Valuable chiral N-Boc-β-benzyl-β-amino acid was concisely synthesized via construction of chiral NBoc-3-benzyl-5-oxoisoxazolidine through cross-metathesis/conjugate addition/oxidation.All of the starting materials f...Valuable chiral N-Boc-β-benzyl-β-amino acid was concisely synthesized via construction of chiral NBoc-3-benzyl-5-oxoisoxazolidine through cross-metathesis/conjugate addition/oxidation.All of the starting materials for the synthesis of chiral N-Boc-β-benzyl-β-amino acid are cheap,and two-step short procedure make it easy for the rapid construction of various chiral β-arylmethyl-β-amino acids and important drugs,such as sitagliptin phosphate.展开更多
Three novel triarylamine dyes（AFL1-AFL3） containing fluorenyl and the biphenyl moieties have been designed and synthesized for application in dye-sensitized solar cells.The light-harvesting capabilities and photovol...Three novel triarylamine dyes（AFL1-AFL3） containing fluorenyl and the biphenyl moieties have been designed and synthesized for application in dye-sensitized solar cells.The light-harvesting capabilities and photovoltaic performance of these dyes were investigated systematically through comparison of different π-bridges.The dye with a furan linker exhibited a higher open-circuit voltage（VOC） and monochromatic incident photon-to-current conversion efficiency（IPCE） compared to thiophene and benzene linker.Thus,AFL3 containing a furan linker exhibited the maximum overall conversion efficiency of 5.81%（VOC = 760 mV,JSC = 11.36 mA cm^-2 and ff=0.68） under standard global AM 1.5 G solar condition.展开更多
基金financial support for this study from the National Natural Science Foundation of China (No. 21472110)
文摘Valuable chiral N-Boc-β-benzyl-β-amino acid was concisely synthesized via construction of chiral NBoc-3-benzyl-5-oxoisoxazolidine through cross-metathesis/conjugate addition/oxidation.All of the starting materials for the synthesis of chiral N-Boc-β-benzyl-β-amino acid are cheap,and two-step short procedure make it easy for the rapid construction of various chiral β-arylmethyl-β-amino acids and important drugs,such as sitagliptin phosphate.
基金National Natural Science Foundation of China (No. 21176223)National Natural Science Foundation of China (No. 21406202)Natural Science Foundation of Zhejiang province (No. LY15B020009)
文摘Three novel triarylamine dyes（AFL1-AFL3） containing fluorenyl and the biphenyl moieties have been designed and synthesized for application in dye-sensitized solar cells.The light-harvesting capabilities and photovoltaic performance of these dyes were investigated systematically through comparison of different π-bridges.The dye with a furan linker exhibited a higher open-circuit voltage（VOC） and monochromatic incident photon-to-current conversion efficiency（IPCE） compared to thiophene and benzene linker.Thus,AFL3 containing a furan linker exhibited the maximum overall conversion efficiency of 5.81%（VOC = 760 mV,JSC = 11.36 mA cm^-2 and ff=0.68） under standard global AM 1.5 G solar condition.
