Materials exhibiting broadband nonlinear optical responses are critically important for ultrafast photonics applications,particularly as saturable absorbers(SAs)that facilitate broadband optical pulse generation.In th...Materials exhibiting broadband nonlinear optical responses are critically important for ultrafast photonics applications,particularly as saturable absorbers(SAs)that facilitate broadband optical pulse generation.In this study,tea polyphenolpolyvinyl alcohol(TP-PVA)composite films are synthesized via a polymer embedding method and employed as SAs to initiate ultrafast pulse operation in fiber lasers.The TP-PVA SA film exhibits excellent broadband saturable absorption performance at wavelengths of 1.0μm,1.5μm,and 2.0μm,with modulation depths of 54.21%,41.41%,and 51.16%,respectively.Stable passively mode-locked pulses with pulse widths of 588 fs,419 fs,and 743 fs are generated in Yb-,Er-,and Tm-doped fiber lasers,respectively.This work confirms the effective performance of TP-PVA as a broadband SA,and establishes a foundation for the integration of novel and sustainable materials within ultrafast photonic systems.The approach paves the way for developing compact broadband ultrafast laser systems operating in the near-infrared spectral region.展开更多
Currently,the performance,cost,and environmental sustainability of saturable absorbers(SAs)represent major bottlenecks in the development of ultrafast fiber lasers.However,the development of high-performance SAs remai...Currently,the performance,cost,and environmental sustainability of saturable absorbers(SAs)represent major bottlenecks in the development of ultrafast fiber lasers.However,the development of high-performance SAs remains challenging due to intricate fabrication processes and inadequate nonlinear performance.In this context,this work presents the natural alkaloid berberine as a promising alternative for mode-locked erbium-doped fiber lasers.The berberine-based SA exhibits excellent nonlinear optical properties,including a modulation depth of 24.40%and a saturation intensity of 1.281MW/cm^(2),and successfully enables stable femtosecond pulse generation.By employing time-stretched dispersive Fourier transform technology,the transient dynamics results indicate that the berberine-based SA significantly shortens the relaxation oscillation time and effectively suppresses pulse intensity fluctuations,thereby accelerating the self-starting process of mode-locking.This work provides a new strategy for developing high-performance,low-cost,and environmentally friendly ultrafast photonic devices,significantly advancing the practical application of green SAs.展开更多
Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,p...Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,pharmaceuticals,organic materials and fine chemicals.In this context,we herein demonstrate an unprecedented,robust and generally applicable synthetically strategy to deliver these two crucial ketone frameworks via visible-light-induced ring-opening coupling reactions of cycloalcohols with vinylazaarenes and enones,respectively.A plausible mechanism involves the selectiveβ-C-C bond cleavage of cycloalcohols enabled by proton-coupled electron transfer and ensuing Giese-type addition followed by single electron reduction and protonation.The synthetic methodology exhibits broad substrate scope,excellent functional group compatibility as well as operational simplicity and environmental friendliness.展开更多
基金supported by the Opening Foundation of Hubei Key Laboratory for New Textile Materials and Applications Research(Grant No.FZXCL202410)the Key Project of Science and Technology Research Program of Hubei Provincial Department of Education,China(Grant No.D20231704)+1 种基金Wuhan Textile University(Grant No.523058)the Foundation of Wuhan Textile University(Grant No.K24058)。
文摘Materials exhibiting broadband nonlinear optical responses are critically important for ultrafast photonics applications,particularly as saturable absorbers(SAs)that facilitate broadband optical pulse generation.In this study,tea polyphenolpolyvinyl alcohol(TP-PVA)composite films are synthesized via a polymer embedding method and employed as SAs to initiate ultrafast pulse operation in fiber lasers.The TP-PVA SA film exhibits excellent broadband saturable absorption performance at wavelengths of 1.0μm,1.5μm,and 2.0μm,with modulation depths of 54.21%,41.41%,and 51.16%,respectively.Stable passively mode-locked pulses with pulse widths of 588 fs,419 fs,and 743 fs are generated in Yb-,Er-,and Tm-doped fiber lasers,respectively.This work confirms the effective performance of TP-PVA as a broadband SA,and establishes a foundation for the integration of novel and sustainable materials within ultrafast photonic systems.The approach paves the way for developing compact broadband ultrafast laser systems operating in the near-infrared spectral region.
基金supported by the Key Project of Science and Technology Research Program of Hubei Provincial Department of Education,China(D20231704)the Opening Foundation of Hubei Key Laboratory for New Textile Materials and Applications Research(FZXCL202410)the Wuhan Textile University Special Fund Project。
文摘Currently,the performance,cost,and environmental sustainability of saturable absorbers(SAs)represent major bottlenecks in the development of ultrafast fiber lasers.However,the development of high-performance SAs remains challenging due to intricate fabrication processes and inadequate nonlinear performance.In this context,this work presents the natural alkaloid berberine as a promising alternative for mode-locked erbium-doped fiber lasers.The berberine-based SA exhibits excellent nonlinear optical properties,including a modulation depth of 24.40%and a saturation intensity of 1.281MW/cm^(2),and successfully enables stable femtosecond pulse generation.By employing time-stretched dispersive Fourier transform technology,the transient dynamics results indicate that the berberine-based SA significantly shortens the relaxation oscillation time and effectively suppresses pulse intensity fluctuations,thereby accelerating the self-starting process of mode-locking.This work provides a new strategy for developing high-performance,low-cost,and environmentally friendly ultrafast photonic devices,significantly advancing the practical application of green SAs.
基金financial support from National Natural Science Foundation of China(Nos.21801129,22078153 and22378201)National Key Research and Development Program of China(No.2022YFB3805603)+3 种基金Natural science research projects in Jiangsu Higher Education Institutions(No.18KJB150018)Open Research Fund of School of Chemistry and Chemical EngineeringHenan Normal University(No.2024Y16)Nanjing Tech University(Start-up Grant Nos.39837137,39837101 and 3827401739)for financial support。
文摘Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,pharmaceuticals,organic materials and fine chemicals.In this context,we herein demonstrate an unprecedented,robust and generally applicable synthetically strategy to deliver these two crucial ketone frameworks via visible-light-induced ring-opening coupling reactions of cycloalcohols with vinylazaarenes and enones,respectively.A plausible mechanism involves the selectiveβ-C-C bond cleavage of cycloalcohols enabled by proton-coupled electron transfer and ensuing Giese-type addition followed by single electron reduction and protonation.The synthetic methodology exhibits broad substrate scope,excellent functional group compatibility as well as operational simplicity and environmental friendliness.
