To investigate sulfide detoxification in Urech＆ unicinctus, oxygen consumption rate and sulfide detoxification products were analyzed during sulfide exposure under controlled laboratory conditions. The results showed...To investigate sulfide detoxification in Urech＆ unicinctus, oxygen consumption rate and sulfide detoxification products were analyzed during sulfide exposure under controlled laboratory conditions. The results showed that oxygen consumption rates were elevated significantly during 3 h sulfide exposure compared to the control （P〈0.05）. The concentration of sulfite in body wall and hindgut of experimental worms increased significantly （P〈0.05） when exposed to 50 μmolL^-1 sulfide, reached a maximum at 24 h and then decreased. Similar result was observed in worms exposed to 150 μmolL^-1 sulfide except that sulfite concentration reached a maximum at 12 h. Contents of thiosulfate in body wall and hindgut of U. unicinctus exposed to sulfide were also significantly higher than that of the control without sulfide exposure. In conclusion, during short-time sulfide exposure U. unicinctus may raise oxygen consumption to detoxify toxic sulfide into sulfite and thiosulfate. Sulfide detoxification was restrained when the exposure time was prolonged or sulfide concentration was increased, which was indicated by decrease of sulfite, the intermediate product of sulfide detoxification.展开更多
A novel surface plasmon resonance （SPR） sensor based on molecularly imprinted films （MIFs） was developed for the detection of pentaerythritol tetranitrate （PETN）. In this work, the thin MIFs were formed on a gol...A novel surface plasmon resonance （SPR） sensor based on molecularly imprinted films （MIFs） was developed for the detection of pentaerythritol tetranitrate （PETN）. In this work, the thin MIFs were formed on a gold sensor chip through thermal co-polymerization of functional mono- mers （methacrylic acid, MAA） and crosslinking monomers （ethylene glycol dimethacrylate, EGD- MA） in the presence of template molecules PETN. The template molecules PETN were subsequently removed from the MIFs simply by rinsing the MIFs with a mixture of acetonitrile and acetic acid 9：1 （ v/v）, thus the recognition sites were formed for specific detection of PETN. According to the mass coverage equation, the surface coverage of removed PETN from MIFs was about 10. 8 ng/mm~. The developed SPR sensor allowed for the detection of PETN at concentration down to 10-~~ mol/L. A control experiment utilizing an analogue cyclotrimethylenetrinitramine （RDX） showed MIFs＇ good selectivity to PETN.展开更多
黄海呈现独有的地形条件,且该海域的潮波运动独具特征。本文利用静止海洋水色成像仪(Geostationary Ocean Color Imager, GOCI)遥感反演和俄勒冈州立大学(Oregon State University,OSU)潮流模式分别获取了黄海海域的海表流场,基于该海...黄海呈现独有的地形条件,且该海域的潮波运动独具特征。本文利用静止海洋水色成像仪(Geostationary Ocean Color Imager, GOCI)遥感反演和俄勒冈州立大学(Oregon State University,OSU)潮流模式分别获取了黄海海域的海表流场,基于该海域独特的潮波系统提出并识别潮波干涉区,进而对GOCI反演的流场做潮流提取,并对两种潮流数据作分区可用性评价,通过实测的漂流浮标数据验证评估。结果表明:利用GOCI反演和OSU潮流模式获取的海表流场具有一定程度的可靠性,GOCI反演的海表流场的流速平均相对大小误差值为0.77,OSU潮流模式获取的海表流场流速平均相对大小误差值为0.49;在靠近潮波干涉区的黄海中部海域,GOCI潮流数据与实测数据在方向上的一致性要优于OSU潮流数据,两者平均角度误差值分别为48.45°和63.10°;在远离潮波干涉区的黄海近岸海域,OSU潮流数据与实测数据在速度大小和方向上的一致性要优于GOCI潮流数据。展开更多
基金supported by the National Natural Science Foundation of China under contract Nos.40776074and 30570223
文摘To investigate sulfide detoxification in Urech＆ unicinctus, oxygen consumption rate and sulfide detoxification products were analyzed during sulfide exposure under controlled laboratory conditions. The results showed that oxygen consumption rates were elevated significantly during 3 h sulfide exposure compared to the control （P〈0.05）. The concentration of sulfite in body wall and hindgut of experimental worms increased significantly （P〈0.05） when exposed to 50 μmolL^-1 sulfide, reached a maximum at 24 h and then decreased. Similar result was observed in worms exposed to 150 μmolL^-1 sulfide except that sulfite concentration reached a maximum at 12 h. Contents of thiosulfate in body wall and hindgut of U. unicinctus exposed to sulfide were also significantly higher than that of the control without sulfide exposure. In conclusion, during short-time sulfide exposure U. unicinctus may raise oxygen consumption to detoxify toxic sulfide into sulfite and thiosulfate. Sulfide detoxification was restrained when the exposure time was prolonged or sulfide concentration was increased, which was indicated by decrease of sulfite, the intermediate product of sulfide detoxification.
基金Supported by the National Natural Science Foundation of Chi- na （20771015） the lll Project of Higher Education of China （B07012）
文摘A novel surface plasmon resonance （SPR） sensor based on molecularly imprinted films （MIFs） was developed for the detection of pentaerythritol tetranitrate （PETN）. In this work, the thin MIFs were formed on a gold sensor chip through thermal co-polymerization of functional mono- mers （methacrylic acid, MAA） and crosslinking monomers （ethylene glycol dimethacrylate, EGD- MA） in the presence of template molecules PETN. The template molecules PETN were subsequently removed from the MIFs simply by rinsing the MIFs with a mixture of acetonitrile and acetic acid 9：1 （ v/v）, thus the recognition sites were formed for specific detection of PETN. According to the mass coverage equation, the surface coverage of removed PETN from MIFs was about 10. 8 ng/mm~. The developed SPR sensor allowed for the detection of PETN at concentration down to 10-~~ mol/L. A control experiment utilizing an analogue cyclotrimethylenetrinitramine （RDX） showed MIFs＇ good selectivity to PETN.
文摘黄海呈现独有的地形条件,且该海域的潮波运动独具特征。本文利用静止海洋水色成像仪(Geostationary Ocean Color Imager, GOCI)遥感反演和俄勒冈州立大学(Oregon State University,OSU)潮流模式分别获取了黄海海域的海表流场,基于该海域独特的潮波系统提出并识别潮波干涉区,进而对GOCI反演的流场做潮流提取,并对两种潮流数据作分区可用性评价,通过实测的漂流浮标数据验证评估。结果表明:利用GOCI反演和OSU潮流模式获取的海表流场具有一定程度的可靠性,GOCI反演的海表流场的流速平均相对大小误差值为0.77,OSU潮流模式获取的海表流场流速平均相对大小误差值为0.49;在靠近潮波干涉区的黄海中部海域,GOCI潮流数据与实测数据在方向上的一致性要优于OSU潮流数据,两者平均角度误差值分别为48.45°和63.10°;在远离潮波干涉区的黄海近岸海域,OSU潮流数据与实测数据在速度大小和方向上的一致性要优于GOCI潮流数据。
