrochemical cycling afterwards.High-resolution 6.7Li NMR investigations indicate that conversion and alloying reactions are stepwise involved for SnO_(2)/C/ZrO_(2)anode.The strategy of designing SnO_(2)/C/ZrO_(2)composite from the morphology-controlled metal-organic frameworks for energy storage widens the possibility to fabricate promising materials with enhanced performances.
基金National Natural Science Foundation of China,Grant/Award Numbers:21974007,U1930401 and U1530402。
文摘Rare-earth sulfides are of research interest for lithium-ion batteries(LIBs)due to their abundant lithium intercalation sites and low redox voltage.However,their electrochemical performances are not satisfactory because of poor conductivity and volume change upon electrochemical cycling.Herein,nanoarchitectures ofγ-Ce_(2)S_(3)encapsulated in a hollow mesoporous carbon nanosphere(Ce_(2)S_(3)@HMCS)are fabricated using the self-template strategy combined with the in-sphere sulfuration method and tested as an LIB anode.The void space between the Ce_(2)S_(3)core and the outer layer of the carbon nanosphere has been properly designed and modulated to achieve excellent electrochemical performance in terms of electronic conductivity,reversibility,and rate capability.The reversible capacity of Ce_(2)S_(3)@HMCS is 2.6 times that of the pure Ce_(2)S_(3)anode,which can gradually increase and maintain a capacity of 282 mAh·g^(−1)at a current density of 1 A·g^(-1),and a high Coulombic efficiency(~100%)can be achieved even after 1000 cycles.This good performance is attributed to the unique yolk-shell nanostructure with a highly crystallized and stable Ce3S2 core and volume expansion buffer space upon lithiation/delithiation.Ex situ X-ray diffraction and nuclear magnetic resonance results indicate that the lithiation of Ce_(2)S_(3)@HMCS is an intercalation process.This study represents an important advancement in precise structural design with in-sphere sulfuration and sheds light on a potential direction for highperformance lithium storage.
文摘It is important to understand the impact of wing-morphing on aerodynamic performance in the study of flapping-wing flight of birds and insects. We use a flapping plate hinged with a trailing-edge flap as a simplified model for flexible/morphing wings in hovering. The trailing-edge flapping motion is opti- mized by an adjoint-based approach. The optimized configuration suggests that the trailing-edge flap can substantially enhance the overall lift. Further analysis indicates that the lift enhancement by the trailing- edge flapping is from the change of circulation in two ways: the local circulation change by the rotational motion of the flap, and the modification of vortex shedding process by the relative location between the trailing-edge flao and leading-edge main plate.
基金Project supported by the Natural Science Foundation of Zhejiang Province,China(LQ21E020006)the National Key Research and Development Program of China(2019YFA0709101)Opening Fund of State Key Laboratory of Rare Earth Resource Utilization,China(Changchun Institute of Applied Chemistry)(RERU2018012)。
文摘Non-toxic rare earth(RE) composite materials are promising and active in optoelectronic fields,such as pigment.In this work,Na ions doped γ-Ce_(2) S_(3) pigments were synthesized by solid-phase vulcanization and followed by in-situ synthesis to prepare an outer layer of CePO_(4) film.The characterizations of X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),solid state nuclear magnetic resonance(NMR) indicate that Na-dopedγ-Ce_(2) S_(3) and CePO_(4) uniformly and tightly coated core-shell structure was successfully synthesized.The thermogravimetric analysis(TG) and reflection spectrum(RS) reveal that the CePO_(4) coating significantly improves the colorant and thermal stability performance of γ-Ce_(2) S_(3) .The excellent color quality of γ-Ce_(2) S_(3) @CePO_(4)(L*=45.16,a*=55.94.b*=44.53) is achieved and the red color(L*=43.82,a*=49.79,b*=38.04) is still retained even if the sample is heated in air at 400℃ for 30 min.
基金This work was supported by the second batch of the“Ten thousand plan”,a national high-level talent special support plan(W02020052).
文摘Objective:To evaluate the efficacy and safety of Shen Zhi Ling oral liquid(SZL)alone or combined with basic treatment in treating Alzheimer's Disease(AD).Methods:Databases including PubMed,the Cochrane Library,Embase,Web of science,China National Knowledge Infrastructure(CNKI),Wanfang Database and the Chinese Science and Technology Journal Database(VIP)were searched from inception to September 20,2020 to collect relevant randomized controlled trials(RCTs)comparing SZL with other nootropic drugs for AD.The primary clinical outcomes were scores of the Mini Mental State Examination(MMSE)and the Activities of Daily Living(ADL)during treatment.The secondary outcomes of our study included other neuropsychological scale scores including Rapid Verbal Retrieve(RVR),Digit Span(DS),Fuld Object-Memory Evaluation(FOM)and adverse events or reactions.Two authors searched and screened the literature independently,then extracted the data and evaluated the methodological quality by using the handbook of Cochrane Collaboration,and analyzed the data via the Review Manager 5.3 software.Results:In total,we included four studies,covering 217 participants.All studies were in a low methodological quality.The result of MMSE score,ADL score,RVR score,DS score and FOM score in the meta-analysis showed that no statistically significant difference(P>0.05)between the treatment groups and control groups,and the statistical heterogeneity of all meta-analyses was small(I2<50%).SZL was indicated no better than other nootropic drugs.Among the included studies,no study described adverse events.Conclusions:Considering the low quality of the included trials and the different levels of AD patients,we are unable to come to any conclusion about the efficacy and safety of SZL compared with other nootropic drugs.Moreover,we still need rigorously designed,multi-center,large-scale trials to further confirm the efficacy and safety of SZL.
基金supported by the National Key Research and Development Program of China(2016YFB0701003)Key Program of the Frontier Science of the Chinese Academy of Sciences(YZDY-SSW-JSC018)+1 种基金National Natural Science Foundation of China(51402288)Natural Science Foundation of Liaoning Province(201602674)
文摘A novel orange-red emitting Ba3 Y4 O9:Sm^(3+) phosphors were prepared by a high temperature solidstate reaction in air. X-ray diffraction(XRD), photoluminescence spectra, fluorescence decay and temperature-dependent emission spectra were utilized to characterize the structure and luminescence properties. The results show that the excitation spectrum includes a series of linear peaks at350, 367, 382, 410, 424, 445, 470 and 495 nm, respectively. Under 410 nm excitation, the emission peaks were located at 574 nm(~4 G(5/2)-~6 H(5/2)), 608 nm(~4 G(5/2)-~6 H(7/2)),659 nm(~4 G(5/2)-~6 H(9/2)) and722 nm(~4 G(5/2)-~6 H(11/2)), respectively. The concentration quenching occurs when x equals 0.08 for Ba3 Y(4-x)O9:xSm^(3+) phosphor and its mechanism is ascribed to the dipole-dipole interaction. The chromaticity coordinates of Ba3 Y(3.92)O9:0.08 Sm^(3+) phosphor are in the orange-red region. The temperature-dependent study shows that this phosphor has excellent luminescence thermal-stability.And the luminescence intensity of Ba3 Y(3.92)O9:0.08 Sm^(3+) phosphor at 473 K only declines by about25.75% of its initial intensity. The experimental data indicate that Ba3 Y4 O9:Sm^(3+) phosphor may be promising as an orange-red emitting phosphor for white light emitting diodes.
基金Project supported by the National Key Research and Development Program of China(2018YFD0901505)the Science and Technology Cooperation Program between Jilin Province and Chinese Academy of Sciences(2019SYHZ0008)。
文摘The powder samples of Ca_(9)Sc(PO_(4))_(7):xDy^(^(3+))white emitting phosphors were prepared via a solid state reaction technique.The Ca_(9)Sc(PO_(4))_(7):Dy^(3+)samples were researched by using the GSAS Rietveld refinement and X-ray diffraction(XRD) methods,and SEM images and elemental maps were recorded.Under 350 nm excitatio n,the emission spectra of Ca_(9)Sc(PO_(4))_(7):xDy^(3+)samples have two obvious peaks and one weak peak at 484,572 and660 nm,corresponding to the characteristic electron transitions of(^(4)F_(9/2)→ ^(6)H_(15/2),blue),(^(4)F_(9/2)→ ^(6)H_(13/2),yellow) and(^(4)F_(9/2)→ 6 H11/2,red),respectively.The concentration quenching effect,decay lifetime and thermal quenching of the as-synthesized Ca_(9)Sc(PO_(4))_(7):Dy^(3+)samples were researched systematically.The Ca_(9)Sc(PO_(4))_(7):0.02 Dy^(3+)phosphor possesses a good thermal stability,of which the emission intensity at 423 K can maintain 79% of the initial value(273 K).In addition,through the study of the chro maticity coordinates of the Ca_(9)Sc(PO_(4))_(7):0.02 Dy^(3+)phosphor,it is found that it is located in the white region,and the Commission Internationalede L’Eclairage(CIE) chromaticity coordinates are(0.339,0.389),The above results show that Ca_(9)Sc(PO_(4))_(7):xDy^(3+)phosphors can be excellent candidate material for applications in NUV-excited white LEDs.
基金financially supported by the National Key R&D Program of China(Grant Nos.2016YFA0202704 and 2019YFA0706900)the Beijing Municipal Natural Science Foundation(Grant No.2212052)+1 种基金the China Postdoctoral Science Foundation(Grant No.2019T120390)the Jiangsu Planned Projects for Postdoctoral research funds(Grant No.2018K018A)。
文摘It is of great importance to explore a creative route to improve the degradation e ciency of organic pollutants in wastewater.Herein,we construct a unique hybrid system by combining self-powered triboelectric nanogenerator(TENG)with carbon dots-TiO_(2)sheets doped three-dimensional graphene oxide photocatalyst(3 DGA@CDs-TNs),which can significantly enhance the degradation e ciency of brilliant green(BG)and direct blue 5 B(DB)owing to the powerful interaction of TENG and 3 DGA@CDs-TNs photocatalyst.The power output of TENG can be applied for wastewater purification directly,which exhibits a selfpowered electrocatalytic technology.Furthermore,the results also verify that TENG can replace conventional electric catalyst to remove pollutants e ectively from wastewater without any consumption.Subsequently,the unstable fragments and the plausible removal pathways of the two pollutants are proposed.Our work sheds light on the development of e cient and sustainable TENG/photocatalyst system,opening up new opportunities and possibilities for comprehensive utilization of random energy.
基金supported by the National Natural Science Foundation of China (No. 50974010)the Natural Science Foundation of Beijing (No. 2102039)
文摘The tilt-blade mechanical stirring of A356-2.5vol.%SiCp liquid was conducted in a cylindrical crucible to solve the problem of nonhomogeneous radial distribution of SiC particles in conventional straight-blade mechanical stirring. The radial distribution of SiC particles in A356 liquid was studied under the conditions of 25° for horizontal tilt angle α of the blade, 200 r/min for rotating speed of stirrer and 10 mm/s for speed of moving up and down of stirrer. The results show that there exists a nonlinear relationship between circumferential tilt angle β of the blade and radial relative deviation d of SiCp content in A356 liquid. When β is smaller than 20°, the d of SiCp content in A356 liquid between the center and the periphery of crucible decreases with increasing β. Conversely, when β is bigger than 26°, d increases with increasing β. Only when β is about 20°, d can be equal to nought i.e. uniform radial distribution of SiC particles can be realized. It can be seen that the nonhomogeneous radial distribution of SiC particles in conventional straight-blade mechanical stirring can be eliminated in this tilt-blade mechanical stirring of A356-SiCp liquid.
基金Project supported by the National Key Research and Development Program of China(2019YFA0709101)the Science and Technology Cooperation Program between Jilin Province and Chinese Academy of Sciences(2019SYHZ0008)R&D Projects in Key Areas of Guangdong Province(2020B0101010001)。
文摘A series of Eu^(2+)/Dy^(3+) single doped and co-doped Na_(3)Sc_(2)(PO_(4))_(3) phosphors were synthesized by the high-temperature solid-state method,and their phase,morphology,and luminescence properties were characterized.Under the excitation of 370 nm,the Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+),Dy^(3+) phosphor can emit white light whose spectrum is composed of a broad emission band centered at 460 nm and the other three peaks at 483,577,and 672 nm,respectively.There is energy transfer from Eu^(2+)to Dy^(3+)ion in Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+),Dy^(3+) phosphor due to the good overlap between the emission spectrum of Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+) and the excitation spectrum of Na_(3)Sc_(2)(PO_(4))_(3):Dy^(3+),which is further confirmed by the fluorescence lifetime decrease of Eu^(2+)ion with the increase of Dy^(3+) concentration.The process of energy transfer is via dipole–quadruple interaction which is confirmed by applying Dexter's theory.By increasing the Dy^(3+)concentration,the color coordinates of the Na_(3)Sc_(2)(PO_(4))_(3):0.01Eu^(2+),xDy^(3+)phosphors can be adjusted from blue to white,and then to yellow.The optimized concentration of Dy^(3+)ions is 4.0 mol%,beyond which the concentration quenching will take place.The Na_(3)Sc_(2)(PO_(4))_(3):Eu^(2+),Dy^(3+)phosphor shows fairly good resistance to thermal quenching behavior,of which the emission intensity at 423 K can maintain 90.3%of the initial value(298 K).These results suggest that the Na_(3)Sc_(2)(PO_(4))_(3):0.01Eu^(2+),xDy^(3+)phosphors have potential applications as the color-tunable or a single-phase white emitting phosphor in white LEDs.
基金supported by the Natural Science Foundation of Zhejiang Province(Grant No.LQ21E020006)the Fundamental Research Funds for the Provincial Universities of Zhejiang(Grant No.2021YW46)the National Natural Science Foundation of China(Grant 62205322,22090043).
文摘Cubic rock salt can lower down or break the rare earth transition barrier through interstitial or vacancy defects owing to its great deformation and rotationflexibility.Here,we demonstrate that oxygen vacancies in SrO are induced by proper oxidization and atmosphere adjustment,resulting in defects with various depths and crystalfield distortion.The thermally assisted tunneling from defects to 5 D_(4) state and electronic population decrease on 5 D_(3) state of Tb^(3+)þare observed by the deformation of adjacent oxygen octahedral structure.Finally,the asprepared SrO:0.01 Tb^(3+)þphosphors,commercial BaMgAl10O17:Eu^(2+)þblue phosphor,and CaAlSiN3:Eu^(2+)þred phosphor are mixed and coated onto 280 nm deep-ultraviolet LED chip to assemble white light-emitting LED device.The LEDs show CCT of 3850 K,4136 K,and 4741 K,with color rendering index of 90.3,90.8,and 92.1,respectively.These insights will advance the fundamental knowledge of crystal engineering in cubic rock salt,and enable new ways to manipulate energy transfer and electronic transition via defects.
文摘The authors regret that Chengyu Li’s affiliation was incorrect in the original manuscript.The corrected list of affiliations for this paper is as shown here.The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
基金the second batch of“Ten thousand plan”-National high level talents special support plan(W02020052).
文摘Severe pneumonia is one of the most serious infectious diseases.Delayed intervention may lead to pulmonary fibrosis,which greatly threatens people’s life and health.Blood stasis syndrome is an important underlying syndrome throughout the evolution of severe pneumonia-pulmonary fibrosis.Xuebijing injection(XBJ)was developed under the theoretical system of“Three syndromes and three methods”,demonstrating a good efficacy in treating severe pneumonia and pulmonary fibrosis due to its effect of removing blood stasis and dispersing toxins.Previous studies have shown that XBJ can protect vascular endothelial function,improve coagulation function and regulate immunity by inhibiting inflammatory.Hence,the research hypothesis is put forward that XBJ treats blood stasis syndrome by removing blood stasis and dredging blood vessels,to inhibit the disease progress of severe pneumonia to pulmonary fibrosis.Further researches are need to confirm the function and explore the mechanism of XBJ.
基金supported by The Youth Innovation Promotion Association,CAS,and Key Clinical Projects of Peking University Third Hospital(no.BYSYZD2023004)This study was conducted with approval from the Peking University Third Hospital Medical Science Research Ethics Committee(no.M2021091)all patients were fully informed and provided written consent prior to participation.
文摘Muscle strength(MS)is related to our neural and muscle systems,essential for clinical diagnosis and rehabilitation evaluation.Although emerging wearable technology seems promising for MS assessment,problems still exist,including inaccuracy,spatiotemporal differences,and analyzing methods.In this study,we propose a wearable device consisting of myoelectric and strain sensors,synchronously acquiring surface electromyography and mechanical signals at the same spot during muscle activities,and then employ a deep learning model based on temporal convolutional network(TCN)+Transformer(Tcnformer),achieving accurate grading and prediction of MS.Moreover,by combining with deep clustering,named Tcnformer deep cluster(TDC),we further obtain a 25-level classification for MS assessment,refining the conventional 5 levels.Quantification and validation showcase a patient's postoperative recovery from level 3.2 to level 3.6 in the first few days after surgery.We anticipate that this system will importantly advance precise MS assessment,potentially improving relevant clinical diagnosis and rehabilitation outcomes.